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Energy Band Structure, Electronic and Optical properties of Transparent Conducting Nickel Oxide Thin Films on $SiO_2$/Si substrate

  • Denny, Yus Rama;Lee, Sang-Su;Lee, Kang-Il;Lee, Sun-Young;Kang, Hee-Jae;Heo, Sung;Chung, Jae-Gwan;Lee, Jae-Cheol
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.347-347
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    • 2012
  • Nickel Oxide (NiO) is a transition metal oxide of the rock salt structure that has a wide band gap of 3.5 eV. It has a variety of specialized applications due to its excellent chemical stability, optical, electrical and magnetic properties. In this study, we concentrated on the application of NiO thin film for transparent conducting oxide. The energy band structure, electronic and optical properties of Nickel Oxide (NiO) thin films grown on Si by using electron beam evaporation were investigated by X-Ray Photoelectron Spectroscopy (XPS), Reflection Electron Energy Loss Spectroscopy (REELS), and UV-Spectrometer. The band gap of NiO thin films determined by REELS spectra was 3.53 eV for the primary energies of 1.5 keV. The valence-band offset (VBO) of NiO thin films investigated by XPS was 3.88 eV and the conduction-band offset (CBO) was 1.59 eV. The UV-spectra analysis showed that the optical transmittance of the NiO thin film was 84% in the visible light region within an error of ${\pm}1%$ and the optical band gap for indirect band gap was 3.53 eV which is well agreement with estimated by REELS. The dielectric function was determined using the REELS spectra in conjunction with the Quantitative Analysis of Electron Energy Loss Spectra (QUEELS)-${\varepsilon}({\kappa},{\omega})$-REELS software. The Energy Loss Function (ELF) appeared at 4.8, 8.2, 22.5, 38.6, and 67.0 eV. The results are in good agreement with the previous study [1]. The transmission coefficient of NiO thin films calculated by QUEELS-REELS was 85% in the visible region, we confirmed that the optical transmittance values obtained with UV-Spectrometer is the same as that of estimated from QUEELS-${\varepsilon}({\kappa},{\omega})$-REELS within uncertainty. The inelastic mean free path (IMFP) estimated from QUEELS-${\varepsilon}({\kappa},{\omega})$-REELS is consistent with the IMFP values determined by the Tanuma-Powell Penn (TPP2M) formula [2]. Our results showed that the IMFP of NiO thin films was increased with increasing primary energies. The quantitative analysis of REELS provides us with a straightforward way to determine the electronic and optical properties of transparent thin film materials.

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Descriptions of Four New Species of Predatory Nematodes (Mononchida) From Korea (韓國産 捕食線蟲(Mononchida: Nematoda)의 4 新種 기재)

  • Choi, Young-Eoun;Khan, Zakaullah;Lee, Sung-Min
    • The Korean Journal of Soil Zoology
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    • v.4 no.2
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    • pp.89-100
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    • 1999
  • Four new and a known spacies of the order Mononchida were described and illustrated. Iotonchus obtusus sp. n. was 2.8 mm long, a=33, b=4.2, c=61, V=68%, buccal cavity=61${\times}$45 mm, and is characterized by having basally situated dorsal tooth, presence of vulval papillae and in having short, hemispherical tail with thick cuticle at terminus. Miconchus vulvapapillatum sp. . was 2.7-3.6 mm long, a=29-36, b=4.1-4.5, c=18.4-21, V=65-69%, buccal cavity=53-61${\times}$29-33 mm, spicules=132-137 mm, ventromedian supplements 28-31, and was characterized by having 5-8 pre- and post vulval papillae in contiguous series, and three pairs of vulval glands. Clarkus koreanus sp. n. was 1.1-1.3 mm long, a=27.5-28.8, b=3.5-3.9, c=12-14.5, V=60-64%, buccal cavity=24-28${\times}$13.5-15 mm, and was characterized by well offset lip region, amphids situated well below to dorsal tooth apex, and vulva elevated, with vulval flap. Coomansus ulsani sp. n. was 1.2-1.5 mm long, a=23.5-26, b=3.4-3.8, c=13.6-14.8, V=65-68%, buccal cavity=36-39${\times}$21-23 mm and was characterized by well offset lip region and a thin longitudinal ridge on vertical walls of stoma.

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On the Rotational Barrier of Organic Molecules (I). Role of Axial Carbon in Ethane (유기분자의 내부 회전장벽에 관한 이론적 연구 (제1보). 에탄에서의 중심 탄소의 역할)

  • Young Sik Kim;Hojing Kim
    • Journal of the Korean Chemical Society
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    • v.26 no.3
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    • pp.117-127
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    • 1982
  • In order to analyze the role of axial carbon atoms in rotational barrier of ethane, we take the carbonless ethane, as a model, which is made of six hydrogens in coordinates of ethane. The energy of the system is calculated by McWeeny's open-shell restricted Hartree-Foch selfconsistent-field (RHF-SCF) method, and the transition density on the staggered-to-eclipsed rotation is examined. As being expected, the eclipsed form of the model is more stable than the staggered one. Through the transition density comparison of this model and real ethane, it is found that the existence of the axial carbon atoms induces the electronic density to be diluted in the vicinity of protonic sites and to be attracted to the region of carbon atoms or further to C-C bond region as the barrier is traversed. This migration of electronic charge tell us that the barrier to the internal rotation of ethane originates from the fact that the magnitude of electronic energy depression is not large enough to offset the increased nuclear-nuclear repulsion on the staggered-to-eclipsed rotation.

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Bathymetry and Marine Geophysical Observations of the Ayu Trough, Southern Philippine Sea: Implications for Crustal Extension and Structure (남부 필리핀해 Ayu Trough에서의 지형과 선상지구물리 관측: 지각 확장과 구조 고찰)

  • Jung, Mee-Sook;Lee, Sang-Mook
    • Ocean and Polar Research
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    • v.24 no.3
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    • pp.179-187
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    • 2002
  • The Ayu Trough, located in the southern end of the Philippine Sea, represents a divergent boundary between the Philippine Sea and the Caroline Plates. A detailed geophysical survey was carried out in the Ayu Trough by R/V Onnuri. Topographically, the Ayu Trough resembles an slow spreading ridge. The trough can be divided into three sections: the south $(0^{\circ}-1^{\circ}30'N),\;middle\;(1^{\circ}30'-4^{\circ}N)$, and north $(4^{\circ}-6^{\circ}30'N)$. The seafloor in the middle section is characterized by features asymmetric with respect to the axis. These features were probably produced by NW-SE and NNW-SSE extensions and seem to support the argument that the opening of the Ayu Trough occurred in an oblique fashion. Farther south, a long transform fault but with a short offset defines the boundary between middle and southern sections. The axial depth increases a stepwise to the south of $1^{\circ}30'N$. A clear difference can be seen between the southern and middle sections with the latter exhibiting much higher mantle Bouguer anomaly values in the axial region. The anomaly indicates that the axial crust perhaps experienced a much higher degree of extension in the middle than in the southern section. The analyses of magnetic field data reveal that the region beyond 100km exhibits considerable variations, whereas the magnetic anomalies within 100km from the trough axis are very much subdued. This observation suggests that the opening of the Ayu Trough involved an initial stage of rifting of existing volcanic arcs, followed by production of new seafloor.

Calculation of Creep Coefficient for Concrete Structures Applying Time Step Analysis for Relative Humidity and Temperature (상대습도 및 온도에 대한 시간 단계 해석을 적용한 콘크리트 구조의 크리프계수 산정 )

  • Kyunghyun Kim;Ki Hyun Kim;Inyeol Paik
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.27 no.5
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    • pp.75-83
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    • 2023
  • As part of a study to analyze the excessive camber occurring in prestressed concrete railway bridges, this paper presents a calculation method and analysis results for the creep coefficient which defines the increase in camber of a concrete structure over time. Using the creep coefficient formula of the design code, the coefficient is obtained by applying the climatic conditions (relative humidity and temperature) of 12 regions in Korea. The effects of differences in climatic conditions by region and starting time of load on the creep coefficient are analyzed. In order to properly calculate the creep, most of which occurs in the early stages of loading, a detailed analysis is performed by applying a time step analysis method to consider varying climate conditions through loaded period. The creep coefficient obtained by applying the average climate conditions of the region is similar to the average of the creep coefficients obtained by time step analysis. Through time step analysis, it is shown that the offset and overlap effects of relative humidity and temperature on the creep coefficient and the climate effect at the time of initial loading can be appropriately represented.

The Efficient Edge Detection using Genetic Algorithms and Back-Propagation Network (유전자와 역전파 알고리즘을 이용한 효율적인 윤곽선 추출)

  • Park, Chan-Lan;Lee, Woong-Ki
    • The Transactions of the Korea Information Processing Society
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    • v.5 no.11
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    • pp.3010-3023
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    • 1998
  • GA has a fast convergence speed in searching the one point around optimal value. But it's convergence time increase in searching the region around optimal value because it has no regional searching mechanism. BP has the tendency to converge the local minimum because it has global searching mechanism. To overcome these problems, a method in which a genetic algorithm and a back propagation are applied in turn is proposed in this paper. By using a genetic algorithm, we compute optimal synaptic strength and offset value. And then, these values are fed to the input of the back propagation. This proposed method is superior to each above method in improving the convergence speed.

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Construction of Korean Space Weather Prediction Center: Storm Prediction Model

  • Kim, R.S.;Cho, K.S.;Moon, Y.J.;Yi, Yu;Choi, S.H.;Baek, J.H.;Park, Y.D.
    • Bulletin of the Korean Space Science Society
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    • 2008.10a
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    • pp.33.2-33.2
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    • 2008
  • Korea Astronomy and Space Science Institute (KASI) is developing an empirical model for Korean Space Weather Prediction Center (KSWPC). This model predicts the geomagnetic storm strength (Dst minimum) by using only CME parameters, such as the source location (L), speed (V), earthward direction (D), and magnetic field orientation of an overlaying potential field at CME source region. To derive an empirical formula, we considered that (1) the direction parameter has best correlation with the storm strength (2) west $15^{\circ}$ offset from the central meridian gives best correlation between the source location and the storm strength (3) consideration of two groups of CMEs according to their magnetic field orientation (southward or northward) provide better forecast. In this talk, we introduce current status of the empirical storm prediction model development.

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A Study on the Image Processing of Visual Sensor for Weld Seam Tracking in GMA Welding (GMA 용접에서 용접선 추적용 시각센서의 화상처리에 관한 연구)

  • 정규철;김재웅
    • Journal of Welding and Joining
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    • v.18 no.3
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    • pp.60-67
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    • 2000
  • In this study, we constructed a preview-sensing visual sensor system for weld seam tracking in GMA welding. The visual sensor consists of a CCD camera, a diode laser system with a cylindrical lens and a band-pass-filter to overcome the degrading of image due to spatters and/or arc light. To obtain weld joint position and edge points accurately from the captured image, we compared Hough transform method with central difference method. As a result, we present Hough transform method can more accurately extract the points and it can be applied to real time weld seam tracking. Image processing is carried out to extract straight lines that express laser stripe. After extracting the lines, weld joint position and edge points is determined by intersecting points of the lines. Although a spatter trace is in the image, it is possible to recognize the position of weld joint. Weld seam tracking was precisely implemented with adopting Hough transform method, and it is possible to track the weld seam in the case of offset angle is in the region of $\pm15^{\circ}$.

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Corridor Navigation of the Mobile Robot Using Image Based Control

  • Han, Kyu-Bum;Kim, Hae-Young;Baek, Yoon-Su
    • Journal of Mechanical Science and Technology
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    • v.15 no.8
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    • pp.1097-1107
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    • 2001
  • In this paper, the wall following navigation algorithm of the mobile robot using a mono vision system is described. The key points of the mobile robot navigation system are effective acquisition of the environmental information and fast recognition of the robot position. Also, from this information, the mobile robot should be appropriately controlled to follow a desired path. For the recognition of the relative position and orientation of the robot to the wall, the features of the corridor structure are extracted using the mono vision system, then the relative position, the offset distance and steering angle of the robot from the wall, is derived for a simple corridor geometry. For the alleviation of the computation burden of the image processing, the Kalman filter is used to reduce search region in the image space for line detection. Next, the robot is controlled by this information to follow the desired path. The wall following control scheme by the PD control scheme is composed of two control parts, the approaching control and the orientation control, and each control is performed by steering and forward-driving motion of the robot. To verify the effectiveness of the proposed algorithm, the real time navigation experiments are performed. Through the result of the experiments, the effectiveness and flexibility of the suggested algorithm are verified in comparison with a pure encoder-guided mobile robot navigation system.

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A Random Access Scheme Robust to Timing Offsets for Uplink OFDMA Systems (타이밍오차에 강건한 상향링크 OFDMA 시스템의 랜덤 액세스 기법)

  • Song, Hyun-Joo;Rim, Dae-Woon;Jeong, Byung-Jang;Noh, Tae-Gyun;Rim, Min-Joong
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.33 no.6A
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    • pp.659-665
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    • 2008
  • If ranging processes are not frequent in an uplink OFDMA system, the timing synchronization between base and mobile stations may not be maintained. Especially in the case of infrequent random accesses in a large cell, timing offsets can be considerable and the destroyed orthogonality of OFDMA signals may result in the degraded performance. This paper proposes a novel random access scheme for uplink OFDMA systems, which support the orthogonality of OFDMA signals with timing offsets by allowing a random access OFDMA symbol shorter than a normal one. In order to make uplink OFDMA systems robust to timing offsets, the proposed scheme inserts a zero-padding region in an OFDMA symbol.