• Journal of the Korean Chemical Society
• /
• v.39 no.10
• /
• pp.812-817
• /
• 1995

Rapid and selective reduction of aromatic nitro compounds is of important for the preparation of amino derivertives in organic synthesis, particularly when a molecule has other reducible substituents. While Bakers' Yeast has been used for the enantioselective reduction of carbonyl compounds, little attention has been paid to the reduction of aromatic nitro compounds with Bakers' Yeast. Nitro group of m-bromonitrobenzene was selectively and rapidly reduced to corresponding amino derivative in good yield by Bakers' Yeast in basic solution. Furthermore, nitrosobenzene was rapidly reduced to aniline in good yield by Bakers' Yeast under neutral condition. In this paper, we wish to report a rapid and simple reduction of m-bromonitrobenzene and nitrosobenzene to the corresponding amino derivatives using Bakers' Yeast. And the effects of various agents, temperature and pH on the reduction will be discussed.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
• /
• 2000.06a
• /
• pp.1273-1279
• /
• 2000

A new concept of piezoelectric smart panels for noise reduction in wide band frequencies is proposed and their possibility is experimentally investigated. The proposed panels are based on active and passive methods. They use piezoelectric smart structure technology for active noise reduction at low band frequencies and passive sound absorbing materials for mid-range of noise frequencies. To prove the concept of piezoelectric smart panels, an acoustic measurement experiment was performed. The smart panels exhibit a good noise reduction in middle and high frequency ranges due to the mass effects of absorbing materials or/and the air gap. The use of piezoelectric smart panel renders noise reduction large at resonance frequency. Another concept of smart panel that uses piezoelectric damping is experimentally investigated. Since piezoelectric dampings can reduce vibration and noise at resonance frequencies with simple shunt circuit, they have merits in terms of economy and simplicity. Dissipated energy method(DEM) is adopted to tune the shunt circuit precisely in piezoelectric dampings. Noise reduction at multiple resonance frequencies is demonstrated.

• Proceedings of the KSME Conference
• /
• 2003.11a
• /
• pp.448-453
• /
• 2003

In this study, the effects of oxygen component in fuel and exhaust gas recirculation(EGR) method on the exhaust emissions has been investigated for a D.I. diesel engine. It was tested to estimate change of exhaust emission characteristics for the commercial diesel fuel and oxygenate blended fuel which has five kinds of blending ratio. Dimethoxy methane(DMM) contains oxygen component 42.5% in itself. and it is a kind of effective oxygenated fuel for reduction of smoke emission. It was affirmed that smoke emission was decreased with increasing of DMM blending ratio. But, NOx emission was increased compared with commercial diesel fuel. It was needed a NOx reduction countermeasure that EGR method was used as a countermeasure for NOx reduction. It was found that simultaneous reduction of smoke and NOx emission was achieved with DMM blended fuel and cooled EGR method($10{\sim}15%$).

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
• /
• 2011.04a
• /
• pp.443-444
• /
• 2011

This paper discusses a model order reduction for large order rotor dynamics systems results from the finite element discretization. Typical rotor systems consist of a rotor, built-on parts, and a support system, and require prudent consideration in their dynamic analysis models because they include unsymmetric stiffness, localized nonproportional damping and frequency dependent gyroscopic effects. When the finite element model has a very large number of degrees of freedom because of complex geometry, repeated dynamic analyses to investigate the critical speeds, stability, and unbalanced response are computationally very expensive to finish within a practical design cycle. In this paper, the Krylov-based model order reduction via moment matching significantly speeds up the dynamic analyses necessary to check eigenvalues and critical speeds of a Nelson-Vaugh rotor system. With this approach the dynamic simulation is efficiently repeated via a reduced system by changing a running rotational speed because it can be preserved as a parameter in the process of model reduction. The Campbell diagram by the reduced system shows very good agreement with that of the original system. A 3-D finite element model of the Nelson-Vaugh rotor system is taken as a numerical example to demonstrate the advantages of this model reduction for rotor dynamic simulation.

• Journal of Korean Society on Water Environment
• /
• v.29 no.1
• /
• pp.45-54
• /
• 2013

This study analyzes the reduction effects of runoff and flood damage through different arrangements of stormwater storage facilities. Three scenarios based on the spatial allocation of storage capacity are used: concentrated, decentralized and combinative. The characteristics of runoff and flood damage by scenario are compared. The XP-SWMM model is used for runoff simulation by the probable rainfall of return period. The result shows that the concentrated arrangement of storage facilities is most effective to reduce the amount of peak flow and to delay the time of peak flow. Yet, while the concentrated arrangement is most effective to reduce the inundation damage, it is not effective to reduce runoff volume. The decentralized arrangement is most effective to reduce runoff volume. The combinative arrangement is effective not only the runoff reduction but also the reduction of flood damage. The result indicates that the flood mitigation strategies against heavy rainfall need to consider decentralized on-site arrangement for the reduction of runoff volume along with concentrated off-site arrangement of storage facilities.

• Journal of Korean Physical Therapy Science
• /
• v.21 no.1
• /
• pp.53-58
• /
• 2014

Background : The purpose of this study is to identify the level of positive influence on the pain and the gripping power in patients with tennis elbow by comparing the TENS treatment method and the kinesio taping therapy with good accessibility among the kinesio taping therapy and electrical therapy. Methods : Targeting the patients diagnosed with tennis elbow, the subjects were categorized in groups of four, each of electrical therapy group and kinesio tape therapy group where the degree of pain reduction through VAS before and after the treatment of each group and the measurement of the degree of gripping power increase using the gripping power measurement tool as well as the pain reduction changes and gripping power increase before and after the treatment between the two groups were compared. Result : As a result, the electrical therapy group and the kinesio tape group were able to obtain the results of pain reduction and gripping power increase through VAS before and after the treatment, but for all pain reduction and gripping power increase, it had no statistically significant changes(p>.05). In addition, in the changes of pain reduction and changes of gripping power increase before and after the treatment, there were no statistically significant differences between the electrical therapy group and the kinesio tape group(p>.05). Conclusion : Based on the results so far, it is thought that the kinesio taping therapy can positively influence the pain reduction of patients with tennis elbow and increase of gripping power.

• Journal of Environmental Impact Assessment
• /
• v.20 no.2
• /
• pp.123-131
• /
• 2011

The objective of this study is to prepare the effective management plan of environmental noise with a noise map, and the guideline on the management plan of environmental noise was suggested through the review of existing application examples. The management plan of environmental noise with a noise map includes the practical contents in the stages of subdivision of management areas, establishment of reduction measures, opinion collection, post investigation, and reformulation of management plan. First, the classification of management regions is performed considering the excess degree of noise standard and the facility type in the phase of subdivision of management areas. Second, the optimal management plan is established through the investigation of regional characteristics and various noise reduction measures in the phase of establishment of reduction measures, which includes the examination of noise reduction effects with a noise map and the budget planning with the costing of noise reduction measures. Third, the opinion survey with a local resident and a expert is carried out in order to prove the validity of the management plan in the phase of opinion collection, and the management plan is modified with gathered opinions. Fourth, the post examination plan with noise measurement is performed in order to verify the real effect of noise reduction measures according to the management plan in the phase of post investigation. Finally, the amendment of the management plan as well as the improvement of a noise map is carried out at a regular cycle in the phase of reformulation of management plan.

• Bulletin of the Korean Chemical Society
• /
• v.34 no.8
• /
• pp.2335-2339
• /
• 2013

Relative reactivity of various Al-substituted dialkylalans ($AlR_2(X)$) in reduction of acetone has been studied with density functional theory and MP2 method. Formation of the alan dimers and the alan-acetone adduct, and the transition state for the Meerwein-Ponndorf-Verley (MPV) type reduction of the adduct were calculated to figure out the energy profile. Formation of dimeric alans is highly exothermic. Both the relative free energies for acetone-alan adduct formation and the TS barriers for the MPV type reduction with respect to alan dimers and acetone were calculated and they show the same trend. Based on these energetic data, relative reactivity of alans is expected to be; $AlR_2(Cl)$ > $AlR_2(OTf)$ > $AlR_2(O_2CCF_3)$ > $AlR_2(F)$ > $AlR_2(OMs)$ > $AlR_2(OAc)$ > $AlR_2(OMe)$ > $AlR_2(NMe_2)$. The energy profile is relatively well correlated with the experimental order of the reactivity of Al-substituted dialkylalans. It is noted that the substituents of alans have initial effects on the relative free energies for the carbonyl-adduct formation. Therefore, an $AlR_2(X)$ which forms a more stable carbonyl-adduct is more reactive in carbonyl reduction.

• Steel and Composite Structures
• /
• v.11 no.4
• /
• pp.273-290
• /
• 2011

In current ductility-based earthquake-resistant design, the estimation of design forces continues to be carried out with the application of response modification factors on elastic design spectra. It is well-known that the response modification factor (R) takes into account the force reduction, strength, redundancy, and damping of structural systems. The key components of the response modification factor (R) are force reduction ($R_{\mu}$) and strength ($R_S$) factors. However, the response modification and strength factors for structural systems presented in design codes were based on professional judgment and experiences. A numerical study has been accomplished to evaluate force reduction, strength, and response modification factors for special steel moment resisting frames. A total of 72 prototype steel frames were designed based on the recommendations given in the AISC Seismic Provisions and UBC Codes. Number of stories, soil profiles, seismic zone factors, framing systems, and failure mechanisms were considered as the design parameters that influence the response. The effects of the design parameters on force reduction ($R_{\mu}$), strength ($R_S$), and response modification (R) factors were studied. Based on the analysis results, these factors for special steel moment resisting frames are evaluated.

• International Journal of Naval Architecture and Ocean Engineering
• /
• v.7 no.6
• /
• pp.1020-1033
• /
• 2015

In order to design a compact urea selective catalytic reduction system, numerical simulation was conducted by computational fluid dynamics tool. A swirl type static mixer and a mixing chamber were considered as mixing units in the system. It had great influence on flow characteristics and urea decomposition into ammonia. The mixer caused flow recirculation and high level of turbulence intensity, and the chamber increased residence time of urea-water-solution injected. Because of those effects, reaction rates of urea decomposition were enhanced in the region. When those mixing units were combined, it showed the maximum because the recirculation zone was significantly developed. $NH_3$ conversion was maximized in the zone due to widely distributed turbulence intensity and high value of uniformity index. It caused improvement of $NO_x$ reduction efficiency of the system. It was possible to reduce 55% length of the chamber and connecting pipe without decrease of $NO_x$ reduction efficiency.