• Title/Summary/Keyword: Recycling oil

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A Study on the Remediation using Microbial Activator from Oil-Contaminated Soil (미생물활성화제를 이용한 유류오염토양 복원에 관한 연구)

  • Lee, Chae-Young;Chung, Chan-Kyo;Kim, Jong-Moon
    • Journal of the Korea Organic Resources Recycling Association
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    • v.19 no.2
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    • pp.41-48
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    • 2011
  • In this study, the soil remediation by landfarming was carried out using microbial activators. Feasibility studies and reduction capacity of TPH(Total Petroleum Hydrocarbons) were investigated in order to find out how fast and eco-friendly the contaminated soil can be recovered. The lab-test confirmed not only the performance and degradation efficiency of microbial activators but also the effect of TPH reduction in the contaminated soil. The optimum growth conditions for indigenous microorganisms were identified using microbial activators. Based on the results of TPH removal, although there had been a little of difference in between natural decomposition and microbial activators until 20 days, the sample groups of microbial activators were higher than the control ones after 20 days. Microbial activators were applied to the field experiments on landfarming. Based on the results of removal rate in each floor of soil, it was found that the removal rates were 85.8 % in the upper, 84.4 % in the middle, and 66.10 % in the bottom. Considering that the reduction rate of TPH for the control group averaged 71.1%, the microbial activators might not be fully transferred into the bottom, which resulted from the piles of soil. As the piles have already reached 1 m in the field experiments, the low piles of soil under 0.6 m may enhance the treatment efficiency of TPH.

Evaluation of Replacement Ratio of Organic Fertilizers for Basal Application of Nitrogen Fertilizer in Pot Cultivation of Rice (벼 재배 시 유기질비료의 질소 밑거름 대체량 평가)

  • Kim, Myung-Sook;Kim, Seok-Cheol;Park, Seong-Jin;Lee, Chang-Hoon
    • Journal of the Korea Organic Resources Recycling Association
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    • v.27 no.1
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    • pp.5-14
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    • 2019
  • The objective of this study was investigated the effect of organic fertilizer(OF) application on the grain yield, protein content, and soil chemical properties in rice cultivation to evaluate the replacement ratio of OF based on basal fertilization of inorganic(nitrogen) fertilizer, In case of soil 1 with optimum range of organic matter for rice growth, the grain yield of rice in 70% and 100% treatments of OF were higher than the other treatments. In soil 2 with higher than the optimum range of soil organic matter, the grain yield of rice of NPK, 30%, 70%, 100%, and 300% treatments of OF showed no significant difference. When the protein criteria of rice quality was below 7%, the treatment of 30%, 70%, and 100% using OF in soil 1 were satisfied with protein criteria of rice. In case of soil 1, ammonium nitrogen content, electrical conductivity, and the organic matter in 30%, 70%, 100%, 300% treatments of OF showed similar tendency to NPK treatment. These results suggested that the substitution ratio of OF 70~100% could be appropriate to increase the yield and commercial quality for rice.

Impacts of Different Organic Fertilizers on Soil Fertility and Soil Respiration for a Corn (Zea mays L.) Cropping System (옥수수 밭에서 유기질 비료가 토양 비옥도 및 토양 호흡에 미치는 영향)

  • Mavis, Brempong Badu;Hwang, Hyun Young;Lee, Sang Min;Lee, Cho Rong;An, Nan Hee
    • Journal of the Korea Organic Resources Recycling Association
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    • v.30 no.4
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    • pp.151-163
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    • 2022
  • This study was conducted to promote organic fertilizer(s) that sustain soil productivity for corn production and protect the environment as required by the Act on the promotion of eco-friendly agriculture. It was conducted at the research station of the Organic Agriculture Division of the National Institute of Agricultural. The treatments consisted of Compost (Com), Bokashi as fermented organic fertilizer (FOF), and mixed expeller pressed cake (PC). They were applied at 174 kg N /ha to field corn, together with a 'no fertilizer' check in Randomized Complete Block Design. At eight weeks after transplanting (WAT) corn, compost increased soil carbon (C) and nitrogen (N) to 7.48 and 0.76 g/kg respectively, while other fertilizers maintained the initial levels (before treatment application). At corn harvest (13 WAT), soil chemical properties (total C, total N, pH, electrical conductivity, P2O5, Ca, K, and Mg) were similar among all organic fertilizer treatments. For soil respiration, FOF increased soil CO2 respiration by 31-76% above other fertilizer treatments. However, there were no prominent changes in the trends of CH4 fluxes following the two mechanical weeding operations. Fermented organic fertilizer affected N2O emissions between 87-96% lower than other fertilizer treatments. Compared to the initial microbial densities, FOF increased fungi and actinomycete colony foming unit by 25 and 16% at harvest. Therefore, the additional potential of improving soil biological fertility and local availability of raw materials make FOF a better option to sustain soil productivity while protecting the environment.

Development of Aqueous/Semi-Aqueous Cleaning Agent and its Field Application to Cleaning Process of Electronic Parts (수계/준수계 세정제의 개발 및 전자부품 세정공정 현장적용 연구)

  • Kim, Han-Seong;Cha, An-Jeong;Bae, Jae-Heum;Lee, Ha-Yeoul;Lee, Myung-Jin;Park, Byeong-Deog
    • Clean Technology
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    • v.10 no.2
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    • pp.61-72
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    • 2004
  • In this study, aqueous/semi-aqueous cleaning agents which consist of organic solvent, surfactant, cosurfactant, and water were developed by changing formulation parameters such as organic solvent type and contents, surfactant type and contents, and cosurfactant/surfactant(A/S) ratio, etc.. And physical properties and flux removal of the formulated cleaning agents have been evaluated. Also, the performance of oil-water separation from the rinse water contaminated during the cleaning process was evaluated for its recycling. The formulated cleaning agents in this work expected to have good penetration because of their low viscosity and low surface tension values of 30.2~32.5 dyne/cm. The flux removal with the terpene type cleaning agent was higher than that with hydrocarbon type cleaning agent and two commercial products (CPA(commercial product A), CPB(commercial product B)). And the performance of oil-water separation by gravity settling from the rinse water contaminated with formulated cleaning agent and soils was shown to be very good. The cleaning agents developed in this work were applied to surface mounting technology(SMT) cleaning process for manufacturing electronic parts at L electronic company. As a result, the newly developed cleaning agents showed two times better cleaning speed for removal of solder cream than the conventional ond containing ethanol and IPA(isopropyl alcohol). In addition, malodor and VOC problems generated by the previous organic cleaning agents have been solved in the manufacturing field through introduction of the non-volatile and environmental-friendly cleaning agents to the field.

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Polyether Ester by Rubber Content and Rubber According to the Type of Dynamic Vulcanized Properties (TPEE) (폴리에스터계 동적가교물의 고무함량 및 고무종류에 따른 물성)

  • Yun, Ju-Ho;Yun, Jung-Hwan;Ha, Seong-Mun;Kim, Il;Sim, Sang-Eun
    • Elastomers and Composites
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    • v.48 no.1
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    • pp.67-75
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    • 2013
  • E-TPE (Engineering Thermoplastic Polyether Ester) was Ester Elastomer with functional groups as recycling and fast processability. In addition, if the car's lightweight enough to highlight eco-friendly materials that help to improve fuel economy has become. Have all the attributes of the rubber and engineering plastics E-TPE the available temperature area is spacious, heat resistance and oil resistance is excellent but getting attention as a new material in the field of auto parts in the field of electrical and electronic domestic depends entirely on imports by the lack of core technology and has been research and development is urgently needed. In this study, the hard segments, polyester (TPEE) as the base soft elastomers of the segments Ethylen-prophylene-Copolymer and CSM (Choloro sulphonated polyethylene Rubber), VAMAC (Ethylene Acrylic Rubber), NBR (Acrylonitrin Butadiene Rubber), 1, 3-Phenylene-bisoxazoline is dealing with Dynamic Vulcanized by content and added rubber properties, thermal variation observed. As a result, the properties of the dynamic vulcanization with NBR compared to other rubber heat resistance and oil resistance is on the increase.

Sustainability of Olive Flounder Production by the Systems Ecology -II. Simulating the Future of Olive Flounder Aquaculture on the Land- (시스템 생태학적 접근법에 의한 넙치생산의 지속성 평가 -2. 넙치 육상양식산업에 대한 예측-)

  • Kim Nam Kook;Son Ji Ho;Kim Jin Lee;Cho Eun Il;Lee Suk Mo
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.35 no.6
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    • pp.660-665
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    • 2002
  • In Korea, an olive flounder is very popular fish food item. However, due to the increasing human population, the present catches of the olive flounder may not be sufficient to satisfy the present demand. To increase the supply of the olive flounder, aquaculture has been begun. An interest in the aquaculture of the olive flounder has been increased recently because of its characteristics of good growth and high price in the market, However, the productivity of the olive flounder aquaculture depends on economic inputs such as fuels, facilities, and labor. The rapid growths of the olive flounder aquaculture and the concerns about economic and ecological sustainability have focused peoples attention on the aquaculture industry. In this study, an energy systems model was built to simulate the variation of sustainability on the aquaculture of olive flounder, The results of simulation based on calibration data in 1995 show that olive flounder production yield and asset slowly increase to steady state because of the law of supply and demand. The results of simulation based on the variation of oil price show that the more increase the oil price, the more decrease the olive flounder economic yield and asset. Energy sources required for systems determine the sustainability of systems. Conclusionally, the present systems of the olive flounder aquaculture should be transformed to ecological-recycling systems or ecological engineering systems which depend on renewable resources rather than aquaculture systems which depend on fossil fuels, and be harmonized with the fishing fisheries by the sustainable use of renewable resources in the carrying capacity.

Mechanical Strength Evaluation of A53B Carbon Steel Subjected to High Temperature Hydrogen Attack

  • Kim, Maan-Won;Lee, Joon-Won;Yoon, Kee-Bong;Park, Jai-Hak
    • International Journal of Safety
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    • v.6 no.2
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    • pp.1-7
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    • 2007
  • In this study mechanical strength of A53B carbon steel was analyzed using several types of test specimens directly machined from oil recycling pipe experienced a failure due to hydrogen attack in chemical plants. High temperature hydrogen attack (HTHA) is the damage process of grain boundary facets due to a chemical reaction of carbides with hydrogen, thus forming cavities with high pressure methane gas. Driven by the methane gas pressure, the cavities grow on grain boundaries forming intergranular micro cracks. Microscopic optical examination, tensile test, Charpy impact test, hardness measurement, and small punch (SP) test were performed. Carbon content of the hydrogen attacked specimens was dramatically reduced compared with that of standard specification of A53B. Traces of decarburization and micro-cracks were observed by optical and scanning electron microscopy. Charpy impact energy in hydrogen attacked part of the pipe exhibited very low values due to the decarburization and micro fissure formation by HTHA, on the other hand, data tested from the sound part of the pipe showed high and scattered impact energy. Maximum reaction forces and ductility in SP test were decreased at hydrogen attacked part of the pipe compared with sound part of the pipe. Finite element analyses for SP test were performed to estimate tensile properties for untested part of the pipe in tensile test. And fracture toughness was calculated using an equivalent strain concept with SP test and finite element analysis results.

Material Life Cycle Assessment of Extrusion Process of A7003 (A7003 알루미늄 합금 압출공정의 MLCA 산정기술)

  • Jo Huyng-ho;Cho Hoon;Kim Byung-min;Kim Young-jig
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2002.11a
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    • pp.43-49
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    • 2002
  • A7003 alloy has characteristics of their excellent weldability, high corrosion resistance and superior plastic working however the broadening of application for the alloy has been hampered by the lower extrudability associated by Mg content. For improvement of extrudability and enhanced recovery efficiency during Al scrap recyeling, it has been generally practiced to reduce Mg content in A7003 alloy. Therefore, it is necessary to investigate the influence of Mg content on mechanical strength and extrudability of A7003 alloy. For efficient material processing which has small amounts, life cycle assessment in material processing(MLCA) is evaluated. The quantitative analysis of energy requirements and $CO_2$ emission for production of A7003 extruded bar are estimated with different Mg content and billet pre-heating process (heating source by light oil or LPG). In particular, the estimation of energy requirements was performed within shipping and gating range (except the mining and extraction stages)to investigate the influence of the variables on energy requirements and $CO_2$ emission in detail. As Mg content increased, the flow stress and the extrusion pressure for A7003 alloy increased. It has been thought that an increment in extrusion pressure with increasing Mg content is caused by the solid solution hardening of Mg atoms in the matrix and increment in volume fraction of intermetallic compound, $Mg_2Si$. The extrudability and the tensile strength are equal to, or above that of conventional A 7003 alloy even the content of Mg varied from $1.1wt.\%\;to\;0.5wt.\%$ alloy. This means that minimizing the content of Mg in A7003 alloy can enhance recovery efficiency during Al scrap recycling. It can be quoted that rather than Mg content energy source for billet heating is a prime factor to determine the atmospheric $CO_2$ emission.

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The Ejector Design and Test for 5kW MCFC System (5kW 용융탄산염 연료전지(MCFC) 이젝터 설계 및 시험)

  • Kim, Beom-Joo;Kim, Do-Hyeong;Lee, Jung-Hyun;Lee, Sung-Yoon;Kim, Jin-Yoel;Kang, Seung-Won;Lim, Hee-Chun
    • Transactions of the Korean hydrogen and new energy society
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    • v.20 no.1
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    • pp.31-37
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    • 2009
  • An ejector is a machine utilized for mixing fluid, maintaining a vacuum, and transporting fluid. The Ejector enhances system efficiency, are easily operated, have a mechnically simple structure, and do not require a power supply. Because of these advantages, the ejector has been applied to a variety of industrial fields such as refrigerators, power plants and oil plants. In this work, an ejector was used to safely recycle anode tail gas in a 5 kW Molten Carbonate Fuel Cell system at KEPRI(Korea Electric Power Research Institute). In this system, the ejector is placed at mixing point between the anode tail gas and the cathode tail gas or the fresh air. Commercial ejectors are not designed for the actual operating conditions for our fuel cell system. A new ejector was therefore designed for use beyond conventional operating limits. In this study, the entrainment ratio is measured according to the diametrical ratio of nozzle to throat in the designed ejector. This helps to define important criteria of ejectors for MCFC recycling.

A Personal Reformer(PR) for your Fuel cell system (연료전지를 위한 개인용 개질기)

  • Kim Hyeon Yeong
    • 한국전기화학회:학술대회논문집
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    • 2004.06a
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    • pp.103-108
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    • 2004
  • The present paper relates to an apparatus in which all carbonaceous material such as coal, oil, plastics and any substance having carbon atoms as part of its constituents are reformed(gasified) into syngas at temperature above $1,200^{\circ}C$(KR patent No.0391121, and PCT/KR2001/01717 and PCT/KR2004/001020). It comprises a single-stage reforming reactor without catalyst and a syngas burner as shown in Fig.2. syngas is combusted with $O_2$ gas in the syngas bunter to produce $M_2O$ and $CO_2$ gas with exothermic heat. Reaction products are introduced into the reforming reactor, reaction heat from syngas burner elevate the temperature of reactor above $1,200^{\circ}C$, and reaction products reduce carbonaceous material down to CO and $H_2$ gases. Reactants and heat necessary for the reaction are provided through the syngas burner only, Neither $O_2$ gas nor steam are injected into the reforming reactor. Reformer is made of ceramic inner lining and sst outer casing. Multiple syngas burners may be connected to the reforming reactor in order to increase the syngas output, and a portion of the product syngas is recycled into syngas burner. The present reformer as shown in Fig.2 is suitable to gasify carbonaceous wastes without secondary pollutants formed from oxidation. Further, it can be miniaturized to accompany a fuel cell system as shown in Fig.3 The output syngas may be used to drive a fuel cell and a portion of electrical power generated in a fuel cell is used to heat a compact reformer up to $1,200^{\circ}C$ so that gas/liquid fossil fuel can efficiently reformed into syngas. The fuel cell serves as syngas burner in Fig.2. The reformation reaction is sustained through recycling a portion of product syngas into a fuel cell and using a portion of electric power generated to heat the reformer for continuous operation. Such reforming reactor may be miniaturized into a size of PC, then you have a Personal Reformer(PR).

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