• Bulletin of the Korean Chemical Society
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• 제26권12호
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• pp.1937-1940
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• 2005

A lab-made chemiluminescence system with air pump was developed for monitoring of some metal levels in rain. The air pump enabled injection of 17.7 $\mu$g samples into a glass cell filled with luminol-$H_2O_2$ reagent of typically 300 $\mu$L for chemiluminescence measurement. The monitored trend of total metal ions in the rain collected in our campus was compared with analytical results of each metal ion from GFAAS. The system was also demonstrated to determine $Cr^{6+}$ by reduction to $Cr^{3+}$ using $SnCl_2$. The limit of detection for $Cr^{6+}$ obtained by 4 measurements was 85.0 pg $mL^{-1}$ with a relative standard deviation of 3.4%. Although this system doesn’t have selectivity due to the characteristics of chemiluminescence, application of it to environmental monitoring as a sensor for some transition metal ions was demonstrated.

• Bulletin of the Korean Chemical Society
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• 제25권2호
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• pp.213-215
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• 2004

An indirect, sensitive and accurate method for the determination of trace amounts of hydrazine is described. The method is based on the oxidation of hydrazine by a known excess of iodate in the presence of hydrochloric acid. The unreacted iodate is used in the oxidation of hydroxylamine to nitrite. Sulfanilic acid is diazotized by the nitrite formed. The resulting diazonium ion is coupled with N-(1-naphthyl)ethylenediamine to form a stable azo dye, which shows an absorption maximum at 540 nm. Hydrazine can be determined in the range of 20-400 ng $mL^{-1}$ with a detection limit of 3.1 ng $mL^{-1}$. The relative standard deviation for 50, 200 and 400 ng $mL^{-1}$ of hydrazine is 2, 1.5 and 1.3%, respectively (n = 10). The method was applied to the determination of hydrazine in water samples.

• Bulletin of the Korean Chemical Society
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• 제24권8호
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• pp.1177-1180
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• 2003

Thallium is quantitatively retained by 1,10-phenanthroline and tetraphenylborate onto benzophenone in the pH range 0-11 from a large volumes of aqueous solutions of various samples. After filtration, the solid mass consisting of thallium complex and benzophenone is dissolved with 5 mL of dimethylformamide and the metal was determined by flame atomic absorption spectrometric. About 0.4 ㎍ of thallium can be concentrated from 400 mL of aqueous sample, where its concentration is as low as 1.0 ng/mL. Eight replicate determinations of 8.0 ㎍/mL of thallium in final dimethylformamide solution gave a mean absorbance of 0.160 with a relative standard deviation of 1.7%. The sensitivity for 1% absorption was 0.22 ㎍/mL. The interference of a large number of anions and cations has been studied and the optimized conditions developed were utilized for the trace determination of thallium in various alloys and biological samples.

• 한국지역사회생활과학회지
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• 제11권2호
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• pp.1-14
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• 2000

The purpose of this study was to empirically verify influence of objective variables and subjective variables of time management strategy of unmarried men and women and provide a basis for the development of time management. The subject of this study were 370 unmarried men and women and interviewed with a questionnaire. The data were analyzed by SPSS/PC+ program for the frequency, mean, standard deviation, and regression analysis. The major results of this study were as follows: 1. The score of implementing time management strategy of unmarried men and women was the highest. The score of getting support time management strategy of unmarried men and women was the lowest. 2. Variables that affect overall time management strategy were age, academic career, sex, degree of information using fate control orientation and communication. 3. The relative contribution of subjective variables on time management strategy were higher than objective variables.

• 품질경영학회지
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• 제21권2호
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• pp.17-26
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• 1993

Process fault diagnosis is a complicated matter because quality control problems can result from a variety of causes. These causes include problems with electrical components, mechanical components, human errors, job justification errors, and air conditioning influences. In order to make the system run smoothly with minimum delay, it is necessary to suggest heuristic remedies for the detected faults. Hence, this paper describes a heuristic methodology of fault diagnosis that is performed using statistical patterns generated by quality characteristics The proposed methodology is described briefly as follows: If a sample pattern generated by random variables is similar to the number of prototype patterns, the sample pattern may be matched by any prototype pattern among them to be resembled. This concept is based on the similarity between a sample pattern and the matched prototype pattern. The similarity is calculated as the weighted average of squared deviation, which is expressed as the difference between the relative values of standard normal distribution to be transformed by the observed values of quality characteristics in a sample pattern and the critical values of the corresponding ones in a matched prototype pattern.

• 한국연초학회지
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• 제10권1호
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• pp.65-73
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• 1988

The fragilities of the tobacco has been considered to be one of the most Important factor in determing not only the quality of the tobacco but also the economic effect to cigarettes manufacturing. The three blender methods to determine relative fragilities were compared with the Korea Tabacco & Ginseng Research Institute Standared Fragilities Test in order to established a suitable method for measuring the fragilities of Korea tobacco leaves. Fragilities measurement by the blender methods expressed either sieve aperture or fineness index and a statistical comparison of the three blender methods was made to short the mirror variance, standard deviation, coefficient of variation, slope, correlation, sensitivity index, etc.

• 한국환경과학회지
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• 제19권8호
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• pp.941-949
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• 2010

The three electrode system was used to detect the pesticide fenitrothion ($C_9H_{12}NO_5PS$. MW=277.24) using cyclic voltammetry (CV) and square wave anodic stripping voltammetry (SWASV). The working electrode was mercury immobilized on a carbon nanotube paste electrode (Hg-CNTPE). At the optimized condition, the limit of detection (LoD) was 0.6 ppt ($2.16{\times}10^{-12}\;M$), and the relative standard deviation was 0.035% (n=15). And there is more sensitive in detecting fenitrothion than common type carbon nanotube paste electrode. When it was implanted into the brain of live fish (carp), the existence of fenitrothion was measured without any destruction or damage of tissue.

• Natural Product Sciences
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• 제10권6호
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• pp.262-267
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• 2004

A reversed-phase liquid chromatographic method for decursin and decursinol angelate of Angelicae gigantis Radix, an important crude drug in Korean traditional medicine, was developed and validated. Decursin and decursinol angelate, the structure isomer (pyranocoumarin) each other, are the main organic constituents in Angelicae gigantis Radix. This method was developed using a RP-18 column, UV detector at 280 nm and 50% acetonitrile solution containing 0.01 M sodium dodecyl sulfate and 25 mM sodium dihydrogen phosphate (pH 5.0) as the mobile phase. Various validation parameters were included and evaluated satisfactorily. Linearity was established in range 2-75 mg/ml of decursin and decursinol angelate (correlation coefficient = 0.9997 and 0.9995, respectively). This analytical method showed good accuracy (98.1% and 99.5%, respectively). Precision (repeatability) revealed a relative standard deviation value of 1.71% (decursin) and 3.19% (decursinol angelate). For intermediate precision measure the considered variables were equipment and days. A robustness test showing the influence of deferent counter-ion concentration in mobile phase was also performed.

• 에너지공학
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• 제22권2호
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• pp.205-210
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• 2013

Cycle-to-cycle variation has long been recognized as limiting the range of operating conditions of spark ignition engines, in particular, under lean and highly diluted operation conditions. At a part load, some of the cycles tend to knock, while others may have incomplete combustion by the time the exhaust valve opens. An experimental study has been performed in order to evaluate the relative contribution of several relevant parameters on the cyclic variability in spark ignition engines. In general, the stability of engine operation is improved with fuel injector according to the optimal injection timing, but the stability of engine operation at idle is not improved compared with a practical gasoline engine. In this study, we investigated the relationship of the effect of operating conditions for the stability at low speed and load.

• ETRI Journal
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• 제17권3호
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• pp.45-63
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• 1995

This paper proposes an algorithm to improve the correlation between giga-hertz transverse electromagnetic (GTEM) cell and open area test site (OATS). It is based on the dipole modeling process of an unknown source object in a GTEM cell and on the evaluation of the approximate far field equations correlated with measured GTEM powers at output port of the GTEM cell. In this algorithm, the relative phase differences between dipole moments play an important part in modeling the test object as a set of dipoles and offer stable calculation of emission values. The radiated emission test using this algorithm requires fifteen orientations of equipment under test, but the increased orientations as compared with the previous method have little effect on the time needed for testing. Radiation from a notebook computer has been tested for statistical analysis of the correlation between GTEM data and OATS data. The emission test results of the notebook computer show that the mean, the standard deviation, and the correlation coefficient are -0.62, 1.99, and +0.85, respectively. These figures indicate that this algorithm provides improved accuracy in the measurement of electromagnetic emissions over the previous method.