• Title/Summary/Keyword: Reduction atmosphere

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Effect of Soil Texture and Tillage Method on Rice Yield and Methane Emission during Rice Cultivation in Paddy Soil

  • Cho, Hyeon-Suk;Seo, Myung-Chul;Kim, Jun-Hwan;Sang, Wan-gyu;Shin, Pyeong;Lee, Geon Hwi
    • Korean Journal of Soil Science and Fertilizer
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    • v.49 no.5
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    • pp.564-571
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    • 2016
  • As the amount of rice straw collected increases, green manure crops are used to provide the needed organic matter. However, as green manure crops generate methane in the process of decomposition, we tested with different tillage depths in order to reduce the emission. The atmosphere temperature of the chamber was $25{\sim}40^{\circ}C$ during the examination of methane and soil temperature was $2{\sim}10^{\circ}C$ lower than air temperature. The redox potential (Eh) of the soil drastically fell right before irrigated transplanting and showed -300~-400 mV during the cultivating period of rice (7~106 days after transplant). When hairy vetch was incorporated to soil and the field was not irrigated, the generation of methane did not occur from 12 to 4 days before transplanting rice and started after irrigation. Regarding the pattern of methane generation during the cultivation of rice, methane was generated 7 days after transplanting, reached the pinnacle at by 63~74 days after transplanting, rapidly decreased after 86~94 days past transplanting and stopped after 106 days past transplanting. When tested by different soil types, methane emission gradually increased in loam and clay loam during early transplant, whereas it sharply increased in sandy loam. The total amount of methane emitted was highest in sandy loam, followed by loam and clay loam. In all three soil types, methane emission significantly reduced when tillage depth was 20 cm compared to 10 cm. The rice growths and yield were not affected by tillage depth. Therefore, reduction of methane emission could be achieved when application hairy vetch to the soil with tillage depth of 20 cm in paddy soil.

Corrosion Cost and Corrosion Map of Korea - Based on the Data from 2005 to 2010

  • Kim, Y.S.;Lim, H.K.;Kim, J.J.;Hwang, W.S.;Park, Y.S.
    • Corrosion Science and Technology
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    • v.10 no.2
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    • pp.52-59
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    • 2011
  • Corrosion of metallic materials occurs by the reaction with corrosive environment such as atmosphere, marine, soil, urban, high temperature etc. In general, reduction of thickness and cracking and degradation are resulted from corrosion. Corrosion in all industrial facilities and infrastructure causes large economic losses as well as a large number of accidents. Economic loss by corrosion has been reported to be nearly 1-6% of GNP or GDP. In order to reduce corrosion damage of industrial facilities, corrosion map as well as a systematic investigation of the loss of corrosion in each industrial sector is needed. The Corrosion Science Society of Korea in collaboration with 15 universities and institutes has started to survey on the cost of corrosion and corrosion map of Korea since 2005. This work presents the results of the survey on cost of corrosion by Uhlig, Hoar, and input-output methods, and the evaluation of atmospheric corrosion rate of carbon steel, weathering steel, galvanized steel, copper, and aluminum in Korea. The total corrosion cost was estimated in terms of the percentage of the GDP of industry sectors and the total GDP of Korea. According to the result of Input/output method, corrosion cost of Korea was calculated as 2.9% to GDP (2005). Time of wetness was shown to be categories 3 to 4 in all exposure areas. A definite seasonal difference was observed in Korea. In summer and fall, time of wetness was higher than in other seasons. Because of short exposure period (12 months), significant corrosion trends depending upon materials and exposure corrosion environments were not revealed even though increased mass loss and decreased corrosion rate by exposure time.

A Study of Optimum Shielding Gas Flow Rate in FCAW for Shipbuilding (선박조립과정의 FCAW 적용시 적정 보호가스 유량에 대한 연구)

  • Lee, Hoon-Dong;Shim, Chun-Sik;Song, Ha-Cheol;Yum, Jae-Seon
    • Journal of the Society of Naval Architects of Korea
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    • v.48 no.1
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    • pp.76-83
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    • 2011
  • FCAW(Flux Cored Arc Welding) is a widely used welding method in shipbuilding. It also conducts WPS(Welding Procedure Specification) requested by the classification variations of the factors which affect the quality on the welded area such as thickness of base metal, type of welding wire and shielding gas etc. which has to be satisfied. CO2 is commonly used as a shielding gas for FCAW due to the economic point of view. The amount of shielding gas is stated when classification certify WPS. However, the shielding gas is unnecessarily used at the shipyard leaning only on the welder's experience as there are classification standards for using the shielding gas. It causes production cost to rise. Also recently, CO2 is a main contributor for global warming, and large amounts of CO2 are discharged into the atmosphere during shipbuilding processes without any filtration. Therefore it was confirmed by the security of the welded area as a result of conducting the destructive and non-destructive tests with setting up the factors and the standards by using the Taguchi method. Then the FCAW shielding gas's amounts were calculated precisely when assembling a ship. It will be applied to cost reduction and prevention of environmental pollution at the shipyard.

Effects of Postannealing on GaN Grown by MOCVD on Reactive ion Beam Pretreated Sapphire Substrate (활성화 이온빔 처리된 사파이어 기판상 MOCVD로 성장시킨 GaN의 열처리 효과)

  • Lee, Sang-Jin;Byeon, Dong-Jin;Hong, Chang-Hui;Kim, Geung-Ho
    • Korean Journal of Materials Research
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    • v.11 no.3
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    • pp.191-196
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    • 2001
  • GaN is a key material for blue and ultraviolet optoelectronics. Postannealing process was employed to investigate the structural change and the effect on electrical property of the GaN thin film grown on reactive ion beam(RIB) treated sapphire (0001) substrate. Full width half maximum (FWHM) of double crystal x-ray diffraction (DCXRD) spectra and Hall mobility of the specimen were significantly changed depending on the postannealing time at $1000^{\circ}C$ in N2 atmosphere. FWHM of DCXRD reduced upto about 50arc-sec and the mobility increased about $80\textrm{cm}^2$/V.sec. The postannealed specimen with the best mobility was compared with sample without annealing by TEM. The former sample showed a decrease in the lattice strain and reduction of dislocation density by about 56~59%. This implies that there is a strong correlation between crystalline quality and the electrical property of the film. The Present results clearly show that the combination of RIB pretreatment and proper post annealing conditions results in the improved properties of GaN films grown by MOCVD.

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Observation of Thermal Conductivity of Pressureless Sintered AlN Ceramics under Control of Y2O3 Content and Sintering Condition (Y2O3 함량과 소결조건에 따른 상압소결 AlN 세라믹스의 열전도도 고찰)

  • Na, Sang-Moon;Go, Shin-Il;Lee, Sang-Jin
    • Journal of the Korean Ceramic Society
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    • v.48 no.5
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    • pp.368-372
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    • 2011
  • Aluminum nitride (AlN) has excellent thermal conductivity, whereas it has some disadvantage such as low sinterability. In this study, the effects of sintering additive content and sintering condition on thermal conductivity of pressureless sintered AlN ceramics were examined on the variables of 1~3 wt% sintering additive ($Y_2O_3$) content at $1900^{\circ}C$ in $N_2$ atmosphere with holding time of 2~10 h. All AlN specimens showed higher thermal conductivity as the $Y_2O_3$ content and holding time increase. The formation of secondary phases (yttrium aluminates) by reaction of $Y_2O_3$ and $Al_2O_3$ from AlN surface promoted the thermal conductivity of AlN specimens, because the secondary phases could reduce the oxygen contents in AlN lattice. Also, thermal conductivity was increased by long sintering time because of the uniform distribution and the elimination of the secondary phases at the grain boundary by the evaporation effect during long holding time. A carbothermal reduction reaction was also affected on the thermal conductivity. The thermal conductivity of AlN specimens sintered at $1900^{\circ}C$ for 10 h showed 130~200W/mK according to the content of sintering additive.

Reformation Methods of Environmental Impact Assessment in Water Resources Development Project by Examining Local Resident Opinions (수자원 개발사업 주민의견 유형분석을 통한 환경영향평가 개선방안)

  • Yang, Kee-Hyoun;Park, Jae-Chung;Ryu, Young-Han;Jeong, Yong-Moon;Song, Sang-Jin;Shin, Jae-Ki
    • Journal of Environmental Impact Assessment
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    • v.20 no.3
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    • pp.397-409
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    • 2011
  • This study was carried out for improving the effectiveness of water resources development project through local resident opinions in the environmental impact assessment(EIA). The EIA reports of seven dams were examined. Four dams -Youngju Dam, Seongduck Dam, Buhang Dam and Hantangang Dam- which included many local opinions including 470 opinions of 341 local residents were selected to be analyzed. Local residents submitted their opinions in the six fields which are meteorological phenomena, water quality, land use, fauna and flora, noise and vibration, and residence, and the major opinions of those opinions came from the atmosphere environment field which is 32% of total opinions and social and economic field which is 38% of total opinions, respectively. In submerged area, opinions of the measure for migration and compensation were 91% and in non-submerged area, opinions of the measure for meteorological phenomena was 86%. Those percentages were maximum in each area. Opinions concerned meteorological phenomena were 86% and 53% in Youngju Dam and Seongduck Dam where area is surrounded by existing dam, but there was only 9% and 0% of opinions in Buhang Dam and Hantangang Dam where area is without existing dam nearby. The reformation methods which reflected the resident's opinions were suggested on EIA in dam development projects. First of all, reliability and objectivity of the field of meteorological phenoma should be enhanced by scientific prediction of the phenomenon days. Secondly, techniques reducing uncertainty of various water quality prediction models ought to be developed and effectiveness of the reduction strategies in environmental impact should be quantified. Finally, the draft of EIA report should involve the detailed plans of migration and compensation's procedures, criteria and measures to support.

Experimental and Numerical Investigation of the Performance of Vertical Thermosyphon for Frozen Ground Stabilization (실험과 수치해석을 통한 동토지반 안정화용 수직형 열사이펀의 성능평가)

  • Lee, Jangguen;Lee, Chulho;Jang, Changkyu;Choi, Changho
    • Journal of the Korean Geosynthetics Society
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    • v.13 no.4
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    • pp.45-56
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    • 2014
  • Frozen ground in cold region consists of an upper active layer and lower permafrost which is permanently frozen land. During the summer season, the air temperature is high enough to make the frozen ground melt, which causes the reduction of soil strength and thaw settlement. These phenomena result in structural instability, so it is necessary to apply frozen ground stability techniques. Thermosyphon is a closed natural two-phase convection device to maintain the ground temperature below $0^{\circ}C$ by extracting heat from the ground and discharges it into the atmosphere. Experimental and numerical investigation has been performed to estimate the effect of the refrigerant filling ratio in thermosyphon using R-134a refrigerant and the thermal conductance of the thermosyphon.

Influence of Temperature and Water Activity on Deleterious Fungi and Mycotoxin Production during Grain Storage

  • Mannaa, Mohamed;Kim, Ki Deok
    • Mycobiology
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    • v.45 no.4
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    • pp.240-254
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    • 2017
  • Cereal grains are the most important food source for humans. As the global population continues to grow exponentially, the need for the enhanced yield and minimal loss of agricultural crops, mainly cereal grains, is increasing. In general, harvested grains are stored for specific time periods to guarantee their continuous supply throughout the year. During storage, economic losses due to reduction in quality and quantity of grains can become very significant. Grain loss is usually the result of its deterioration due to fungal contamination that can occur from preharvest to postharvest stages. The deleterious fungi can be classified based on predominance at different stages of crop growth and harvest that are affected by environmental factors such as water activity ($a_w$) and eco-physiological requirements. These fungi include species such as those belonging to the genera Aspergillus and Penicillium that can produce mycotoxins harmful to animals and humans. The grain type and condition, environment, and biological factors can also influence the occurrence and predominance of mycotoxigenic fungi in stored grains. The main environmental factors influencing grain fungi and mycotoxins are temperature and $a_w$. This review discusses the effects of temperature and $a_w$ on fungal growth and mycotoxin production in stored grains. The focus is on the occurrence and optimum and minimum growth requirements for grain fungi and mycotoxin production. The environmental influence on aflatoxin production and hypothesized mechanisms of its molecular suppression in response to environmental changes are also discussed. In addition, the use of controlled or modified atmosphere as an environmentally safe alternative to harmful agricultural chemicals is discussed and recommended future research issues are highlighted.

Synthesis and Luminescent Characteristics of BaGa2S4:Eu2+ Green Phosphor for Light Emitting Diode (LED용 BaGa2S4:Eu2+ 녹색 형광체의 합성 및 발광특성)

  • Kim, Jae-Myung;Park, Joung-Kyu;Kim, Kyung-Nam;Lee, Seung-Jae;Kim, Chang-Hae
    • Korean Journal of Materials Research
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    • v.16 no.12
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    • pp.761-765
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    • 2006
  • [ $II-III_2-(S,Se)_4$ ] structured of phosphor has been used at various field because those have high luminescent efficiency and broad emission band. Among these phosphors, the europium doped $BaGa_2S_4$ was prepared by solid-state method and had high potential application due to an emissive property of UV region. Also, the common sulfide phosphors were synthesized by using injurious $H_2S\;or\;CS_2$ gas. However, in this study $BaGa_2S_4:Eu^{2+}$ phosphor in addition to excess sulfur was prepared under at 5% $H_2/95%\;N_2$ reduction atmosphere. Thus, this process could be considered as large scale synthesis because of non-harmfulness and simplification. The photoluminescence efficiency of the prepared $BaGa_2S_4:Eu^{2+}$ phosphor increased 20% than that of commercial $SrGa_2S_4:Eu^{2+}$ phosphor. The prepared $BaGa_2S_4:Eu^{2+}$ could be applied to green phosphor for white LED of three wavelengths.

Effect of Oxygen Content on Shape Memory Characteristics of Ti-18Nb-6Zr-XO (X = 0~1.5at%) Alloys (생체용 Ti-18Nb-6Zr-XO (X = 0~1.5at%) 합금의 형상기억특성에 미치는 산소 농도의 영향)

  • Park, Young-Chul;Ock, Ji-Myeon;Oh, Jeong-Hwa;Park, Su-Ho;Lee, Jun-Hee;Kim, Jae-Il
    • Korean Journal of Materials Research
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    • v.21 no.11
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    • pp.617-622
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    • 2011
  • The effect of oxygen on the shape memory characteristics in Ti-18Nb-6Zr-XO (X = 0-1.5 at%) biomedical alloys was investigated by tensile tests. The alloys were fabricated by an arc melting method at Ar atmosphere. The ingots were cold-rolled to 0.45 mm with a reduction up to 95% in thickness. After severe cold-rolling, the plate was solution-treated at 1173 K for 1.8 ks. The fracture stress of the solution-treated specimens increased from 450 Mpa to 880 MPa with an increasing oxygen content up to 1.5%. The fracture stress increased by 287MPa with 1 at% increase of oxygen content. The critical stress for slip increased from 430 MPa to 695 MPa with an increasing oxygen content up to 1.5 at%. The maximum recovery strain of 4.1% was obtained in the Ti-18Nb-6Zr-0.5O (at%) alloy. The martensitic transformation temperature decreased by 140 K with a 1.0 at% increase in O content, which is lower than that of Ti-22Nb-(0-2.0)O (at%) by 20 K. This may have been caused by the effect of the addition of Zr. This study confirmed that addition of oxygen to the Ti-Nb-Zr alloy increases the critical stress for slip due to solid solution hardening without being detrimental to the maximum recovery strain.