• Title/Summary/Keyword: Reference Material

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A study on the SEI film formation as organic solvent decomposition of lithium ion batteries and its electrochemical behavior (리튬이온전지의 유기용매분해에 따른 SEI film형성과 전기화학적 거동에 관한 연구)

  • 김민성;구할본
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11a
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    • pp.545-549
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    • 2001
  • We have produced electrolyte solution out of 1.15M LiPF$\sub$6/ EC/EMC/DEC/PC(30/55/10/5 by vol%) as a reference, and at the same time, performed basic physical property test using a single solvent of 1.15M LiPF$\sub$6/DEC, DMC, EMC and a 2 component electrolyte solution of 1.15M LiPF$\sub$6/ EC/DEC(1/2 by vo%%) and PC/DEC(1/2 by vol%). Cyclic Voltammetry Analysis showed that, compared to existing carbonate organic solvent, the addition of DEC, DMC and EMC brought the de-decomposition peak of salt anion of PF$\sub$6/$\^$-/ and the solvent at lower oxidization potential of 2.3V, 0.7V and 2.1V(vs. Li/Li$\^$+/\`). In addition, a kinetics current peak, in which intercalation of Li$\^$+/ is proceeded at 750mv, 450mv(vs. Li/Li$\^$+/), was confirmed. These findings suggest that the DEC solvent decomposition occurred at an electric potential lower than that of oxidization of existing carbonate organic solvent. Through the impedance analysis, we checked electric charge transfer resistance(R$\sub$ct/) according to the electric potential of Li$\^$+/ intercalation at 750mv(vs. Li/Li$\^$+/), which was the same as the resistance (R$\sub$f/) and cyclic voltammetry of SEI film that was formed at Reference. By doing so, we found that the significant decrease of polarization resistance(R$\sub$p/) when Reference was played a part in the formation of compact SEI layer at the initial decomposition reaction.

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Structure of Station Class Lightning Arresters and Electrical Characteristics of ZnO Varistor Blocks (발변전용 피뢰기의 구조 및 ZnO 바리스터 소자의 전기적 특성)

  • Cho, Han-Goo;Han, Se-Won;Lee, Un-Yong;Yoon, Han-Soo;Choi, In-Hyuk
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07b
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    • pp.1158-1161
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    • 2004
  • This paper presents structural characteristics of station class lightning arresters and electrical characteristics of manufactured ZnO varistor blocks which are usable in those arresters. Three types of station class lightning arresters were investigated and those are a ceramic arrester, a FRP tube type polymer arrester, and a FRP rod type polymer arrester. Each arrester has merits and demerits with structural characteristics. In general, polymer arresters were made of silicon rubber for housing materials, FRP tube or rod for mechanical strength, ZnO blocks for electrical characteristics, and metal parts for electrical contact and the silicon rubber, the housing materials, was directly injected to the arrester module which was assembly composed of electrodes, ZnO blocks and FRP tube or rod, and to prevent the nonlinear electric fields distribution on upper parts of arresters, the grade ring was adopted to the upper electrodes. The reference voltage, nonlinear coefficient, residual voltage, and voltage ratio of manufactured ZnO varistors are 4.90kV, 50, 9.54kV, 1.94, respectively. Compared to designed electrical characteristics, the reference voltage was low for 600v and the voltage ratio was slightly high. However, the characteristics of discharge withstand was so excellent that the mechanical destruction does not occur at the impulse current of $8/20{\mu}s$ 10kA for 100 times.

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Application of Perturbation-based Sensitivity Analysis to Nuclear Characteristics (섭동론적 감도해석 이론의 원자로 핵특성에의 응용)

  • Byung Soo Lee;Mann Cho;Jeong Soo Han;Chung Hum Kim
    • Nuclear Engineering and Technology
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    • v.18 no.2
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    • pp.78-84
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    • 1986
  • An equation of material number density sensitivity coefficient is derived using first-order perturbation theory. The beginning of cycle of Super-Phenix I is taken as the reference system for this study. Effective multiplication factor of the reference system is defined as system response function and fuel enrichment and fuel effective density are chosen for the variation of reference input data since they are described by material number density which is a component of Boltzmann operator. The nuclear computational code system (KAERI-26 group cross section library/1DX/2DB/PERT-V) is employed for this calculation. Sensitivity coefficient of fuel enrichment on effective multiplication factor is 4.576 and sensitivity coefficient of effective fuel density on effective multiplication factor is 0.0756. This work shows that sensitivity methodology is lesser timeconsuming and gives more informations on important design parameters in comparison with the direct iterative calulation through large computer codes.

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Deriving the Effective Atomic Number with a Dual-Energy Image Set Acquired by the Big Bore CT Simulator

  • Jung, Seongmoon;Kim, Bitbyeol;Kim, Jung-in;Park, Jong Min;Choi, Chang Heon
    • Journal of Radiation Protection and Research
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    • v.45 no.4
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    • pp.171-177
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    • 2020
  • Background: This study aims to determine the effective atomic number (Zeff) from dual-energy image sets obtained using a conventional computed tomography (CT) simulator. The estimated Zeff can be used for deriving the stopping power and material decomposition of CT images, thereby improving dose calculations in radiation therapy. Materials and Methods: An electron-density phantom was scanned using Philips Brilliance CT Big Bore at 80 and 140 kVp. The estimated Zeff values were compared with those obtained using the calibration phantom by applying the Rutherford, Schneider, and Joshi methods. The fitting parameters were optimized using the nonlinear least squares regression algorithm. The fitting curve and mass attenuation data were obtained from the National Institute of Standards and Technology. The fitting parameters obtained from stopping power and material decomposition of CT images, were validated by estimating the residual errors between the reference and calculated Zeff values. Next, the calculation accuracy of Zeff was evaluated by comparing the calculated values with the reference Zeff values of insert plugs. The exposure levels of patients under additional CT scanning at 80, 120, and 140 kVp were evaluated by measuring the weighted CT dose index (CTDIw). Results and Discussion: The residual errors of the fitting parameters were lower than 2%. The best and worst Zeff values were obtained using the Schneider and Joshi methods, respectively. The maximum differences between the reference and calculated values were 11.3% (for lung during inhalation), 4.7% (for adipose tissue), and 9.8% (for lung during inhalation) when applying the Rutherford, Schneider, and Joshi methods, respectively. Under dual-energy scanning (80 and 140 kVp), the patient exposure level was approximately twice that in general single-energy scanning (120 kVp). Conclusion: Zeff was calculated from two image sets scanned by conventional single-energy CT simulator. The results obtained using three different methods were compared. The Zeff calculation based on single-energy exhibited appropriate feasibility.

A Study for the Fire Retardant-Characteristics of Expandable Graphite Composite Materials (팽창흑연을 사용한 복합재료의 난연 특성에 관한 연구)

  • Chun, Kwan-Ok;Rie, Dong-Ho
    • Journal of the Korean Society of Safety
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    • v.32 no.3
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    • pp.28-33
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    • 2017
  • In this study, the composite material of expandable graphite was made to the material development for improving such as a composite material of the sandwich panels or material properties of a fire door and was tested by the ISO 1182, ISO 5660-1(Cone calorimeter Method). For the test, the composite material of expandable graphite, what the expandable graphite ratio was increased by respectively 0g~30g, was classified A1,A2, A3, A4, and made to the test specimens. Through cone calorimeter test, peak heat release rate(HRR) and total heat release(THR), expanded thickness and expansion rate of each composite material of expandable graphite, and fire prone crack and mass loss rate after burning was measured. Thus, the effect of the addition of the expandable graphite and whether is suitable for reference as a fire retardant, was analyzed. Consequently the correlation of THR and fire retardant performance rate was confirmed.

Material Property-Estimate Technique Based on Natural Frequency for Updating Finite Element Model of Orthotropic Beams

  • Kim, Kookhyun;Park, Sungju;Lee, Sangjoong;Hwang, Seongjun;Kim, Sumin;Lee, Yonghee
    • Journal of Ocean Engineering and Technology
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    • v.34 no.6
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    • pp.481-488
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    • 2020
  • Composite materialsuch as glass-fiber reinforced plastic and carbon-fiber reinforced plastic (CFRP) shows anisotropic property and have been widely used for structural members and outfitings of ships. The structural safety of composite structures has been generally evaluated via finite element analysis. This paper presents a technique for updating the finite element model of anisotropic beams or plates via natural frequencies. The finite element model updates involved a compensation process of anisotropic material properties, such as the elastic and shear moduli of orthotropic structural members. The technique adopted was based on a discrete genetic algorithm, which is an optimization technique. The cost function was adopted to assess the optimization problem, which consisted of the calculated and referenced low-order natural frequencies for the target structure. The optimization process was implemented with MATLAB, which includes the finite element updates and the corresponding natural frequency calculations with MSC/NASTRAN. Material properties of a virtual cantilevered orthotropic beam were estimated to verify the presented method and the results obtained were compared with the reference values. Furthermore, the technique was applied to a cantilevered CFRP beam to successfully estimate the unknown material properties.

Radioimmunoassay Using Quality Control Materials BIO-RAD of the Suggestions for Setting Acceptable Range (BIO-RAD 정도관리 물질을 이용한 방사면역측정법의 Acceptable Range 설정에 대한 제언)

  • Park, Hee-Won;Kim, Tae-Hoon;Roh, Gyeong-Un;Kim, Hyun-Joo
    • The Korean Journal of Nuclear Medicine Technology
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    • v.16 no.1
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    • pp.108-114
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    • 2012
  • Purpose: Immunosorbent assay most commonly used in the laboratory and commercial third-party quality control material is a substance that provided by BIO-RAD. However, in Reference Sheet by radioimmunoassay test kit or a measuring device for the mention of Acceptable Range is somewhat lacking. Radioimmunoassay for the inspection of test results by setting Acceptable Range to increase the objectivity of the recommendations on the data accumulated by the manufacturer listed in the Reference Sheet is to be issued. Materials and Methods : In our hospital since 2009 partially BIO-RAD using quality control materials in 2011, excluding certain items, some items were most of the BIO-RAD third-party quality control materials are used. Thus, internal quality control data accumulated BIO-RAD's Unity Real Time program by using the items were measured. Results : BIO-RAD using quality control material items were about 50 of the 20 Point Data averages, standard deviations, variation coefficients were calculated to measure the Acceptable Range of kit, automated immunoassay attributed Roche Elecsys / E170 / cobas e Systems the measures and compared. Conclusions : BIO-RAD QC materials commonly used hospital and peer group by setting the measurement kit, suitable for laboratory equipment for radioimmunoassay of Acceptable Range manufacturer recommendation to increase the objectivity of the test results by national and international recognition for radioimmunoassay should seek to increase.

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Development of Surface Myoelectric Sensor for Myoelectric Hand Prosthesis

  • Choi, Gi-Won;Moon, In-Hyuk;Sung, So-Young;Lee, Mynug-Joon;Chu, Jun-Uk;Mun, Mu-Seong
    • 제어로봇시스템학회:학술대회논문집
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    • 2005.06a
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    • pp.1268-1271
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    • 2005
  • This paper proposes a compact-sized surface myoelectric sensor for myoelectric hand prosthesis. To fit the surface myoelectric sensor in the socket of the myoelectric hand prosthesis, the sensor should be a compact size. The surface myoelectric sensor is composed of a skin interface and a single processing circuit that are mounted on a single package. Since the skin interface has one reference and two input electrodes, and the reference electrode is located in middle of two input electrodes, we propose two types of sensors with the circle- and bar-shaped reference electrode, but all input electrodes are the bar-shaped. The metal material used for the electrodes is the stainless steel (SUS440) that endures sweat and wet conditions. Considering conduction velocity and median frequency of the myoelectric signal, we select the inter-electrode distance (IED) between two input electrodes as 18mm, 20mm, and 22 mm. The signal processing circuit consists of a differential amplifier with band pass filter, a band rejection filter for rejecting 60Hz power-line noise, amplifiers, and a mean absolute value circuit. We evaluate the proposed sensor from the output characteristics according to the IED and the shape of the reference electrode. From the experimental results we show the surface myoelectric sensor with the 18mm IED and the bar-shaped reference electrode is suitable for the myoelectric hand prosthesis.

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Characterizing a Full Spectrum of Physico-Chemical Properties of Ginsenosides Rb1 and Rg1 to Be Proposed as Standard Reference Materials

  • Kim, Il-Woung;Hong, Hee-Do;Choi, Sang-Yoon;Hwang, Da-Hye;Her, Youl;Kim, Si-Kwan
    • Journal of Ginseng Research
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    • v.35 no.4
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    • pp.487-496
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    • 2011
  • Good manufacturing practice (GMP)-based quality control is an integral component of the common technical document, a formal documentation process for applying a marketing authorization holder to those countries where ginseng is classified as a medicine. In addition, authentication of the physico-chemical properties of ginsenoside reference materials, and qualitative and quantitative batch analytical data based on validated analytical procedures are prerequisites for certifying GMP. Therefore, the aim of this study was to propose an authentication process for isolated ginsenosides $Rb_1$ and $Rg_1$ as reference materials (RM) and for these compounds to be designated as RMs for ginseng preparations throughout the world. Ginsenoside $Rb_1$ and $Rg_1$ were isolated by Diaion HP-20 adsorption chromatography, silica gel flash chromatography, recrystallization, and preparative HPLC. HPLC fractions corresponding to those two ginsenosides were recrystallized in appropriate solvents for the analysis of physico-chemical properties. Documentation of the isolated ginsenosides was made according to the method proposed by Gaedcke and Steinhoff. The ginsenosides were subjected to analyses of their general characteristics, identification, purity, content quantitation, and mass balance tests. The isolated ginsenosides were proven to be a single compound when analyzed by three different HPLC systems. Also, the water content was found to be 0.940% for $Rb_1$ and 0.485% for $Rg_1$, meaning that the net mass balance for ginsenoside $Rb_1$ and $Rg_1$ were 99.060% and 99.515%, respectively. From these results, we could assess and propose a full spectrum of physicochemical properties for the ginsenosides $Rb_1$ and $Rg_1$ as standard reference materials for GMP-based quality control.

A Study on the Frictional Characteristics of B$_{4}$C Added Cu Base Sintered Friction Material (B$_{4}$C의 첨가에 따른 동계소결합금 마찰재의 마찰특성 변화에 관한 연구)

  • 정동윤;김기열;조정환
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 1996.04a
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    • pp.99-107
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    • 1996
  • Examined in this paper is the effect of B$_{4}$C addition on the frictional characteristics of Cu-Sn based sintered friction material. For the specimens 1%, 2% and 4% of B$_{4}$C were added into the reference material. A pin-on-disk type friction tester was used to measure the friction and wear with respect to the surface temperature and sliding distance. Wear mechanism of each specimen is analyzed in the view point of the oxide film formation. The specimen containing 4% of B$_{4}$C showed stable friction and low wear since the oxide film was sustained up to higher surface temperature ranges.

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