• Journal of Applied Biological Chemistry
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• v.66
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• pp.258-265
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• 2023

After application of veterinary antibiotics, they may be partially metabolized before they are excreted by feces or urine either as unaltered form or as metabolites. Residual antibiotics enter the adjacent agricultural environments by spraying manure-based compost and liquid fertilizer on farmlands and lead to secondary pollution. The objective of this study was to compare the residual concentrations of 6 veterinary antibiotics by different production stages of liquid fertilizer from livestock manure recycling facilities. The relationship between concentration change of the residual antibiotics and the amount of liquid fertilizer component was also assessed. Pre-treatment showed the recovery of 63.4-106.7% at ppb level and the limit of quantification of 0.009-0.037 ㎍/L.As the result of analyzing the relationship between the residual concentrations of antibiotics and the amount of N component in liquid fertilizer by different production stages, the residual concentrations of antibiotics and N tended to decrease as the stabilization period elapsed during the liquid fertilization process. Average concentrations of sulfamethazine in raw materials, middle and final products of liquid fertilizer were 40.85, 26.17, 3.54 ㎍/L, respectively. Those of chlortetracycline decreased from 2.32 to 1.25 ㎍/L. The other 4 antibiotics also showed a decreasing trend by different production stages of liquid fertilizer. The amount of liquid fertilizer component N decreased from 0.21 to 0.096% by production stages of liquid fertilizer. It is considered that the correlation between residual antibiotic concentrations and N content can be applied as basic data for setting antibiotic reduction indicators.

• Korean Journal of Environmental Agriculture
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• v.39 no.4
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• pp.297-304
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• 2020

BACKGROUND: Emission of nitrous oxide (N2O) from the soil is expected to depend on the types of nitrogen fertilizer used. Biochar has recently been proposed as a potential mitigation of climate change by reducing the N2O emission. Although laboratory studies reported that biochar applications could reduce N2O emission, the number of field-based studies is still limited. Therefore, a field experiment was conducted to investigate the effect of biochar on N2O emission when different nitrogen fertilizers were applied in corn cultivated field. METHODS AND RESULTS: The field experiment consisted of six treatments: urea fertilizer without biochar (U), ammonium sulfate fertilizer without biochar (A), oil cake fertilizer without biochar (O), urea fertilizer with biochar (U+B), ammonium sulfate fertilizer with biochar (A+B), and oil cake fertilizer with biochar (O+B). Biochar was applied at a rate of 10 t/ha. Greenhouse gas fluxes were measured during growing seasons using static vented chambers. The cumulative N2O emissions were 0.99 kg/ha in the U, 1.23 kg/ha in the A, 3.25 kg/ha in the O, 1.19 kg/ha in the U+B, 0.86 kg/ha in the A+B, and 1.55 kg/ha in the O+B. CONCLUSION: It was found that N2O emission was related to application of both nitrogen fertilizer type and biochar. In particular, the N2O reduction effect was the highest in the corn field incorporated with biochar when oil cake was applied to the soil.

• Korean Journal of Soil Science and Fertilizer
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• v.38 no.5
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• pp.294-300
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• 2005

The effect of hairy vetch sod culture on reduction of soil loss and providing of nitrogen was investigated for the fields of Chinese cabbage in Hoenggye-Ri, Pyeongchang-Gun Gangwon-Do (780 m above sea level) from 2002 to 2003. Hairy vetch was sowed at just before planting, 15, 30 and 40 days after planting and right after harvest of Chinese cabbage. Hairy vetch was sod-cultivated with Chinese cabbage. The amount of sowing was $40kg\;10a^{-1}$. In this experiment, proper sowing times that had no influence on the yield of Chinese cabbage were 30 and 40 days after planting while other sowing times led to decrease the yield. In case of the former, there was 74% reduction effect of soil loss compared with no-hairy vetch because of covering the fields with hairy vetch right after harvest. Moreover, when the hairy vetch was put into the soil before planting of Chinese cabbage in the next year, it showed 61-79% substitution effect of standard application rate ($320kg\;ha^{-1}$, chemical fertilizer) for nitrogen fertilizer. It is suggested that using hairy vetch as cover crop would be useful in conservation of soil loss and reduction input of agricultural materials.

• Korean Journal of Soil Science and Fertilizer
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• v.46 no.6
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• pp.458-462
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• 2013

A drainage ditch is normally a component of drainage networks in farming systems to remove surplus water, but at the same time, it may act as a major conduit of agricultural nonpoint source pollutions such as sediment, nitrogen, phosphorus, and so on. The hybrid turbidity reduction system using biodegradable check dam and synthetic polymer was developed in this study to manage pollutant discharge from agricultural farmlands during rainfall events and/or irrigation periods. The performance of this hybrid system was assessed using a laboratory open channel sized in 10m-length and 0.2m-width. Various check dams using agricultural byproducts (e.g., rice straw, rice husks, coconut fiber and a mixture of rice husks and coconut fiber) were tested and additional physical factors (e.g., channel slope, flowrate, PAM dosage, turbidity level, etc.) affecting on turbidity reduction were applied to assess their performance. A series of lab experiments clearly showed that the hybrid turbidity reduction system could play a significant role as a supplementary of Best Management Practice (BMP). Moreover, the findings of this study could facilitate to develop an advanced BMP for minimizing nonpoint source pollution from agricultural farmlands and ultimately to achieve the sustainable agriculture.

• Korean Journal of Soil Science and Fertilizer
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• v.11 no.2
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• pp.113-118
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• 1979

In the soil treated with irrigation control and gypsum, different species of rice plants, Jin-heung, Aggibare, Tong-il, Mil-yang 23, Noindo, Yugnong-chat, were grown. The content of cadmium, copper and zinc in the brown rice was investigated. Results obtained are as follows : 1) Cadmium Content of brown rice was remarkably reduced under the condition to maintain the reduction than oxidation after ear forming stage, and also the application of gypsum was additional effects to reduce cadmium uptake under reduction condition. Zinc and copper contents in the brown rice was similar to calcium reducing, but their effects of reduction were appeared less than cadmium. 2) The reduced tendency of cadmium uptake under the reduction condition was in the order of Tong-il>Mil-yang23>Aggibare>Yugnong-chal>Noindo>Jin-heung. 3) In the oxidzing condition, Jin-heung uptaked cadmium, copper and zinc more than any other species.

• Journal of Animal Environmental Science
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• v.18 no.sup
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• pp.13-20
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• 2012

This research investigated the effect of $SCOD_{Mn}$ concentrations and pH adjustment at the stage before land application, namely 2nd-aeration treatment stage of liquid fertilizer in the liquid fertilizer treatment process of swine manure on the physicochemical compositions of 2nd-aeration treated liquid fertilizer. The liquid fertilizer used in this research is the alkaline fermented liquid fertilizer of swine manure more than pH 9.0 through aeration treatment (Alkaline fermentation treatment group). About the alkaline liquid fertilizer, phosphate neutralization treatment was conducted with phosphoric acid and it was a phosphate neutralization treatment group. In 2nd-aeration treatment of liquid fertilizer for 30 days, each group was divided into alkaline treatment groups (T-1, T-2, and T-3) and phosphate neutralization treatment groups (T-4, T-5, and T-6) according to early $SCOD_{Mn}$ concentrations. The research results are as follows. 1. As for $SCOD_{Mn}$ reduction rate, the average 29.9% in alkaline treatment groups and the average 36.9% in phosphate neutralization treatment groups were shown and so the relatively high reduction rate was shown in phosphate neutralization treatment groups. 2. After finishing the experiment, the group of the lowest $SCOD_{Mn}$ concentrations was the phosphate neutralization treatment group, T-6 with the lowest inflow concentrations. In case the final goal level of 2nd-aeration treated liquid fertilizer is assumed as concentrations less than $SCOD_{Mn}$ 3,000 ppm, it would be desired that inflow concentrations of 2nd-aeration treatment groups are adjusted less than $SCOD_{Mn}$ 5,500 ppm. 3. As for the persistence rate of nitrogen, the average 29.3% in alkaline treatment groups and the average 38.9% in phosphate neutralization treatment groups were shown and so phosphate neutralization treatment groups showed the relatively low loss rate of nitrogen, meanwhile, in the case of T-P, phosphate neutralization treatment groups maintained high concentrations (average 1,473 ppm). 4. In the event of 2nd-aeration treatment of liquid fertilizer, "alkaline fermentation treatment" condition in 'low phosphate-low nitrogen' type and "phosphate neutralization treatment" condition in 'high phosphate-high nitrogen' type are expected to be favorable.

• Proceedings of the Korean Society of Crop Science Conference
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• 2001.09a
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• pp.72-90
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• 2001

Environment agriculture carried out from 1999 in Daeho reclaimed saline area, located in central east cost of Choongnam Korea, resulted in dramatic reduction of amount of nitrogen fertilizer and application times and amount of pesticides. The ecological status of Daeho reclaimed saline area was considered to still very sound from the results of ecological survey on flora and fauna. However, it was desirable to adapt precision agriculture for production of high eating quality of rice and preservation of Daeho ecosystem. Especially, precise application of nitrogen and phosphorus fertilizer was recommendable for prevention of water pollution in environment rice cultivation by duck or mud snail or crab. The bioefficacy of Scirpus maritimus and Echinochloa crus-galli in paddy field of environment rice cultivation by duck or mud snail or crab in Daeho reclaimed saline area was revealed very low. Therefor, it was concluded that the pre-measures of reduction of natural weed population were necessary for successful environment agriculture. The most desirable and ideal environmentally sound agriculture in Daeho reclaimed saline area was performance of crop rotation, introduction of legume crops and green manure crops, and also, simultaneous management of crop production and animal husbandry for smooth flow of energy cycle within the closed Daeho ecosystem.

• Korean Journal of Soil Science and Fertilizer
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• v.49 no.5
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• pp.541-547
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• 2016

In this experiment we investigated the influence of various anions including oxalic acid encountered as solution phase in soil on the adsorption and desorption of sulfate in Chungwon Bt soil. The effect of chloride and nitrate on the adsorption of sulfate was not significant, suggesting that sulfate was better able to compete for adsorption sites at concentrations studied, in contrast to the large reduction in the amount of chloride adsorbed in the presence of sulfate. The results of competition for sorption sites between sulfate and anion showed that the simultaneous presence of two anions in solution was effective in reduction of competing anion at a maximum value of adsorption, due to the similar adsorption mechanism for anion competition. Therefore, the variation in the buffer power of the acids will produce a change in the strength and amount of adsorption and the competitive ability.

• Korean Journal of Soil Science and Fertilizer
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• v.49 no.1
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• pp.66-74
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• 2016

Environmental pollution from abandoned metal mines has been awarded as serious problem and many techniques have been applied to remediate pollutants. Main objective of this research was to evaluate efficiency of heavy metal sorption capacity of spent mushroom media (SMM) in aqueous and soil matrix. Laboratory batch experiment was conducted and 4 different heavy metals (Cd, Pb, Cu, Zn) were evaluated. In aqueous phase, all 4 heavy metals showed high reduction efficiency ranged from 60-99% and Pb showed the highest sorption efficiency. In case of soil phase, much lower sorption efficiency was observed compared to aqueous phase. The highest reduction efficiency was observed in Cd (average of 38%). With scanning electron microscopy energy dispersive detector (SED-EDS) analysis, we confirmed sorption of heavy metals at the surface of SMM. Overall, SMM can be used as sorption materials for heavy metals in both aqueous and soil matrix and more research should be conducted to increase sorption efficiency of SMM in soil.

• Journal of Bio-Environment Control
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• v.13 no.4
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• pp.240-244
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• 2004

This study was conducted to evaluate the effect of different surfactants on the fertilizer reduction and increase of the mineral nutrients uptake of lettuce (Latuca sativa L. 'Hanbatchungchima') in deep flow technique culture. The measured items from lettuce leaves expanded fully were growth, photosynthetic and transpiration rate, and mineral nutrient content K, Ca and Mg, respectively. The highest growth were observed at $0.3mg{\cdot}L^{-1}$ polyvinyl alcohol (PV4-95) treatment, including lettuce grown in the half strength of nutrient solution. The highest photosynthetic rate, transpiration rate and mineral nutrient content were observed at $0.3mg{\cdot}L^{-1}$ calcium lignosulfate (CLS) treatment. Therefore, high-quality leaf lettuce production could be achieved by apply proper surfactants PVA-95 and CLS, which can cut down the total amount of fertilizer and increase uptake of mineral nutrients.