• Title/Summary/Keyword: Reductive

검색결과 472건 처리시간 0.032초

Acyclic Eposidations (II)

  • Kim, Deuk-Joon
    • Archives of Pharmacal Research
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    • 제5권2호
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    • pp.109-110
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    • 1982
  • Conveersion of vinylogous glycidic ester 1 to 2 by a stereoselective acyclic allylic epoxidation will be presented.

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거주지역의 정주성 향상을 위한 연구 (I) - 미래 주거생활주기에 따른 대구지역 대학생의 지역선호와 가치를 중심으로 - (A Study for the Elevation of Settlement in Residential District(I))

  • 임소연;김재경;안옥희
    • 한국주거학회논문집
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    • 제10권4호
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    • pp.1-10
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    • 1999
  • The purpose of this study was to investigate the environmental factors having a influence on the preference of residential district and to furnish basic information for the successful settlement. For the purpose, residential preference and values on the residential district were estimated according to the housing life cycle. Data were collected through questionnaires designed for this study, and the objects of this research were university students. To analyze the data were used spsswin program. The major results were as follows. 1. According to the housing life cycle, there were significant differences in the preference of the residential district, living area and housing type in the future. Metropolitan and seoul, residential area and commercial area, apartment, office-hotel and row house were preferred in the housing formative. In the stable period, seoul and metropolitan, tower apartment, residential area were preferred. But in the housing reductive period, they preferred a green zone in the rural, the detached house. 2. The degree of consideration of living convenience facilities was high in the housing formative period. Both education-leisure, business facilities and marketing facilities were highly valuated in the housing stable period. But the value of welfare facilities was high in the housing reductive period. 3. The 4 dimensions of values in environmental conditions were extracted through factor analysis. They were natural, human, social, and economic factors. According to the housing life cycle, there were significant differences in factors being considered as the environmental conditions. The values of human and economic factors were high in the housing formative and stable period. Natural factor were highly considered in the housing reductive period.

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혐기성탈염소화 혼합균주에서 산소 노출이 탈염소화 및 수소발생 발효에 미치는 영향 (Effects of Short-Term Oxygen Exposure on Anaerobic Reductive Dechlorination and Formate Fermentation by Evanite Culture)

  • 홍의전;박선화;임종환;안홍일;김남희;이석우;김영
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제15권6호
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    • pp.114-121
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    • 2010
  • Oxygen sensitivity and substrate requirement have been known as possible reasons for the intricate growth of Dehalococcoides spp. and limiting factors of for routinely applying bioaugmentation using anaerobic Dehalococcoides-containing microbes for remediating chlorinated organic compounds. To explore the effect of the short-term exposure of the short-term exposure of oxygen on Dehalococcoides capability, dechlorination performance, and hydrogen production fermentation from formate, an anaerobic reductive dechlorination mixed-culture (Evanite culture) including dehalococcoides spp. was in this study. In the results, once the mixed-culture were exposed to oxygen, trichloroethylene (TCE) degradation rate decreased and it was not fully recovered even addition of excess formate for 40 days. In contrast, hydrogen was continuously produced by hydrogen-fermentation process even under oxygen presence. The results indicate that although the oxygen-exposed cells cannot completely dechlorinate TCE to ethylene (ETH), hydrogen fermentation process was not affected by oxygen presence. These results suggest that dechlorinating microbes may more sensitive to oxygen than fermenting microbes, and monitoring dechlorinators activity may be critical to achieve an successful remediation of a TCE contaminated-aquifer through bioaugmentation using Dehalococcoides spp..

암 치료 표적으로의 NAD(P)H Quinone Oxidoreductase 1 (NQO1) (NAD(P)H Quinone Oxidoreductase 1 (NQO1) as a Cancer Therapeutic Target)

  • 박은정;권택규
    • 생명과학회지
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    • 제24권1호
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    • pp.98-103
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    • 2014
  • NQO1은 플라보 단백질 계통의 2 전자 환원 효소이며 NADH 또는 NADPH를 보조인자로 quinone 계통의 화합물을 hydroquinone으로 환원 한다. 암에서 NQO1은 그에 상응하는 정상 조직과 비교하였을 때 비교적 높은 발현을 나타낸다. NQO1의 다양한 기능 중 quinone 물질 대사는 두 가지 형태의 상반되는 기능을 가진다. 이것은 quinone으로부터 전환된 hydroquinone의 상태적 안정성과 불안정성에 기인하며, 불안정한 hydroquinone의 생성은 산화적 손상 야기 및 DNA 손상은 세포의 운명을 바꾸어 놓게 된다. 따라서 암에서 그 발현이 높은 NQO1을 표적으로 작용하는 생체환원 물질은 암 세포 사멸을 강하게 유도하게 되어 암 치료의 가능성을 보여주고 있다. 항암 표적 분자로서 NQO1 특징과 NQO1을 통해 작용하는 생체환원물질 ${\beta}$-lapachone의 항암 효과와 기전에 대하여 살펴보았다.

오산화바나듐의 수소 환원에 의한 이산화바나듐의 제조 및 열변색 특성 (Preparation of Vanadium Dioxide by Hydrogen Reduction of Vanadium Pentoxide and its Thermochromic Properties)

  • 최승훈;이춘부
    • 자원리싸이클링
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    • 제26권5호
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    • pp.61-66
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    • 2017
  • 이산화바나듐은 적외선 투과를 차단하거나 창을 통해 건물 내부열 손실을 막아주는 광선택적 유리코팅 소재로 알려졌는데, 본 연구에서 이와 같은 열변색 특성을 가진 이산화바나듐을 수소와의 환원반응을 통하여 제조하는 방법에 대해 연구하였다. 환원반응에 의한 이산화바나듐의 제조는 반응이 쉽게 진행되고, 스퍼터, 빔 증발기 등과 같은 반도체 장비가 필요 없이 공정이 단순하고 대량생산에 용이한 장점을 갖고 있는데, 본 연구에서 수소와의 환원반응에 대한 반응온도, 반응시간, 환원가스의 농도 및 사후 열처리 조건, 첨가제로서 텅스텐의 첨가 등에 대해 실험을 수행하였으며, 최적조건을 도출하여 제조된 이산화바나듐 분말의 특성과 열변색 특성에 대해 조사하였다. 본 연구를 통해 개발된 이산화바나듐이 전자소재 및 에너지 저감 소재로서 많이 활용될 것으로 기대되고 있다.