• Title/Summary/Keyword: Relationship coefficient

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Determination and Temperature Dependence of n-Octanol/Water Partition Coefficients for Seven Sulfonamides from (298.15 to 333.15) K

  • Congliang, Zhang;Yan, Wang;Fuan, Wang
    • Bulletin of the Korean Chemical Society
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    • v.28 no.7
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    • pp.1183-1186
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    • 2007
  • A shake-flask method was used to determine the n-octanol/water partition coefficients of sulfamethazine, sulfadimethoxine, sulfamethoxydiazine, sulfamonomethoxine, sulfamethoxazole, sulfaquinoxaline and sulfachloropyrazine from (298.15 to 333.15) K. The results showed that the n-octanol/water partition coefficient of each sulfonamide decreased with the increase of temperature. Based on the fluid phase equilibrium theory, the thermodynamic relationship of n-octanol/water partition coefficient depending on the temperature is proposed, and the changes of enthalpy, entropy, and the Gibbs free energy function for sulfonamides partitioning in n-octanol/ water are determined, respectively. Sulfonamides molecules partitioning in n-octanol/water is mainly an enthalpy driving process, during which the order degrees of system increased. The temperature effect coefficient of n-octanol/water partition coefficient is discussed. The results show that its magnitude is the same as that of values in the literature.

Effects of Concrete Properties and Testing Method! on Coefficient of Chloride Diffusion in Hardened Concrete (콘크리트 물성 및 시험법이 콘크리트 염화물 확산 계수에 미치는 영향)

  • 김명유;양은익;최중철;이광교;민석홍;이성태
    • Proceedings of the Korea Concrete Institute Conference
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    • 2003.05a
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    • pp.699-704
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    • 2003
  • Corrosion of reforcement is the main cause of damage and early failure of reinforced concrete structures. The corrosion is mainly progressed by the chloride ingress. In this paper, an experimental study is executed to investigate the effect of concrete properties and testing method on the coefficient of chloride diffusion. Also, it is compared that the relationship between total chloride and free chloride in concrete. According to this experiment results, w/c ratio and testing method effect on chloride diffusion coefficient of concrete. As w/c ratio is increased, diffusion coefficient in concrete is also increased. Diffusion coefficient obtained by each testing method show the different value, respectively. Also, the content of free chloride in 7days curing concrete is increased as w/c ratio is increased.

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Experimental Determination of Friction Characteristics for Advanced High Strength Steel Sheets (초고강도강판 마찰특성의 실험적 규명)

  • Kim, N.J.;Keum, Y.T.
    • Transactions of Materials Processing
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    • v.22 no.4
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    • pp.223-228
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    • 2013
  • The friction coefficients of advanced high strength steel sheets were experimentally determined. In the friction test, the pulling and holding forces acting on the sheet for various friction conditions, such as lubricant viscosity, pulling speed, blank holding pressure, sheet surface roughness, and hardness of the sheet were measured and the friction coefficient was calculated based on Coulomb's friction law. While the friction coefficient, generally, decreases as the value of friction factor increases, the factor associated with the sheet surface roughness shows U shape behavior for the friction coefficient. Furthermore, the relationship between friction coefficient and the wear volume, which was computed for the roughness of both sheet surfaces and the friction area, is linearly proportional.

Analysis of Characteristics of All Solid-State Batteries Using Linear Regression Models

  • Kyo-Chan Lee;Sang-Hyun Lee
    • International journal of advanced smart convergence
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    • v.13 no.1
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    • pp.206-211
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    • 2024
  • This study used a total of 205,565 datasets of 'voltage', 'current', '℃', and 'time(s)' to systematically analyze the properties and performance of solid electrolytes. As a method for characterizing solid electrolytes, a linear regression model, one of the machine learning models, is used to visualize the relationship between 'voltage' and 'current' and calculate the regression coefficient, mean squared error (MSE), and coefficient of determination (R^2). The regression coefficient between 'Voltage' and 'Current' in the results of the linear regression model is about 1.89, indicating that 'Voltage' has a positive effect on 'Current', and it is expected that the current will increase by about 1.89 times as the voltage increases. MSE found that the mean squared error between the model's predicted and actual values was about 0.3, with smaller values closer to the model's predictions to the actual values. The coefficient of determination (R^2) is about 0.25, which can be interpreted as explaining 25% of the data.

Energy Conservation for Runoff and Soil Erosion on the Hillslope (산지사면의 유출 및 토양침식에 대한 에너지 보존)

  • Shin, Seung-Sook;Park, Sang-Deog;Cho, Jae-Woong;Hong, Jong-Sun
    • Proceedings of the Korea Water Resources Association Conference
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    • 2008.05a
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    • pp.234-238
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    • 2008
  • The energy conservation theory is introduced for investigating processes of runoff and soil erosion on the hillslope system changed vegetation condition by wildfire The rainfall energy, input energy consisted of kinetic and potential energy, is influenced by vegetation coverage and height. Output energy at the outlet of hillslope is decided as the kinetic energy of runoff and erosion soil, and mechanical work according to moving water and soil is influenced dominantly by the work rather than the kinetic energy. Relationship between output and input energy is possible to calculate the energy loss in the runoff and erosion process. The absolute value of the energy loss is controlled by the input energy size of rainfall because energy losses of runoff increase as many rainfall pass through the hillslope system. The energy coefficient which is dimensionless is defined as the ratio of input energy of rainfall to output energy of runoff water and erosion soil such as runoff coefficient. The energy coefficient and runoff coefficient showed the highest correlation coefficient with the vegetation coverage. Maximum energy coefficient is about 0.5 in the hillslope system. The energy theory for output energy of runoff and soil erosion is presented by the energy coefficient theory associated with vegetation factor. Also runoff and erosion soil resulting output energy have the relation of power function and the rates of these increase with rainfall.

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The relationship between prediction accuracy and pre-information in collaborative filtering system

  • Kim, Sun-Ok
    • Journal of the Korean Data and Information Science Society
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    • v.21 no.4
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    • pp.803-811
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    • 2010
  • This study analyzes the characteristics of preference ratings by dividing estimated values into four groups according to rank correlation coefficient after obtaining preference estimated value to user's ratings by using collaborative filtering algorithm. It is known that the value of standard error of skewness and standard error of kurtosis lower in the group of higher rank correlation coefficient This explains that the preference of higher rank correlation coefficient has lower extreme values and the differences of preference rating values. In addition, top n recommendation lists are made after obtaining rank fitting by using the result ranks of prediction value and the ranks of real rated values, and this top n is applied to the four groups. The value of top n recommendation is calculated higher in the group of higher rank correlation coefficient, and the recommendation accuracy in the group of higher rank correlation coefficient is higher than that in the group of lower rank correlation coefficient Thus, when using standard error of skewness and standard error of kurtosis in recommender system, rank correlation coefficient can be higher, and so the accuracy of recommendation prediction can be increased.

Relationship between Marital Cohesion : Adaptability and Communication (부부의 응집 및 적응과 의사소통의 관계 : 순환 모델의 곡선성 대 선형성)

  • 김득성
    • Journal of Families and Better Life
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    • v.11 no.2
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    • pp.30-39
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    • 1993
  • This study examined the relationship between marital cohesion adaptability and marital communication and especially tested the linear versus curvilinear hypothese with Circumplex Model. The subjects were 142 couples living in Pusan./ The data were analyzed using frequency one-way ANOVA and Pearson's correlation coefficient The major finding of this study were as follows: The relationship between the dimensions of cohesion adaptability and communica-tion was linear than curvilinear. High cohesion and high adaptability spouses were more effective communication than low cohesion and low adaptability.

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Improvement of the Method using the Coefficient of Variation for Automatic Multi-segmentation Method of a Rating Curve (수위-유량관계곡선의 자동구간분할을 위한 변동계수 활용기법의 개선)

  • Kim, Yeonsu;Kim, Jeongyup;An, Hyunuk;Jung, Kwansue
    • Journal of Korea Water Resources Association
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    • v.48 no.10
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    • pp.807-816
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    • 2015
  • In general, the water stage-discharge relationship curve is established based on the assumptions of linearity and homoscedasticity. However, the relationship between the water stage and discharge is affected from geomorphological factors, which violates the basic assumptions of the water stage-discharge relationship curve. In order to reduce the error due to the violations, the curve is divided into several sections based on the manager's judgement considering change of cross-sectional shape. In this research, the objective-splitting criteria of the curve is proposed based on the measured data without the subjective decision. First, it is assumed that the coefficient of variation follows the normal distribution. Then, if the newly calculated coefficient of variation is outside of the 95% confidential interval, the curve is divided. Namely, the groups is divided by the characteristics of the coefficient of variation and the reasonable criteria is provided for establishing a multi-segmented rating curve. To validate the proposed method, it was applied to the data generated by three artificial power functions. In addition, to confirm the applicability of the proposed method, it is applied to the water stage and discharge data of the Muju water stage gauging station and Sangegyo water stage gauging station. As a result, it is found that the automatically divided rating curve improves the accuracy and extrapolation accuracy of the rating curve. Finally, through the residual analysis using Shapiro-Wilk normality test, it is confirmed that the residual of water stage-discharge relationship curve tends to follow the normal distribution.

The loss coefficient for fluctuating flow through a dominant opening in a building

  • Xu, Haiwei;Yu, Shice;Lou, Wenjuan
    • Wind and Structures
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    • v.24 no.1
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    • pp.79-93
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    • 2017
  • Wind-induced fluctuating internal pressures in a building with a dominant opening can be described by a second-order non-linear differential equation. However, the accuracy and efficiency of the governing equation in predicting internal pressure fluctuations depend upon two ill-defined parameters: inertial coefficient $C_I$ and loss coefficient $C_L$, since $C_I$ determines the un-damped oscillation frequency of an air slug at the opening, while $C_L$ controls the decay ratio of the fluctuating internal pressure. This study particularly focused on the value of loss coefficient and its influence factors including: opening configuration and location, internal volumes, as well as wind speed and approaching flow turbulence. A simplified formula was presented to predict loss coefficient, therefore an approximate relationship between the standard deviation of internal and external pressures can be estimated using Vickery's approach. The study shows that the loss coefficient governs the peak response of the internal pressure spectrum which, in turn, will directly influence the standard deviation of the fluctuating internal pressure. The approaching flow characteristic and opening location have a remarkable effect on the parameter $C_L$.

A Study on the Application of Runway Friction Measurements (활주로 마찰계수 측정 및 적용에 관한 연구)

  • Noh, Kun-Soo
    • Journal of the Korean Society for Aviation and Aeronautics
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    • v.24 no.3
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    • pp.62-68
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    • 2016
  • According to the accident/incident reports of aircraft runway overruns and excursions, it generally shows runway friction reduction and aircraft braking capability deterioration are the basic causes due to adverse weather. Although surface of paved runway gets wet, it also should give good friction capability. If runway surface is worn due to long time usage and friction capability is reduced due to rubber accumulation or weather conditions(snow, rain, ice etc.), airport authorities should rapidly measure friction coefficient and give them to relevant persons through aeronautical information system and support safe takeoff and landing. Operation wise, these information of friction coefficient reduction should be lead to aircraft performance adjustments, but the data from manufacturer(performance manual) are airplane braking coefficient and the data from airport authorities are vehicle measured braking coefficient. But these two data are considered as the same meaning although the definite relationship between them is not clarified yet. So I am trying to search for the technical background of these two data and suggest reasonable method to use them efficiently.