• Title/Summary/Keyword: Reductive

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Acyclic Eposidations (II)

  • Kim, Deuk-Joon
    • Archives of Pharmacal Research
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    • v.5 no.2
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    • pp.109-110
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    • 1982
  • Conveersion of vinylogous glycidic ester 1 to 2 by a stereoselective acyclic allylic epoxidation will be presented.

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A Study for the Elevation of Settlement in Residential District(I) (거주지역의 정주성 향상을 위한 연구 (I) - 미래 주거생활주기에 따른 대구지역 대학생의 지역선호와 가치를 중심으로 -)

  • 임소연;김재경;안옥희
    • Journal of the Korean housing association
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    • v.10 no.4
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    • pp.1-10
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    • 1999
  • The purpose of this study was to investigate the environmental factors having a influence on the preference of residential district and to furnish basic information for the successful settlement. For the purpose, residential preference and values on the residential district were estimated according to the housing life cycle. Data were collected through questionnaires designed for this study, and the objects of this research were university students. To analyze the data were used spsswin program. The major results were as follows. 1. According to the housing life cycle, there were significant differences in the preference of the residential district, living area and housing type in the future. Metropolitan and seoul, residential area and commercial area, apartment, office-hotel and row house were preferred in the housing formative. In the stable period, seoul and metropolitan, tower apartment, residential area were preferred. But in the housing reductive period, they preferred a green zone in the rural, the detached house. 2. The degree of consideration of living convenience facilities was high in the housing formative period. Both education-leisure, business facilities and marketing facilities were highly valuated in the housing stable period. But the value of welfare facilities was high in the housing reductive period. 3. The 4 dimensions of values in environmental conditions were extracted through factor analysis. They were natural, human, social, and economic factors. According to the housing life cycle, there were significant differences in factors being considered as the environmental conditions. The values of human and economic factors were high in the housing formative and stable period. Natural factor were highly considered in the housing reductive period.

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Effects of Short-Term Oxygen Exposure on Anaerobic Reductive Dechlorination and Formate Fermentation by Evanite Culture (혐기성탈염소화 혼합균주에서 산소 노출이 탈염소화 및 수소발생 발효에 미치는 영향)

  • Hong, Ui-Jeon;Park, Sun-Hwa;Lim, Jong-Hwan;Ahn, Hong-Il;Kim, Nam-Hee;Lee, Suk-Woo;Kim, Young
    • Journal of Soil and Groundwater Environment
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    • v.15 no.6
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    • pp.114-121
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    • 2010
  • Oxygen sensitivity and substrate requirement have been known as possible reasons for the intricate growth of Dehalococcoides spp. and limiting factors of for routinely applying bioaugmentation using anaerobic Dehalococcoides-containing microbes for remediating chlorinated organic compounds. To explore the effect of the short-term exposure of the short-term exposure of oxygen on Dehalococcoides capability, dechlorination performance, and hydrogen production fermentation from formate, an anaerobic reductive dechlorination mixed-culture (Evanite culture) including dehalococcoides spp. was in this study. In the results, once the mixed-culture were exposed to oxygen, trichloroethylene (TCE) degradation rate decreased and it was not fully recovered even addition of excess formate for 40 days. In contrast, hydrogen was continuously produced by hydrogen-fermentation process even under oxygen presence. The results indicate that although the oxygen-exposed cells cannot completely dechlorinate TCE to ethylene (ETH), hydrogen fermentation process was not affected by oxygen presence. These results suggest that dechlorinating microbes may more sensitive to oxygen than fermenting microbes, and monitoring dechlorinators activity may be critical to achieve an successful remediation of a TCE contaminated-aquifer through bioaugmentation using Dehalococcoides spp..

NAD(P)H Quinone Oxidoreductase 1 (NQO1) as a Cancer Therapeutic Target (암 치료 표적으로의 NAD(P)H Quinone Oxidoreductase 1 (NQO1))

  • Park, Eun Jung;Kwon, Taeg Kyu
    • Journal of Life Science
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    • v.24 no.1
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    • pp.98-103
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    • 2014
  • NAD(P)H quinone oxidoreductase 1 (NQO1) is a flavoprotein that catalyzes the two electron reduction of diverse substrates, including quinones. It uses NADH or NADPH as a cofactor for enzymatic machinery. In the metabolism of quinones, NQO1 has two conflicting functions because of the different stability of converted hydroquinones. The stable form of hydroquinone is excreted from cells by conjugation with glutathione or glucuronic acid. The unstable form of hydroquinone induces cell death by induction of oxidative stress and DNA damage. Certain quinones known as bio-reductive agents have a cytotoxic function following reduction by NQO1. Bio-reductive agents, such as ${\beta}$-lapachone or mitomycin C, induce the depletion of NAD(P)H and the generation of oxidative stress in an NQO1-dependent manner. NQO1 is highly expressed in several cancer tissues. Therefore, NQO1 is a good therapeutic target for cancer treatment with bio-reductive agents.

Preparation of Vanadium Dioxide by Hydrogen Reduction of Vanadium Pentoxide and its Thermochromic Properties (오산화바나듐의 수소 환원에 의한 이산화바나듐의 제조 및 열변색 특성)

  • Choi, Seung Hoon;Lee, Chun Boo
    • Resources Recycling
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    • v.26 no.5
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    • pp.61-66
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    • 2017
  • Vanadium Dioxide has been investigated for use as a "spectrally-selective" window coating to block infrared transmission and reduce the loss of building interior heat through windows. The preparation of thermochromic $VO_2$ powder by the reductive reaction with hydrogen was studied. The reductive reaction method has many advantages of easy and mass production of $VO_2$ powder according to controlled reaction without semi-conductor equipments like sputter and beam evaporator. The reaction temperature, time, concentration of reductive gas, post-annealing condition and W addition as dopant would affect the characterization of $VO_2$ powder and its thermochromism. Many applications for electrical device and energy-saving technologies is expected.