• Title/Summary/Keyword: Reduced-scale experiments

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Degradation of energetic compounds using an integrated zero-valent iron-Fenton process

  • Oh Seok-Young;Kim Byung J.;Chiu Pei C.;Cha Daniel K.
    • 한국지구물리탐사학회:학술대회논문집
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    • 2003.11a
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    • pp.493-500
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    • 2003
  • The effect of reductive treatment with elemental iron on the extent of mineralization by Fenton oxidation was studied for the explosive 2,4,6-trinitrotoluene (TNT) and hexahydro-l,3,5-trinitro-l,3,5-triazine (RDX) using a completely-stirred tank reactor (CSTR). The results support the hypothesis that TNT and RDX are reduced with elemental iron to products that are oxidized more rapidly and completely by Fenton's reagent. Iron pretreatment enhanced the extent of TOC removal by approximately $20\%\;and\;60\%$ for TNT and RDX, respectively. Complete TOC removal was achieved for TNT and RDX solutions with iron pretreatment under optimal conditions. On the other hand, without iron pretreatment, complete mineralization of TNT and RDX solutions were not achieved even with much higher $H_2O_2$ and $Fe^{2+}$ concentrations. The bench-scale iron treatment-Fenton oxidation integrated system showed more than $95\%$ TOC removal for TNT and RDX solutions under optimal conditions. The proposed zero-valent iron-Fenton process was evaluated with pink water from the Iowa Army ammunition plant. Results from batch and column experiments show that TNT, RDX, and octahydro-l,3,5,7-tetranitro-l,3,5,7-tetrazocine (HMX) were completely removed from the pink water and that triaminotoluene (TAT) and ${NH_4}^+$ were recovered as products in reduction with zero-valent iron. By using an integrated system, $83.3\pm4.2\%$ of TOC was removed in a CSTR with 10 mM of $Fe^{2+}$ and 50 mM of $H_2O_2$. These results suggest that the reduction products of TNT and RDX are more rapidly and completely mineralized by Fenton oxidation and that a sequential iron treatment-Fenton oxidation process may be a viable technology for pink water treatment.

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Manganese Removal of Bank Filtrate using Manganese Sand Filtration (망간모래여과를 이용한 강변여과수의 망간제거)

  • Kim, Chung-Hwan;Kim, Hak-Chul;Kim, Han-Seung;Kim, Berm-Soo;Ahn, Hyo-Won
    • Journal of Korean Society on Water Environment
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    • v.20 no.5
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    • pp.409-414
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    • 2004
  • Pilot-scale experiments were performed for the treatment of bank filtrate contammg high manganese concentration around 2mg/L using rapid manganese sand filtration to investigate effects of oxidant dose and pH control on the removal efficiency of manganese. For theoretical dose ranges of oxidant (sodium hypochlorite) between 3 and 4mg/L, the manganese concentration of effluent was 0.57 mg/L, which corresponded to 72.5% removal and was higher than drinking water quality standards of 0.3mg/L. For excess dose ranges of oxidant between 4 and 8mg/L, the manganese concentration of effluent was reduced to 0.14mg/L, which corresponded to 94.5% removal, but the residual chlorine concentration was over 1.0mg/L. On the other hand, manganese removal efficiency drastically increased up to the value of 98.0%, which is equivalent to the effluent concentration of 0.03mg/L by controling pH to the range between 7 and 8 for the theoretical dose of oxidant. Consequently, these results indicated that appropriate dose of chemicals, such as oxidant and alkali, and continuous monitoring of manganese should be necessary to obtain efficient removal of manganese and to optimize the maintenance of treatment facilities for the treatment of bank filtrate with high concentration of manganese.

Measurements of Ablations on Nozzle Throats of KL-3 Engines Using Image Analysis (영상분석을 통한 KL-3 엔진 노즐목 삭마량 측정)

  • 김영한;고영성;박성진;류철성;강선일;오승협
    • Journal of the Korean Society of Propulsion Engineers
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    • v.7 no.3
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    • pp.1-7
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    • 2003
  • In this research, it is intended to measure shape of the nozzle throat of the KL-3 engine, which is the main engine of the KSR-III rocket. For the purpose, an image-based method was invented to replace the 3D pointer, which is actually inaccessible to such large scale engines. As a result, our equipment showed satisfactory Performances. Analysing the results of experiments, we find that the pattern of ablation is determined by the spray pattern and that the process of thermal ablation phenomena can be categorized in three regimes - the first regime that the shape of nozzle throat is maintained and ablation is negligible, the second regime that saw-tooth form is developed and ablation is accelerated, and the third regime that the saw-tooth form is already established and the growth of ablation rate is reduced Also, we find that the ratio of area increase after 60 seconds combustion is +5.82% and conclude that the ratio is acceptable and satisfactory.

An Experimental Study on the Performance of Multi-Diameter Lateral for Riverbed Filtration (하상여과용 다직경 수평집수관의 효능에 대한 실험연구)

  • Bae, Gha-Ram;Kim, Seung-Hyun
    • Journal of Korean Society of Environmental Engineers
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    • v.34 no.5
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    • pp.359-364
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    • 2012
  • In order to prevent the decrease in well efficiencies due to friction in the axial flow in long, large-diameter laterals, a multi-diameter lateral was devised and tested through lab-scale sand-box experiments to assess its performance. In the experiment, three different production rates were applied over the multi-diameter and the three single-diameter laterals to obtain the hydraulic head distributions for each, which was used to assess the performance of the laterals. Results elucidated that the multi-diameter lateral reduced the material cost by more than a third, in comparison to the single-diameter lateral, while maintaining the production rate at higher than 93%, proving its superiority. Furthermore, results indicated that exit velocities exceeding 0.8 m/sec in horizontal wells tended to distort the hydraulic head distribution near the exit, providing evidence of its inefficiency.

Effect of the supernatant reflux position and ratio on the nitrogen removal performance of anaerobic-aerobic slaughterhouse wastewater treatment process

  • Tong, Shuang;Zhao, Yan;Zhu, Ming;Wei, Jing;Zhang, Shaoxiang;Li, Shujie;Sun, Shengdan
    • Environmental Engineering Research
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    • v.25 no.3
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    • pp.309-315
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    • 2020
  • Slaughterhouse wastewater (SWW) is characterized as one of the most harmful agriculture and food industrial wastewaters due to its high organic content. The emissions of SWW would cause eutrophication of surface water and pollution of groundwater. This study developed a pilot scale anaerobic-aerobic slaughterhouse wastewater treatment process (AASWWTP) to enhance the chemical oxygen demand (COD) and total nitrogen (TN) removal. The optimum supernatant reflux position and ratio for TN removal were investigated through the modified Box-Behnken design (BBD) experiments. Results showed that COD could be effectively reduced over the whole modified BBD study and the removal efficiency was all higher than 98%. The optimum reflux position and ratio were suggested to be 2 alure and 100%, respectively, where effluent TN concentration was satisfied with the forthcoming Chinese discharge standard of 25 mg/L. Anaerobic digestion and ammonia oxidation were considered as the main approaches for COD and TN removal in the AASWWTP. The results of inorganic nutrients (K+, Na+, Ca2+ and Mg2+) indicated that the SWW was suitable for biological treatment and the correspondingly processes such as AASWWTP should be widely researched and popularized. Therefore, AASWWTP is a promising technology for SWW treatment but more research is needed to further improve the operating efficiency.

The Effects of Chuna for Thoracic in Patients with Nuchal Pain, Seven Cases Report (흉추의 추나요법을 시행한 경항통 환자 치험 7례 보고)

  • Cho, Dong-In;Yoon, Jeong-won;Kim, Soon-Joong;Park, Dong-Su
    • Journal of Korean Medicine Rehabilitation
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    • v.25 no.4
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    • pp.147-159
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    • 2015
  • Objectives The purpose of this study is to investigate the clinical application of chuna for thoracic in the patients with nuchal pain. Methods Seven patients were treated by chuna for thoracic to evaluate the effect of the treatment. The patient's symptoms were assessed by visual analogue scale (VAS), neck disability index (NDI) and cervical lordotic curvature. Results In all cases, the pain was reduced according to VAS, NDI. Cervical lordotic curvature of 6 cases were improved in terms of Jackson's angle. 5 cases were improved in terms of Depth of cervical curve and Method of Jochumsen. 4 cases were improved in terms of Angle of cervical curve (C2~C7) and Ishihara index. 3 cases were improved in terms of Angle of cervical curve (C1~C7). Conclusions These results suggest that chuna on thoracic might be an effective method to treat nuchal pain with extension malposition of thoracic. But, it's necessary to have more observations and experiments.

Total-internal-reflection Holographic Photo-lithography by Using Incoherent Light (비가간섭광을 이용한 내부전반사 홀로그래픽 리소그라피)

  • Lee, Joon-Sub;Park, Woo-Jae;Lee, Ji-Whan;Song, Seok-Ho;Lee, Sung-Jin
    • Korean Journal of Optics and Photonics
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    • v.20 no.6
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    • pp.334-338
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    • 2009
  • Recently, with increasing demand for flat-panel display product, methods for large area patterning are required. TIR (total internal reflection) holographic photo-lithography isstudied as one of the methods of large area lithography. In conventional TIR holography, light sources for hologram recording and image reconstruction are coherent beams such as laser beams. If the image is reconstructed with an incoherent light source such a UV lamp, the image noise from the coherence of light will be reduced and the UV lamp will be a better light source for large area exposure. We analyzed the effect of spectral bandwidth and angular bandwidth of the light source in image reconstruction and verified image blurring with experiments. For large area patterning which has micro-scale line width, it is expected that TIR holographic photo lithography by UV lamp will become a low-noise and low-priced technique.

Reduction of Hydrogen Sulphide in Chicken Manure by Immobilized Sulphur Oxidising Bacteria Isolated from Hot Spring

  • Hidayat, M.Y.;Saud, H.M.;Samsudin, A.A.
    • Microbiology and Biotechnology Letters
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    • v.47 no.1
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    • pp.116-124
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    • 2019
  • The rapid development of the poultry industry has led to the production of large amounts of manure, which produce substances like hydrogen sulfide ($H_2S$) that contribute to odor pollution. $H_2S$ is a highly undesirable gas component and its removal from the environment is therefore necessary. Sulfur-oxidizing bacteria (SOB) are widely known to remove contaminating $H_2S$ due to their ability to oxidize reduced sulfur compounds. In this study, three potential SOB (designated AH18, AH25, and AH28) that were previously isolated from a hot spring in Malaysia were identified by 16S rRNA gene analysis. Laboratory-scale biological deodorization experiments were conducted to test the performance of the three isolates-in the form of pure or mixed cultures, with the cells immobilized onto alginate as a carrier-in reducing the $H_2S$ from chicken manure. On the basis of 16S rRNA phylogenetic analysis, isolate AH18 was identified as Pseudomonas sp., whereas isolates AH25 and AH28 were identified as Achromobacter sp. The most active deodorizing isolate was AH18, with an $H_2S$ reduction rate of 74.7% (p < 0.05). Meanwhile, the reduction rates for isolates AH25 and AH28 were 54.2% and 60.8% (p > 0.05), respectively. However, the $H_2S$ removal performance was enhanced in the mixed culture, with a reduction rate of 81.9% (p < 0.05). In conclusion, the three potential SOB isolates were capable of reducing the $H_2S$ from chicken manure in the form of a pure culture immobilized on alginate, and the reduction performance was enhanced in the mixed culture.

An Efficient Application of XML Schema Matching Technique to Structural Calculation Document of Bridge (XML 스키마 매칭 기법의 교량 구조계산서 적용 방안)

  • Park, Sang Il;Kim, Bong-Geun;Lee, Sang-Ho
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.32 no.1D
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    • pp.51-59
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    • 2012
  • An efficient application method of XML schema matching technique to the document structure of structural calculation document (SCD) of bridge is proposed. With 30 case studies, a parametric study on weightings of name, sibling, child, and parent elements of XML scheme component that are used in the similarity measure of XML schema matching technique has been performed, and suitable weighting to analyze document structure of SCD is suggested. A simplified formula for quantification of similarity is also introduced to reduce computation time in huge scale document structure of SCDs. Numerical experiments show that the suggested method can increase the accuracy of XML schema matching by 10% with suitable weighting parameters, and can maintain almost the same accuracy without weighting parameters compared to previous studies. In addition, computation time can be reduced dramatically when the proposed simplified formula for the quantification of similarity is used. In the numerical experiments of testing 20 practical SCDs of bridges, the suggested method is superior to previous studies in the accuracy of analyzing document structure and 4 to 460 times faster than the previous results in computation time.

A Mobility Management Scheme based on the Mobility Pattern of Mobile Networks (이동 네트워크의 이동 패턴에 기반을 둔 이동성 관리 기법)

  • Yang, Sun-Ok;Kim, Sung-Suk
    • Journal of KIISE:Information Networking
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    • v.35 no.4
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    • pp.345-354
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    • 2008
  • Recently, small-scale mobile network which is composed of many mobile devices in a man becomes popular. Also, Examples of large-scale mobile network can be thought access networks deployed on public transportation such as ships, trains and buses. To provide seamless mobility for mobile nodes in this mobile network, binding update messages must be exchanged frequently. However, it incurs network overhead increasingly and decreases energy efficiency of mobile router. If we try to reduce the number of the messages to cope with the problem, it may happen the security -related problems conversely Thus, mobile router needs a effective algorithm to update location information with low cost and to cover security problems. In this paper, mobility management scheme based on mobile router's mobility pattern is proposed. Whenever each mobile router leaves a visiting network, it records related information as moving log. And then it periodically computes mean resident time for all visited network, and saves them in the profile. If each mobile router moves into the visited network hereafter, the number of binding update messages can be reduced since current resident time may be expected based on the profile. At this time, of course, security problems can happen. The problems, however, are solved using key credit, which just sends some keys once. Through extensive experiments, bandwidth usages are measured to compare binding update messages in proposed scheme with that in existing scheme. From the results, we can reduce about 65% of mobility-management-related messages especially when mobile router stays more than 50 minutes in a network. Namely, the proposed scheme improves network usage and energy usage of mobile router by decreasing the number of messages and authorization procedure.