• 환경영향평가
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• 제16권4호
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• pp.277-283
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• 2007

Since the Kyoto Protocol became into effect, Korea has been expected to be part of the Annex I countries performing the duty of GHG reduction in the phase of post-Kyoto. Therefore, it is necessary to develop emission factors appropriate to Korean circumstances. In order to develop emission factors this study utilized the CleanSYS, which is the real-time monitoring system for industrial smoke stacks to calculate the emission rate of $CO_2$ continuously. In this study, the main focus was on the power generation plants emitting the largest amount of $CO_2$ among the sectors of fossil fuel combustion. Also, an examination on the comparison of $CO_2$ emission was made among 3 generation plants using the different types of fuels such as bituminous coal and LNG; one for coal and others for LNG. The $CO_2$ concentration of the coal fired plant showed Ave. 13.85 %(10,384 ton/day). The LNG fired plants showed 3.16 %(1,031 ton/day) and 3.19 %(1,209 ton/day), respectably. Consequently, by calculating the emission factors using the above results, it was found that the bituminous coal fired power plant had the $CO_2$ emission factor average of 88,726 kg/TJ, and the LNG fired power plants had the $CO_2$ average emission factors of 56,971 kg/TJ and 55,012 kg/TJ respectably which were similar to the IPCC emission factor.

• 대한기계학회논문집
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• 제19권2호
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• pp.591-596
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• 1995

In order to investigate the reduction of NO emissions, natural gas was fueled for two-stage combustion apparatus. NO and CO emissions were described by five variables: total air ratio, primary air ratio, secondary air injection position, secondary air injection velocity, and swirl ratio. It was mainly observed that, as the primary air ratios of 0 and 0.4 NO emission decreased with increasing the secondary air injection position and secondary air injection velocity. The effect of weak swirl on NO emission was found to be insignificant.

• 한국기후변화학회지
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• 제7권3호
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• pp.341-349
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• 2016

This study is intended to set a greenhouse gas emission scenario based on green remodeling pilot project (Annex building of Seoul Customs Office) using LEAP model, a long-term energy plan analysis model, to calculate the energy saving and greenhouse gas emission till year 2035 as well as to analyze the effect of electric power saving cost. Total 4 scenarios were made, Baseline scenario, assuming the past trend is to be maintained in the future, green remodeling scenario, reflecting actual green remodeling project of Seoul Customs Office, behavior improvement and renewable energy supply, and Total scenario. According to the analysis result, the energy demand in 2035 of Baseline scenario was 6.1% decreased from base year 2013, that of green remodeling scenario was 17.5%, that of behavior improvement and renewable energy supply scenario was 21.1% and that of total scenario was 27.3%. The greenhouse emission of base year 2013 was $878.2tCO_2eq$, and it was expected $826.3tCO_2eq$, approx. 5.9% reduced, in 2035 by Baseline scenario. the cumulative greenhouse gas emission saving of the analyzing period were $-26.5tCO_2eq$ by green remodeling scenario, $2.8k\;tCO_2eq$ by behavior improvement and renewable energy supply scenario, and $2.0k\;tCO_2eq$ by total scenario. In addition the effect of electricity saving cost through energy saving has been estimated, and it was approx. 634 million won by green remodeling scenario and appro. 726 million won by behavior improvement and renewable energy supply scenario. So it is analyzed that of behavior improvement and renewable energy supply scenario would be approx. 12.7% higher than that of green remodeling scenario.

• 자원ㆍ환경경제연구
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• 제18권2호
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• pp.279-309
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• 2009

산업에서 발생되는 온실가스를 줄이기 위해서는 각 산업별 온실가스 발생량을 정확히 예측해야 한다. 이에 본 연구에서는 2003년 산업연관표와 에너지 사용량 통계자료를 기초로 401개 산업별 직 간접 $CO_2$ 원단위를 산출하고 이를 활용하는 방안을 검토하였다. 본 연구는 국내에 없는 일부 데이터 대신 해외 데이터 사용, 석유정제부문에 대한 분배 문제, 카본뉴트럴 측면에서 재검토 필요성, 폐기물처리 부문 과정의 일부 미고려 등에 따른 결과의 한계를 가지고 있다. 그럼에도 불구하고 부산물로 얻어지는 코크스로가스나 철강계 가스, 자원순환 관점에서 주목받고 있는 폐기물 영향까지를 고려한 401개 상세 산업별 직 간접 $CO_2$ 원단위를 산출했다는 측면에서 의미가 있다. 산업별 $CO_2$ 배출 원단위 분석 결과를 살펴보면, 간접 $CO_2$ 원단위가 크게 나타난 대표적인 산업으로는 조강, 레미콘, 선재 및 궤조, 주철물, 철근 및 봉강 산업이다. 이들 산업은 직접 $CO_2$ 원단위가 큰 산업에서 생산된 원료물질을 이용하여 제품을 생산하고 있다. 직접 $CO_2$ 배출 원단위가 크게 나타난 대표적인 산업으로는 시멘트, 선철, 석회 및 석고 제품, 석탄화합물 등 자연으로부터 채취한 원광석 등을 이용하여 다른 산업에 유용한 원료물질로 정제하는 산업이었다. 본 연구 결과는 산업별 특성이 반영된 저감 목표치 산정, $CO_2$ 저감정책별 감축 잠재량 산정, 기업의 $CO_2$ 배출량 수준 파악 및 저감 목표량을 설정할 때 유용하게 활용될 수 있다. 그 밖에도 국내에서 활발히 연구되고 있는 환경경제통합계정, 산업별 물질흐름분석 분야에서 널리 응용될 수 있을 것이다.

• KEPCO Journal on Electric Power and Energy
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• 제3권1호
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• pp.35-39
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• 2017

Recently, the public opinion is growing that the main cause of greenhouse gas, fine dust and nitrogen oxide, sulfuric acid emission is coal-fired power plant, and now the decommission or conversion to other clean fuel is being demanded. However, it is a huge national loss to decommission coal-fired power plant with remaining life, and also simple fuel converting to natural gas will lead to drastic rise on power generating cost. Therefore, this study aims to provide the analysis result about the reduction effect of $CO_2$, environment emission, and to influence to power plant performance and facilities when repowering with adding gas turbine is applied to domestic aged coal-fired power plant.

• 유기물자원화
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• 제28권1호
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• pp.37-51
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• 2020

2015년 말 채택된 파리협정으로 2023년부터 5년 단위로 국제이행점검(Global stock-taking)이 진행될 예정이며, 국가 온실가스 인벤토리와 온실가스 감축 목표 달성 경과 등을 의무적으로 보고해야 한다. 이에 대비하여 온실가스 배출량 산정의 신뢰도를 향상시키고, 온실가스 배출원별 특성 파악과 배출량 관리가 중요한 시점이다. 이에 본 연구에서는 폐기물 매립 부문을 대상으로 2000 GPG, 2006 IPCC 가이드라인 및 2019 Refinement 산정방법에 따라 온실가스 배출량을 비교·분석하였다. 그 결과, 2016년 기준 시나리오 1에서는 2,287 Gg CO₂_eq, 시나리오 2-1은 1,870 Gg CO₂_eq, 시나리오 2-2는 10,886 Gg CO₂_eq, 시나리오 2-3은 10,629 Gg CO₂_eq, 시나리오 3은 12,468 Gg CO₂_eq으로 나타나 2000 GPG 대비 2006 IPCC 가이드라인 적용 시 온실가스 배출량이 증가하는 것으로 나타났다. 이러한 배출량 변화의 차이는 산정방식의 변화와 적용되는 배출계수 값에 기인하였으며, 이에 우리나라 특성에 따른 배출계수의 국가고유값 개발이 시급한 것으로 나타났다.

• 한국수소및신에너지학회논문집
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• 제23권1호
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• pp.83-92
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• 2012

Syngas combustion characteristics of mass produced oxygen carrier particle (OCN706-1100) were investigated in a pressurized fluidized bed reactor using simulated syngas and air as reactants for reduction and oxidation, respectively. The oxygen carrier showed high fuel conversion, high $CO_2$ selectivity, and low CO concentration at reduction conditions and no NO emission at oxidation conditions. Moreover, OCN706-1100 particle showed good regeneration ability during successive reduction-oxidation cyclic tests up to the 10th cycle. Fuel conversion and $CO_2$ selectivity decreased and CO emission increased as temperature increased. These results can be explained by trend of calculated equilibrium CO concentration with temperature. However, fuel conversion and $CO_2$ selectivity increased and CO emission decreased as pressure and gas residence time increased.

• 한국수소및신에너지학회논문집
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• 제32권1호
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• pp.53-62
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• 2021

Batch type reduction-oxidation tests were performed to check effects of temperature, pressure, gas velocity, and capacity on reduction characteristics of mass produced particle in a 0.5 MWth chemical looping combustion system. The fuel conversion and the CO2 selectivity increased as the temperature increased and as the gas velocity decreased. However the CO2 selectivity showed the maximum and decreased as the capacity increased because the CO emission increased. The results show that high temperature, low gas velocity and low inert gas concentration are preferable to ensure high reactivity of oxygen carrier in the fuel reactor.

• 한국수소및신에너지학회논문집
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• 제26권5호
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• pp.499-506
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• 2015

Recently the Korean government announced its decision to select the $3^{rd}$ proposal, which targets reducing $CO_2$ by 37% of the BAU level by 2030, for the Intended Nationally Determined Contribution (INDC). According to this proposal, natural gas (or equivalent gas) combined cycle (NGCC) are suggested as alternatives for conventional pulverized coal (PC). In this study, we analyzed the environmental, economic, and energy mixing aspects of synthetic natural gas combined cycle(SNGCC) using NETL material (2011~2012 version) and other domestic materials (2014 version). We found the following conclusions: 1) Considering carbon capture and storage (CCS) integration, $CO_2$ emission factors of SNGCC and supercritical PC are the same. However, 60% of $CO_2$ from SNGCC is produced as high pressure and high purity (99%) gas, making it highly suitable for CCS, which is now strongly supported by the government. 2) Based on the economic analysis for SNGCC using domestic materials and comparison with NGCC, it was found that the settlement price of SNGCC was 30% lower than that of NGCC.

• 한국대기환경학회지
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• 제15권3호
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• pp.249-255
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• 1999

We sdudied effect of additives on catalytic activity in thermal catalytic de-NOx process which was composed of thermal reduction, catalytic reduction and catalytic oxidation stage. Pd-Pt/${\gamma}$-$Al_2O_3$ catalysts with the addition of transition metals(Co, Cu, Fe, Ni, W, Zn, Zr) and rare earth metals(Ce, Sr) were prepared by the conventional washcoating method. Those catalysts were characterized by CO pulse chemisorption, ICP, $N_2$ adsorption, SEM and XRD. The effect of catalyst additives on NOx removal for diesel emission was studied in thermal catalytic de-NOx process at reduction temperature(350~50$0^{\circ}C$), space velocity(5,000~20,000 $hr^{-1}$) and the engine load(0~120kW). The concentraton of CO, $CO_2$, NO and $NO_2$ in the exhaust gas increased with the engine load. On the other hand the concentration of $O_2$ decreased. The de-NOx activityof all prepared catalysts increased with respect to high CO and low $O_2$ level in the thermal reduction stage of the process. Insertion of Ce to Pt-Pd/${\gamma}$-$Al_2O_3$ catalyst showed the best activity of all the catalysts under these experimental conditions. De-NOx catalysts are effective to remove CO in addition to NOx in the catalytic reduction stage.