• Title/Summary/Keyword: Reduction process

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Effects of Initial Responses in Steps for the Release Accidents of Hydrofluoric Acid (불산수용액 누출사고에 대한 초기대응 단계별 영향)

  • Choi, Jae Sik;Choi, Jae U;Shim, Ju Yong;Lee, Mu Chul
    • Korean Chemical Engineering Research
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    • v.59 no.1
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    • pp.68-76
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    • 2021
  • As hazardous chemicals are releasing in process industries such as chemical & petro-chemical plants, the importance of initial responses has been always emphasized. However, little attention of quantitative analysis of the consequence by different initial responses during releasing of the chemicals has been done. The main objective of current paper is to investigate the effects of initial responses for the release accidents of hydrofluoric acid. For this, a simplified equation that can easily calculate the effect distance by varying concentrations of hydrofluoric acid was firstly deduced. In addition, a causal loops for the initial response steps using the system dynamics technique was constructed during release of 50% hydrofluoric acid. The effect distances according to different scenarios of the initial actions were also quantitatively analyzed by applying the simplified equation to the causal map. As a result, the highest reduction rate on the maximum effect distance was obtained with 'start time of action after leak detection' being about 87% while the lowest was 'arrival time of professional response team' being about 50%, as expected. It is expected that the results gained from the current study can be helpful as of basics of the initial response to the workplace, dealing with the hydrofluoric acid.

Measurement of Sulfur Dioxide Concentration Using Wavelength Modulation Spectroscopy With Optical Multi-Absorption Signals at 7.6 µm Wavelength Region (7.6 µm 파장 영역의 다중 광 흡수 신호 파장 변조 분광법을 이용한 이산화황 농도 측정)

  • Song, Aran;Jeong, Nakwon;Bae, Sungwoo;Hwang, Jungho;Lee, Changyeop;Kim, Daehae
    • Clean Technology
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    • v.26 no.4
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    • pp.293-303
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    • 2020
  • According to the World Health Organization (WHO), air pollution is a typical health hazard, resulting in about 7 million premature deaths each year. Sulfur dioxide (SO2) is one of the major air pollutants, and the combustion process with sulfur-containing fuels generates it. Measuring SO2 generation in large combustion environments in real time and optimizing reduction facilities based on measured values are necessary to reduce the compound's presence. This paper describes the concentration measurement for SO2, a particulate matter precursor, using a wavelength modulation spectroscopy (WMS) of tunable diode laser absorption spectroscopy (TDLAS). This study employed a quantum cascade laser operating at 7.6 ㎛ as a light source. It demonstrated concentration measurement possibility using 64 multi-absorption lines between 7623.7 and 7626.0 nm. The experiments were conducted in a multi-pass cell with a total path length of 28 and 76 m at 1 atm, 296 K. The SO2 concentration was tested in two types: high concentration (1000 to 5000 ppm) and low concentration (10 ppm or less). Additionally, the effect of H2O interference in the atmosphere on the measurement of SO2 was confirmed by N2 purging the laser's path. The detection limit for SO2 was 3 ppm, and results were compared with the electronic chemical sensor and nondispersive infrared (NDIR) sensor.

Applying a smart livestock system as a development strategy for the animal life industry in the future: A review (미래 동물생명산업 발전전략으로써 스마트축산의 응용: 리뷰)

  • Park, Sang-O
    • Journal of the Korean Applied Science and Technology
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    • v.38 no.1
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    • pp.241-262
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    • 2021
  • This paper reviewed the necessity of a information and communication technology (ICT)-based smart livestock system as a development strategy for the animal life industry in the future. It also predicted the trends of livestock and animal food until 2050, 30 years later. Worldwide, livestock raising and consumption of animal food are rapidly changing in response to population growth, aging, reduction of agriculture population, urbanization, and income growth. Climate change can change the environment and livestock's productivity and reproductive efficiencies. Livestock production can lead to increased greenhouse gas emissions, land degradation, water pollution, animal welfare, and human health problems. To solve these issues, there is a need for a preemptive future response strategy to respond to climate change, improve productivity, animal welfare, and nutritional quality of animal foods, and prevent animal diseases using ICT-based smart livestock system fused with the 4th industrial revolution in various aspects of the animal life industry. The animal life industry of the future needs to integrate automation to improve sustainability and production efficiency. In the digital age, intelligent precision animal feeding with IoT (internet of things) and big data, ICT-based smart livestock system can collect, process, and analyze data from various sources in the animal life industry. It is composed of a digital system that can precisely remote control environmental parameters inside and outside the animal husbandry. The ICT-based smart livestock system can also be used for monitoring animal behavior and welfare, and feeding management of livestock using sensing technology for remote control through the Internet and mobile phones. It can be helpful in the collection, storage, retrieval, and dissemination of a wide range of information that farmers need. It can provide new information services to farmers.

Evaluation of Compressive Strength and Freeze-thaw Resistance Properties of Concrete using Superabsorbent Polymer (고 흡수성 폴리머를 혼입한 콘크리트의 압축 강도 및 동결융해 저항성 평가)

  • Kim, Il-Sun;Choi, So-Yeong;Yang, Eun-Ik
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.24 no.5
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    • pp.86-94
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    • 2020
  • When the Superabsorbent Polymer (SAP) is added into concrete, the slump decreases rapidly, deteriorating the workability, the internal curing effect can be obtained through the water absorption and discharge process, and the internal voids of the concrete are increased. In this study, the effects of internal curing and voids were evaluated by evaluating the compressive strength, freeze-thaw resistance, and chloride penetration resistance of SAP-adding concrete that secured workability using a water reducing agent. Also, the internal curing effect of SAP was evaluated by dividing the curing conditions of concrete into water curing and sealed curing. From the result, as the SAP adding ratio increased, the amount of water reducing agent increased, and as for the compressive strength, the SAP adding ratio of 1.5% showed the greatest compressive strength. In particular, in the case of sealed curing showed higher compressive strength than the water curing. It is considered that the compressive strength increased due to the reduction of the effective water-cement ratio and the internal curing effect. Adding 1.0~1.5% of SAP improved the freeze-thaw resistance similar to the case of adding the AE agent, and the addition of more than 1.0% of SAP improved the chloride penetration resistance. The optimal adding ratio of SAP is 1.5%, and the adding ratio of 2.0% or more adversely affects the compressive strength and freeze-thaw resistance.

A Study on the Installation of a Sewage Separator Pipe inside an Existing Combined Sewer System for CSO Control (기존 합류식 하수관거에 CSO 제어를 위한 하수분리관의 설치에 관한 연구)

  • Guerra, Heidi B.;Kim, Youngchul
    • Journal of Wetlands Research
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    • v.23 no.1
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    • pp.85-93
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    • 2021
  • Sewage separation which often involves installing a new pipe to separate wastewater flow from stormwater runoff flow can be costly and depends highly on its feasibility in a site. To be able to develop a potentially more economical alternative that can also lessen major road traffic disturbance during this process, a different approach where a smaller sewage separator pipe is installed inside an existing combined sewer pipe was investigated. A small-scale of a box sewer and the proposed sewage separator pipe was constructed in the laboratory to observe and compare the deposition of solids and other solid-associated major pollutants at different flow rates. In addition, three-dimensional flow simulations considering five different scenarios were conducted using Ansys Fluent to observe the effect of the proposed sewage separator pipe to the hydraulic flow if installed inside the combined sewer pipe. Results revealed that the deposition of TSS, TCOD, TN, and TP were reduced by at least 60% when the wastewater was conveyed by the sewage separator pipe instead of the combined sewer pipe. Moreover, the flow simulations conducted showed that there was little to no major disturbance in hydraulic flow and velocity distribution when the sewage separator was installed inside a straight pipe and even at pipe transitions such as intersections, turns, and drop in elevation. Considering the pipe dimensions and the results of the study, the proposed approach can be promising in terms of reduction in pollutant deposition without a major effect on the hydraulic flow. Further investigation and cost-analysis should be done in the future to support these preliminary findings and help alleviate the problems caused by combined sewer overflows by introducing an alternative approach.

Verification of Weight Effect Using Actual Flight Data of A350 Model (A350 모델의 비행실적을 이용한 중량 효과 검증)

  • Jang, Sungwoo;Yoo, Jae Leame;Yo, Kwang Eui
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.50 no.1
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    • pp.13-20
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    • 2022
  • Aircraft weight is an important factor affecting performance and fuel efficiency. In the conceptual design stage of the aircraft, the process of balancing cost and weight is performed using empirical formulas such as fuel consumption cost per weight in estimating element weight. In addition, when an airline operates an aircraft, it promotes fuel efficiency improvement, fuel saving and carbon reduction through weight management activities. The relationship between changes in aircraft weight and changes in fuel consumption is called the cost of weight, and the cost of weight is used to evaluate the effect of adding or reducing weight to an aircraft on fuel consumption. In this study, the problems of the existing cost of weight calculation method are identified, and a new cost of weight calculation method is introduced to solve the problem. Using Breguet's Range Formula and actual flight data of the A350-900 aircraft, two weight costs are calculated based on take-off weight and landing weight. In conclusion, it was suggested that it is reasonable to use the cost of weight based on the take-off weight and the landing weight for other purposes. In particular, the cost of weight based on the landing weight can be used as an empirical formula for estimating element weight and optimizing cost and weight in the conceptual design stage of similar aircraft.

Odor Reduction of Pig Wastewater Using Magnesia (in-situ test) (마그네시아를 이용한 돈분 폐수의 악취 저감(현장 시험))

  • Bae, Su Ho;Ryoo, Keon Sang
    • Journal of the Korean Chemical Society
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    • v.66 no.3
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    • pp.202-208
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    • 2022
  • In this study, we tried to obtain the optimal conditions to reduce odors generated from pig wastewater using magnesia (MgO) through in-situ test after producing a reactor for removing odors. For this purpose, the filling amount of magnesia, the injection amount of pig wastewater, the aeration method, the aeration amount and the aeration time were considered. The field experiment was conducted at Cheongwoon Livestock Farm, which has a pig wastewater reservoir. As the amount of magnesia added to the weight of wastewater (500 kg) increases, the amount of ammonia (NH3) and hydrogen sulfide (H2S) generated tended to gradually decrease. As a result of the test, ammonia and hydrogen sulfide in the pig wastewater decreased up to 65% and 77%, respectively, for 2 days aeration after 0.8% of magnesia was added to the reaction tank. The initial pH of the pig wastewater in the reactor was 8.2, and the pH was found to be 9.2 when magnesia was added up to 0.8%. In the light of this trend, it can be known that magnesia gradually increases the pH in the pig wastewater and makes it weakly alkaline. As the pH increases, part of the ammonia gas present in the pig wastewater vaporizes into the air and the remaining part is removed by precipitation after chemical bonding with dissolved magnesium ions and phosphate ions. In order to remove the odor of pig wastewater and turn it into compost, most of the existing livestock farms go through a six-month aeration process using microorganisms. In contrast, the current study proved the effect of removing odors from pig wastewater within 2 days through chemical reactions that do not affect microbial activity.

Effect of Teaching Program for Model Ignorance on the Perception and Teaching Practice of Pre-service Chemistry Teachers (모델 이그노런스 교수프로그램이 예비화학교사의 인식 및 교수 실행에 미치는 효과)

  • Jeon, Eunsun;Paik, Seoung-Hey
    • Journal of the Korean Chemical Society
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    • v.66 no.3
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    • pp.228-242
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    • 2022
  • In this study, the educational effect was investigated by providing a teaching program so that pre-service chemistry teachers could apply model ignorance education to teacher training practice. The teaching program was constructed in consideration of the sensemaking concept proposed in the study of Odden & Russ and the process of teacher sensemaking proposed by Asli et al. The subjects of this study were 23 pre-service teachers in the 4th year of chemistry education department at a teacher training university in the central region of Korea. In order to form a sensemaking for the model's ignorance education, the teaching program consisted of four stages; the initial idea generation stage, cognition of model's ignorance stage in a inconsistent situation, the lesson strategy construction stage for model ignorance education, and lesson plan & practice stage during teacher training practice. In the first stage of this program, pre-service teachers' initial ideas about the Arrhenius model and Bronsted-Lowry model of acid-base reaction, and the electron transfer model of the oxidation-reduction reaction were investigated. In the second stage, inconsistant situation that cannot be explained by the knowledge of model was presented to recognize the ignorance of the model. The third stage was to develop the teaching ability of model's ignorance through textbook analysis and lesson strategy composition activities. As a final stage, during the teacher training practice, the pre-service teachers were asked to plan and practice the implementation of the model's ignorance education. Through the teaching program to form a sensemaking for ignorance education of the models, pre-service teachers had come to recognize the ignorance of the model, acquired ability to organize and execute lesson strategies reflecting model ignorance, and acquired recognition of the educational value and necessity of teaching the ignorance of models.

A Qualitative Exploration of Intentions of Financial Chatbot Service (금융 챗봇 서비스의 사용 의도에 대한 질적 탐색)

  • Kim, Wonil;Yoon, Hyun Shik
    • Journal of Digital Convergence
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    • v.19 no.11
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    • pp.181-199
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    • 2021
  • Recently, financial companies are promoting chatbot services in line with the reduction of branches and the expansion of non-face-to-face services. However, it is difficult to expand the chatbot services at once in the presence of technical limitations and constraints of internal and external environment. Therefore, it is necessary to analyze the various situations of chatbot service to preemptively identify problems that can occur in stages and seek solutions. This study conducted interviews with 12 field practitioners and researchers to examine the intentions and behaviors of financial chatbot service users and interpreted them using TPB. The study revealed the characteristics of 'feelings and attitudes' such as convenience or inconvenience from the chatbot experience, 'subjective norms' such as herd behavior or the yearning for empathy of others, and 'behavioral control' according to the recognition of difficulty or convenience of chatbot use process. This study shows that this characteristic can affect the intention and actual behavior of users to use chatbot service continuously. In the future research, it is necessary to empirically study specific intentions and influence factors for actual users.

A Study on the Patterns and Characteristics of Spatial Changes in Unregistered Private House Gardens (문화재 미등록 민가정원의 공간변화 양상 및 특성 연구)

  • Lee, Kyeong-Mi;Bae, Jun-Gyu;Shin, Hyun-Sil
    • Journal of the Korean Institute of Traditional Landscape Architecture
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    • v.40 no.3
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    • pp.67-73
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    • 2022
  • This study tracked the changing process of unregistered private house gardens by using the form at the time of the construction of gardens as the prototype of each garden, investigated the spatial value of the garden, and discussed the historical spatial value of unregistered private house gardens in terms of inheritance and change of traditional gardens. To this end, targeting on unregistered private house gardens in Gangwon-do, which are in danger of preserving their gardens due to the recent increase in the number of designated cultural heritage dismantled, the patterns of unregistered private house gardens, their characteristics and values were identified through the spatial change of the garden, and the following results were derived. First, the unregistered private house gardens were able to inherit and maintain the form of a traditional garden, being located in a clan village. The garden space was divided by the influence of Confucian philosophy, and the components of the garden, tree species and planting methods appeared differently. In other words, the use of garden components according to the status hierarchy appeared. Second, space reduction was continuously confirmed at four target sites. The reduced spaces are garden spaces, and part of the garden was attributed to the state due to the building of new road and environmental improvement project. The reduced spaces are garden spaces, and part of the garden was attributed to the state due to the new road and environmental improvement project. Third, eight old big trees over 100 years old were identified in three of the four target sites, and the garden components such as stone water tanks, quickset doors, and ponds were commonly identified in Korea, China, and Japan during the Joseon Dynasty, inheriting the historicity of the traditional garden.