• Title/Summary/Keyword: Reduction atmosphere

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A Study on the 4-level quasi-geostropic numerical model (4층 준지균 수치모형에 관한 연구)

  • 이우진;이천우
    • Water for future
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    • v.17 no.3
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    • pp.211-219
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    • 1984
  • A 4-level baroclinic numerical model is designed by using the vorticity equation and Omega equation. Block-Cyclic-Reduction method is applied to the solution of the Helmholtz defferential equation, which is proved to be better than the Relaxation method from the composite viewpoint of accuracy, stability and economy. It was investigated whether the model explains the physical process influenced by voricity and temperature advection. It was also examined if the model atmosphere describes the general circulation. This examination is similar to Phillips(1956). The result of this numerical experiment shows that the model explains qualitatively the Quasi-Geostrophic theory for the development of Baroclinic wave, as throughly described in Holton(1972).

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The Effect of $NH_3$ Annealing for Gate Oxide (게이트 산화막에 대한 암모니아 어닐링의 효과)

  • 김영조;김철주
    • Proceedings of the Materials Research Society of Korea Conference
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    • 1992.05b
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    • pp.57-58
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    • 1992
  • The NH$_3$oxidation, which forms thermal oxide layer on silicon substrate with pure $O_2$gas added with small amounts of NH$_3$gas, has good interface sates due to activated gettering effect during oxidation. The superiority of interfae state in NH$_3$ oxidation method is not affected by preprocess but by gettering during oxidation. The dramatec reduction fo interface state is conformed with observing OSF when NH$_3$ oxide is annealed in NH$_3$ atmosphere.

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Retrofit Scheme against Crack Growth of ILM Bridge Superstructure in accordance with Each Construction Stage (시공단계별 ILM 교량상부의 균열성장에 대한 보강방안)

  • 이창수;김승익;김현겸
    • Proceedings of the Korea Concrete Institute Conference
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    • 2000.10b
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    • pp.1001-1006
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    • 2000
  • These should be constructed partially, because many prestressed concrete box girder bridges in situ have large cross section and long span. Therefore, accurate prediction of differences, both elapse time of each construction stage and exposure of atmosphere at each position of cross section, is very important. Though it is importance, engineers are apt to overlook it. This study predicted cracks due to shrinkage and stress concentration phenomenon by each construction stage and then, ascertained reduction of tensile stresses after applying retrofit scheme.

Preparation of BaTiO3 Powder in $BaO2-TiO2-Reduction Agent-PSCA (Particle Size Control Agent) System by SHS and Its Dielectric Properties (B3O2-TiO2-환원제-입자제어제계에서 자전연소합성법에 의한 BaTiO3분말의 제조 및 유전특성)

  • Yun, Ki-Seok;Lim, Sung-Jae;Nersisyan, Hayk;Won, Chang-Whan
    • Journal of the Korean Ceramic Society
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    • v.41 no.11
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    • pp.842-850
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    • 2004
  • We have investigated on the preparation of BaTiO$_3$ powder at the system of BaO$_2$-TiO$_2$-Reduction ag.-PSCA by SHS. C and Mg were used as reduction agent, and NaCl was used as PSCA (Particle Size Control Agent). The effects of the various reduction agent and its concentration, particle size control agent, reaction mixture mass on the product in the preparation of BaTiO$_3$ powder at the optimum system by SHS were investigated. The optimum conditions for reaction system and composition were BaO$_2$+TiO$_2$+0.11 Mg +0.2C+0.75NaCl in the As atmosphere. NaCl as PSCA showed the effect of controlling the particle size of product as well as the combustion temperature. The particle size of BaTiO$_3$ synthesized at the optimum condition was about 0.5 ${\mu}{\textrm}{m}$. And as the mixture mass for the reaction was increased, the more stable combustion wave appeared. We have conducted the sintering experiment at the temperature of 130$0^{\circ}C$, the time of 2 h and the atmosphere of air to measure the dielectric properties of BaTiO$_3$ synthesised in this work, and the sample sintered in this condition showed 2,290 of dielectric constant at 10$0^{\circ}C$ and 13,890 at curie point (129$^{\circ}C$).

Effect of Modified Atmosphere Packaging on Preservation of Pumpkin Rice Cake (호박 설기떡의 저장성에 미치는 변형기체포장의 영향)

  • Moon, Ki-Bok;Kim, Hwan-Ki;An, Duck-Soon;Lee, Dong-Sun
    • Food Science and Preservation
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    • v.17 no.6
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    • pp.908-913
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    • 2010
  • Modified atmosphere packaging (MAP) was evaluated for the storage of pumpkin rice cake as a means of preserving quality and extending shelf-life. Retail-sized amounts of rice cake were packaged in trays under different modified atmosphere conditions (air, vacuum, 60% $CO_2$/40% $N_2$ and 100% $CO_2$) using gas-barrier plastic film; control was in air-permeable stretch wrap. The packages were stored at $20^{\circ}C$ with periodical measurement of package atmosphere and cake quality attributes. The modified atmosphere packages of 60% $CO_2$/40% $N_2$ and 100% $CO_2$ inhibited the growth of molds/yeasts completely and significantly retarded the growth of aerobic bacteria. All the packages except that of 100% $CO_2$ showed the reduction of internal $O_2$ concentration and increase of the $CO_2$ with storage time due to the microbial activity. There has been slight decrease of $CO_2$ concentration for 60% $CO_2$/40% $N_2$ and 100% $CO_2$ packages just after start of the storage possibly due to dissolution of headspace $CO_2$ into the cake. Any MAP conditions did not affect the retrogradation of the rice cake. Surface color of the cake within affordable microbial quality limit was not affected significantly by packaging conditions.

A Study on the Model of Competitive Electricity Market Considering Emission Trading (온실가스 배출권 거래제도를 고려한 경쟁적 전력시장 모형 연구)

  • Kim, Sang-Hoon;Lee, Kwang-Ho;Kim, Wook
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.58 no.8
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    • pp.1496-1503
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    • 2009
  • The United Nations Framework Convention on Climate Change (UNFCCC) is an international environmental treaty to stabilize greenhouse gas concentrations in the atmosphere. In order to fulfil the commitments of the countries in an economically efficient way, the UNFCCC adapted the emission trading scheme in the Kyoto Protocol. If the UNFCCC's scheme is enforced in the country, considerable changes in electric power industry are expected due to the imposed greenhouse gas emission reduction. This paper proposes a game theoretic model of the case when generation companies participate in both competitive electricity market and emission market simultaneously. The model is designed such that generation companies select strategically between power quantity and greenhouse gas reduction to maximize their profits in both markets. Demand function and Environmental Welfare of emission trading market is proposed in this model. From the simulation results using the proposed model the impact of the emission trading on generation companies seems very severe in case that the emission prices are significantly high.

Synthesis and Characteristics of W-l5wt%Cu Nanocomposite Powder by Oxide Reduction (산화물환원에 의한 W-15wt%Cu 나노복합분말의 합성과 특성)

  • 윤의식
    • Journal of Powder Materials
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    • v.4 no.4
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    • pp.304-309
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    • 1997
  • The synthesis of W-l5wt%Cu nanocomposite powder by hydrogen reduction of ball milled W-Cu oxide mixture was investigated in terms of powder characteristics such as particle size, mixing homogeneity and micropore structure. It is found that the micropores in the ball milled oxide (2-50 nm in size) act as an effective removal path of water vapor, followed by the formation of dry atmosphere at reaction zone. Such thermodynamic condition enhances the nucleation of W phase but suppresses the growth process, being in favor of the formation of W nanoparticles (about 21 nm in size). In addition, the superior mixing homogeneity of starting oxide mixture turned out to Play a significant role for forming extraordinary chemical homogeneity of W-l5wt%Cu nanocomposite powder.

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Microstructure of W-Cu Composite Powders with Variation of Milling Method during Mechanochemical Process (기계화학적 공정의 밀링 방법에 따른 W-Cu 복합분말의 미세조직)

  • 이강원;김길수;김대건;김영도
    • Journal of Powder Materials
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    • v.9 no.5
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    • pp.329-335
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    • 2002
  • Recently, the fabrication process of the W-Cu nanocomposite powders has been studied to improve the sinterability through the mechanical alloying and reduction of W and Cu oxide mixtures. In this study. the W-Cu composites were produced by mechanochemical process (MCP) using $WO_3-CuO$ mixtures with two different milling types of low and high energy, respectively. These ball-milled mixtures were reduced in $H_2$ atmosphere. The ball-milled and reduced powders were analyzed through XRD, SEM and TEM. The fine W-Cu powder could be obtained by the high energy ball-milling (HM) compared with the large Cu-cored structure powder by the low energy ball-milling (LM). After the HM for 20h, the W grain size of the reduced W-Cu powder was about 20-30 nm.

Synthesis of 2'-Hydroxydihydrochalcone from Flavone

  • Kim, Mi-Hyang;Shin, Bok-Kyu;Won, Dong-Ho;Han, Jae-Hong
    • Journal of Applied Biological Chemistry
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    • v.50 no.2
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    • pp.85-87
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    • 2007
  • To establish the synthetic method for dihydrochalcones as an important bioactive compounds, 2'-hydroxydihydrochalcone has been synthesized from the reduction of flavone in 20% yield. Flavone with five equivalents of ammonium formate in the presence of Pd/C in methanol under $N_2$ atmosphere produced the C-ring opened product. It was characterized by UV-VIS, ESI-MS and $^1H-NMR$ spectroscopy, and identified as 2'-hydroxydihydrochalcone.

Mechanical and Tribological Properties of $\beta-Sialon/SiC$ Whisker Composite ($\beta-Sialon/SiC$ Whisker 복합재료의 기계적 물성 및 마찰 마모 특성 연구)

  • 김호균;소유영;김인섭;이병하
    • Journal of the Korean Ceramic Society
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    • v.31 no.11
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    • pp.1259-1264
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    • 1994
  • $\beta$-Sialon has been regarded as one of promising materials showing high strength, fracture toughness, corrosion resistence and wear resistence. The improvement of the fracture toughness and tribological properties of $\beta$-Sialon (Z=1) has been attempeted by fabricating the $\beta$-Sialon/ SiC whisker composite. Each of green body composed of following ingredients, i.e., Si3N4, AlN, Y2O3 nd SiC, respectively, was first fired at 178$0^{\circ}C$ for 3hrs in N2 atmosphere and then post-HIPed at 173$0^{\circ}C$ for 1 hr under 170 MPa for N2 gas pressure. The fracture toughness, flexural strength and tribological properties increased with increasing SiC whisker content, despite the reduction of the relative density and hardness. $\beta$-Sialon/15 vol% SiC whisker showed a significant enhancement of wear resistance compared to the monolithic $\beta$-Sialon. The addition of SiC whisker caused the reduction of the density and hardness, but induced the increment of wear resistance.

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