• 제목/요약/키워드: Red Emission

검색결과 625건 처리시간 0.024초

White Organic Light Emitting Diodes using Red and Blue Phosphorescent Materials with Blocking Layer

  • Park, Jung-Hyun;Kim, Gu-Young;Lee, Seok-Jae;Seo, Ji-Hyun;Seo, Ji-Hoon;Kim, Young-Kwan
    • Transactions on Electrical and Electronic Materials
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    • 제8권5호
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    • pp.218-221
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    • 2007
  • High-efficiency white organic light-emitting diodes(WOLEDs) were fabricated with two emissive layers and an blocking layer was sandwiched between two phosphorescent dopants, bis(3,5-difluoro-2-(2-pyridyl)phenyl-(2-carboxypyridyl) iridium III(FIrpic) as the blue emission and a newly synthesized red phosphorescent material guest, bis(5-acetyl-2-phenylpyridinato-N,C2') acetylacetonate($(acppy)_2Ir(acac)$). This blocking layer prevented a T-T annihilation in a red emissive layer, and balanced with blue and red emission as blocking of hole carriers. The white device showed Commission Internationale d'Eclairage($CIE_{x,y}$) coordinates of (0.317, 0.425) at 22400 $cd/m^2$, a maximum luminance of 27300 $cd/m^2$ at 268 $mA/cm^2$, a maximum luminous efficiency and power efficiency of 26.9 cd/A and 18.6 lm/W.

물-메탄올 혼합용액과 계면활성제 용액에서 나프탈렌 나트륨 유도체들의 소수성 상호작용 (Hydrophobic Interaction of Sodium Naphthalene Derivatives in $H_2O$-MeOH Mixture Solutions and in Surfactant Solutions)

  • 최성호;박근수;장주환;김학진
    • 분석과학
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    • 제11권6호
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    • pp.413-420
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    • 1998
  • 물-메탄올 혼합 용액과 계면활성제 용액에서 1-나프탈렌아세트산 나트륨염, 1-나프탈렌말론산 나트륨염, 2-나프탈렌아세트산 나트륨염과 2-나프탈렌프로피온산 나트륨염과 같은 나프탈렌 나트륨 유도체들의 소수성 상호작용에 대해서 연구하였다. 물-메탄올 혼합 용액에서 소수성 상호작용을 측정하였고, 방출선은 red shift가 일어났다. 양이온 계면활성제인 세틸트리메틸암모늄 브롬화 용액에서도 흡수, 방출선은 red shift됨을 보여주었다.

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Novel Red Electroluminescent Material with Indandion Pyran Molecular Backbone

  • Kim, Dong-Uk;Tak, Yoon-Heung;Han, Yoon-Soo;Kim, Sang-Dae;Kim, Ki-Beom;Kim, Tae-Jeong;Baek, Jeong-Ju;Park, Lee-Soon
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2003년도 International Meeting on Information Display
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    • pp.914-916
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    • 2003
  • Novel red organic electroluminescent (EL) dye, RED was developed for an application to the emission layer of EL device. Well known red material DCJTB was also used for comparison. Two kinds of devices were fablicated; one is ITO/ CuPc / TPD / 0.5% RED-1 in Alq3/ Alq3/ Li20/ Al and the other is ITO/ CuPc /TPD / 0.5% DCJTB in Alq3/Alq3/ Li20 / Al. External quantum efficiency of the EL device with RED was two times higher than that of the device with DCJTB. The maximum EL peak was detected at 635nm in the RED EL device.

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Low voltage driving red phosphorescent organic light-emitting devices

  • Kim, Tae-Yong;Suh, Won-Gyu;Moon, Dae-Gyu
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2008년도 International Meeting on Information Display
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    • pp.461-464
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    • 2008
  • We have developed low voltage driving red phosphorescent organic light-emitting devices using a new electron transport layer. $Ir(piq)_3$ and CBP were used as a phosphorescent dopant and an emission host, respectively. The device exhibits a luminance of $1000\;cd/m^2$ at a voltage of 2.8 V. This high luminance at low voltage results from a high electron conduction behavior of the new electron transport layer.

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Synthesis and Characterization of Red Electrophosphorescent Polymers Containing Pendant Iridium(III) Complex Moieties

  • Xu, Fei;Mi, Dongbo;Bae, Hong Ryeol;Suh, Min Chul;Yoon, Ung Chan;Hwang, Do-Hoon
    • Bulletin of the Korean Chemical Society
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    • 제34권9호
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    • pp.2609-2615
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    • 2013
  • A series of fluorene-carbazole copolymers containing the pendant phosphor chromophore $Ir(absn)_2(acac)$ (absn: 2-(1-naphthyl)benzothiazole; acac: acetylacetone) were designed and synthesized via Yamamoto coupling. In the film state, these copolymers exhibited absorption and emission peaks at approximately 389 and 426 nm, respectively, which originated from the fluorene backbone. However, in electroluminescent (EL) devices, a significantly red-shifted emission at approximately 611 nm was observed, which was attributed to the pendant iridium(III) complex. Using these copolymers as a single emission layer, polymer light-emitting devices with ITO/PEDOT:PSS/polymer:DNTPD/TmPyPb/LiF/Al configurations exhibited a saturated red emission at 611 nm. The attached iridium(III) complex had a significant effect on the EL performance. A maximum luminous efficiency of 0.85 cd/A, maximum external quantum efficiency of 0.77, maximum power efficiency of 0.48 lm/W, and maximum luminance of 883 $cd/m^2$ were achieved from a device fabricated with the copolymer containing the iridium(III) complex in a 2% molar ratio.

Simultaneous observations of SiO and $H_2O$ masers toward AGB and post-AGB stars

  • 윤동환;조세형;김재헌;조치영;윤영주;박용선
    • 천문학회보
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    • 제37권2호
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    • pp.237.2-237.2
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    • 2012
  • We performed simultaneous observations of SiO v=1, 2, $^{29}SiO$ v=0, J=1-0 and $H_2O$ $6_{16}-5_{23}$ maser lines toward 132 AGB and 183 post-AGB stars in order to investigate how evolutionary characteristics from AGB to post-AGB stars appear in these two maser emissions. The observations were carried out from 2011 February to 2012 March using the Korean VLBI Network 21-m radio telescopes. We have detected SiO and/or $H_2O$ maser emission from 29 sources out of 183 post-AGB stars including 19 new detections. Of 132 AGB stars which are mainly selected based on the IRAS Point Source Catalog, we detected SiO and/or $H_2O$ maser emission from 38 stars including 18 newly detected sources. An evolutionary characteristic from AGB to post-AGB stars is discussed in IRAS two-color diagram. It is found that SiO v=2, J=1-0 maser emission without SiO v=1 maser detections was detected from 8 sources among 21 SiO detected post-AGB stars and the intensity of SiO v=2, J=1-0 maser tends to be much stronger than that of SiO v=1. We also found that for the post-AGB stars the maser detection rate of blue group sources (which have higher outflow velocities than red group) are higher than that of red group. Especially, only $H_2O$ maser emission was detected from 7 sources among 94 red group sources without SiO maser detections.

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적색 형광체 Gd1-xAl3(BO3)4:Eux3+의 합성과 발광 특성 (Synthesis and Photoluminescence Properties of Red Phosphors Gd1-xAl3(BO3)4:Eux3+)

  • 조신호;조선욱
    • 한국재료학회지
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    • 제22권3호
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    • pp.145-149
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    • 2012
  • Red phosphors of $Gd_{1-x}Al_3(BO_3)_4:{Eu_x}^{3+}$ were synthesized by using the solid-state reaction method. The phase structure and morphology of the phosphors were measured using X-ray diffraction (XRD) and field emission-scanning electron microscopy (FE-SEM), respectively. The optical properties of $GdAl_3(BO_3)_4:Eu^{3+}$ phosphors with concentrations of $Eu^{3+}$ ions of 0, 0.05, 0.10, 0.15, and 0.20 mol were investigated at room temperature. The crystals were hexagonal with a rhombohedral lattice. The excitation spectra of all the phosphors, irrespective of the $Eu^{3+}$ concentrations, were composed of a broad band centered at 265 nm and a narrow band having peak at 274 nm. As for the emission spectra, the peak wavelength was 613 nm under a 274 nm ultraviolet excitation. The intensity ratio of the red emission transition ($^5D_0{\rightarrow}^7F_2$) to orange ($^5D_0{\rightarrow}^7F_1$) shows that the $Eu^{3+}$ ions occupy sites of no inversion symmetry in the host. In conclusion, the optimum doping concentration of $Eu^{3+}$ ions for preparing $GdAl_3(BO_3)_4:Eu^{3+}$ phosphors was found to be 0.15 mol.

Porphyromonas gingivalis가 일부 구강미생물의 형광 발현에 미치는 영향 (Red fluorescence of oral bacteria interacting with Porphyromonas gingivalis)

  • 김세연;우동협;이민아;김지수;이정하;정승화
    • Journal of Korean Academy of Oral Health
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    • 제41권1호
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    • pp.22-27
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    • 2017
  • Objectives: Dental plaque is composed of 700 bacterial species. It is known that some oral microorganisms produce porphyrin, and thus, they emit red fluorescence when illuminated with blue light at a specific wavelength of <410 nm. Porphyromonas gingivalis belongs to the genus Porphyromonas, which is characterized by the production of porphyrin. The aim of this study was to evaluate red fluorescence emission of some oral microorganisms interacting with P. gingivalis. Methods: Five bacterial strains (P. gingivalis, Streptococcus mutans, Lactobacillus casei, Actinomyces naeslundii, and Fusobacterium nucleatum) were used for this study. Tryptic soy agar medium supplemented with hemin, vitamin K3, and sheep blood was used as a growth medium. The fluorescence emission of bacterial colonies was evaluated under 405 nm-wavelength blue light using a Quantitative Light-induced Fluorescence Digital (QLF-D) camera system. Each bacterium was cultured alone and co-cultured in close proximity with P. gingivalis. The red/green (R/G) ratio of fluorescence image was calculated and the differences of R/G ratio according to each growth condition were compared using the Mann-Whitney test (P<0.05). Results: Single cultured S. mutans, L. casei and A. naeslundii colonies emitted red fluorescence (R/G ratio=$2.15{\pm}0.06$, $4.31{\pm}0.17$, $5.52{\pm}1.29$, respectively). Fusobacterium nucleatum colonies emitted green fluorescence (R/G ratio=$1.36{\pm}0.06$). The R/G ratios of A. naeslundii and F. nucleatum were increased when P. gingivalis was co-cultured with each bacterium (P<0.05). In contrast, the R/G ratios of S. mutans and L. casei were decreased when P. gingivalis was co-cultured with each bacterium (P=0.002, 0.003). Conclusions: This study confirmed that P. gingivalis could affect the red fluorescence of other oral bacteria under 405 nm-wavelength blue light. Our findings concluded that P. gingivalis has an important role for red fluorescence emission of dental biofilm.

전기인광을 이용한 고효율 적색 유기 전기발광소자 (Efficient red organic light-emitting devices based on electrophosphorescence)

  • 송원준;강기욱;박수연;설창;이창희
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2000년도 춘계학술대회 논문집 디스플레이 광소자 분야
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    • pp.121-124
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    • 2000
  • Achieving red light-emitting diodes with high quantum and luminous efficiency is required to fabricate the full-color organic electroluminescence display. In this work, we report that devices with 2.3,7,8,12,13,17,18-Octaethyl-21H,23H-porphine palladium (II) (PdOEP), doped into tris(8-Hydroxyquinolinato)-aluminum (III) (Alq3) show a narrow deep red emission (670nm). In addition, PdOEP has been used as host material in which red dyes such as 4-(Dicyanomethylene)-2-methyl-6-(4-dimethylaminostyryl)-4H-pyran (DCM) doped in order to fabricate efficient red-emitting diodes.

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Establishing the Black Hole Mass Estimator of Active Galactic Nuclei with Hydrogen Brackett Lines

  • 김도형;임명신
    • 천문학회보
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    • 제36권1호
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    • pp.51.1-51.1
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    • 2011
  • Red dusty Active Galactic Nuclei (AGNs) are suspected to mid-stage between ULIRG and AGN phase. As well as, red AGNs are suspected that they have more than 50% of whole AGN population. In order to understand the character of red AGNs, Black Hole (BH) mass of red AGN is a key property and can not measured by existing method such as reverberation mapping and single epoch method. Thus we still don't know their character and properties in clearly. To estimate properties of red AGNs without the effect of dust-obscuration, we have obtained Near InfraRed (NIR) spectra of 31 reverberation mapped AGNs and 49 Palomar-Green(PG) Quasi-Stellar Object (QSO) by using the infrared camera (IRC) for AKARI with unique wavelength range $2.5-5.0{\mu}m$. From this spectra, we measured the FWHM and luminosity of brackett ${\alpha}$ and ${\beta}$ at 4.0, 2.6 micron meter for deriving new BH mass estimators based on the properties of Brackett line emission.

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