• Proceedings of the IEEK Conference
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• 2001.10a
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• pp.240-244
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• 2001

Recycling process involving mechanical, thermal, hydrometallurgical, and sol-gel step has been applied to recover cobalt and lithium from spent lithium ion batteries and to synthesize LiCoO$_2$from leach liquor as cathodic active materials. Electrode materials containing lithium and cobalt could be concentrated with 2-step thermal and mechanical treatment. Leaching behaviors of the lithium and cobalt in nitric acid media was investigated in terms of reaction variables. Hydrogen peroxide in 1 M HNO$_3$solution turned out to be an effective reducing agent by enhancing the leaching efficiency. O f many possible processes to produce LiCoO$_2$, the amorphous citrate precursor process (ACP) has been applied to synthesize powders with a large specific surface area and an exact stoichiometry. After leaching used LiCoO$_2$with nitric acid, the molar ratio of Li/Co in the leach liquor was adjusted at 1.1 by adding a fresh LiNO$_3$solution. Then, 1 M citric acid solution at a 100% stoichiometry was also added to prepare a gelatinous precursor. When the precursor was calcined at 95$0^{\circ}C$ for 24 hr, purely crystalline LiCoO$_2$was successfully obtained. The particle size and specific surface area of the resulting crystalline powders were 20 пm and 30 $\textrm{cm}^2$/g, respectively The LiCoO$_2$powder was proved to have good characteristics as cathode active materials in charge/discharge capacity and cyclic performance.

• Environmental Engineering Research
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• v.24 no.4
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• pp.699-710
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• 2019

Electric vehicles (EVs) are spreading rapidly and many counties are promoting hybrid and fully EVs through legislation. Therefore, an increasing amount of lithium ion batteries will reach the end of their usable life and will require effective and sustainable end-of-life management plan which include landfill disposal or incineration. The current research focuses on more sustainable methods such as remanufacturing, reuse and recycling in order to prepare for future battery compositions and provide insights to the need recycling methods to be developed to handle large amounts of batteries sustainably in the near future. The two most prominent material recovery techniques are hydrometallurgy and pyrometallurgy which are explored and assessed on their relative effectiveness, sustainability, and feasibility. Hydrometallurgy is a superior recycling method due to high material recovery and purity, very low emissions, high prevalence of chemical reuse and implementation of environmentally sustainable compounds. Expanding recycling technologies globally should take the research and technologies pioneered by Umicore to establish a sustainable recycling program for end-of-life EVs batteries. Emerging battery technology of Telsa show the most effective designs for high performance batteries includes the use of silicon which is expected to increase capacity of batteries in the future.

• Resources Recycling
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• v.22 no.5
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• pp.63-70
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• 2013

There are generated the hundreds of tons of waste electric wire per year due to replace for increase transmission capacity and/or replacement of old electric wire by Korea's national power grid and/or private industrial factories. Recently, the wire recycling technologies studied extensively in terms of effieiency by of economic aspects and environment aspects. In this paper, the patents and papers for the recycling technologies of spent electric wire were collected and analyzed. The range of search was limited in the open patents of USA (US), European Union (EP), Japan (JP), Korea (KR) and SCI journals from 1975 to 2011. Patents and journals were collected using key-words searching and filtered by filtering criteria. The trends of the patents and journals were analyzed by the years, countries, companies, and technologies.

• Journal of Korean Society on Water Environment
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• v.37 no.5
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• pp.398-404
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• 2021

The use of water purifiers has been increasing every year due to increased drinking water safety concerns raised by the water pollution accidents occasionally reported. Currently, more than 10 million water purifiers have been distributed in Korea, and the estimation of the purifier sales reaches two million units per year. As a result, the number of used water purifier filters that must be replaced on a regular basis has gradually increased. However, regardless of the considerations for the capacity of used filters remaining, water purifier filters were replaced and collected at regular intervals. The high cost of disposal of the used filters by landfill or incineration were required. Thus, in this study, the current status and trends of recycling technologies for used water purifier filters were reviewed. It is noted that there was insufficient statistical data to understand the current status of the difference between the number of used water filters discarded and the number of those recycled. Most studies on the recycling of old water purifier filters have concentrated on pretreatment and cleaning methods for sediment filters and membrane filters, with the goal of extending the lifespan of used filters. Further, the study suggested future study directions on the recycling of used water purifier filters, which could be useful information on establishing environmental policy to promote the recycling of used filters.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.17 no.10
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• pp.86-92
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• 2016

A high-capacity battery installed in a hybrid vehicle or electric vehicle is used to power, or as a power supply for, electric sub-assemblies. In order to use a high-capacity battery as a power supply for electric sub-assemblies, such as an electronic control unit or for lighting, radio, and navigation, there is a need for a DC converter that changes a high voltage of 240-400V to a low voltage of 12-14V, which is done with a low-voltage DC-DC converter (LDC). An LDC undergoes long-term aging so as to reduce latent defects in the production process. With regard to the usual aging method, an LDC is a DC-DC converter. So, a DC power supply is connected and used as input, and a programmable DC electronic load is the output. For stable operation, a product having a larger capacity by 10% (compared to an LDC) is used, and has a structure where electric power is dissipated into 100% heat. So, there is a problem with volume, based on the use of two pieces of equipment to test the LDC, and another problem based on the generation of heat in the programmable DC electronic load. Hence, this paper suggests a load test method as a way of recycling, where a significant portion of the electricity dissipated as heat in a load tester is returned as input. The method realizes savings of 80% or more in the electricity dissipated as heat through improvement in the efficiency of the recycling load tester.

• Resources Recycling
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• v.11 no.1
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• pp.32-36
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• 2002

This study was conducted to compost the mixture of Pig manure, gypsum and fly ash. Initial moisture contents of sample A (Pig manure : saw dust = 6 : 4) and C (Pig manure : saw dust : gypsum : coal fly ash= 6 : 2 : 1 : 1) in the reactor were 64 and 50%. Also temperature and pH of samples in the reactor was nearly the same. Total Organic Carbon (TOC) concentration of sample A and C were about 5500, 2900 mg/kg respectively. This sample was needed a lot of time to mature as viewing cation exchange capacity (CEC) after experiment was over. However added with gypsum and coal fly ash in Process of Pig manure composting Process was suggested that gypsum and coal fly ash have a roles of additive agent.

• Resources Recycling
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• v.19 no.4
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• pp.51-57
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• 2010

As a recycling of Si sludge from Si wafer process, a Si-SiC-CuO-C composite material was synthesized and investigated as an anode material for lithium batteries. The Si sludge consisted of Si, SiC, machine oil, and metallic impurities. The oil and metal impurities was removed by organic washing, magnetic separation, and acid washing. The Si-SiC-CuO-C composite from the recovered Si-SiC mixture was prepared by high-energy mechanical milling. According to the electrochemical tests such as charge-discharge capacity and cycling behavior, it showed the improved cycle performance. The SiC and CuO-related phases were presumed to restrain the volume expansion of the anode and Fe, however, should be removed below 10 ppm prior to synthesis of the composite because it caused the capacity loss of the active material itself.

• Resources Recycling
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• v.28 no.6
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• pp.3-8
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• 2019

Recently, plastic waste in Korea has been recognized as a critical issue due to an increase in massive production of plastics, difficulty in disposal of waste plastics, and public recognition of toxicity in micro-plastics, etc. To resolve those problems, the regulation to reduce plastics consumption may be primarily considered but, in this case, clarification should be made on the rationales and the action plans in the regulation for individual waste plastic items. Another problem is the small capital sizes of domestic recycling companies, which leads to poor R&D capacity, low recycling yields and thus lowering values of recycling items. This adversely affects consumers' perception. The R&D toward recycling technical progress should take into account the environmental friendliness and recyclability from the early product design stages. Certainly, this should be supported in governmental policy and public action plans. In addition, by referring to advanced policies of i.e. European Union, the recycling industry should be recognized as an opportunity toward new investment & employment. If necessary, the regulation of plastic consumption through a formal evaluation process such as Life Cycle Assessment (LCA) will also be helpful. The values of recycled plastics should be improved through the identification and elimination of harmful chemical substances potentially contained in the products.

• Journal of environmental and Sanitary engineering
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• v.15 no.3
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• pp.44-49
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• 2000

The purpose of this research is to evaluate the adsorption capacity of casts for heavy metals. The casts were excreted by earthworm, Lumbricus rubellus, after having eaten the paper sludge. Various batch experiments on adsorption were performed to compare cast and activated carbon. The pH increase in solution due to extractives from cast was 1.3 and the cation exchange capacity which implies adsorption capacity for solubles is greater on activated carbon than on cast. According to the results of batch experiment, the removal rates of Pb, Cu, Cr, Zn using the activated carbon and casts as adsorbent were 98%, 93%, 94%, 89%, 82% and 95%, 90%, 88%,80%, 66%, respectivity, and this removal were achived less than 90 minutes. It can be said that casts is so good adsorbent as activated carbon is, although adsorption carbon was found to be some large than those of casts through Freundlich isotherm applied for adsorption of soluble. As a result on the experiment of isothermic adsorption from the mixed component solution in the batch, the order of preferable elements in heavy metal adsorption was found to be Pb＞Cd＞Cu＞Cr＞Zn on activated carbon, respectively.

• Journal of the Korea Institute of Building Construction
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• v.3 no.1
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• pp.123-129
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• 2003

The production accounts of domestic by-product is increased after 1990's. It is worried about the life reduction of dump land, as dump land's capacity have reached to limitation and the amount of construction industrial wastes is going higher. Recently, recycling aggregates could be gained from the reconstruction works using recycle process, and the study research of recycle concretes developed concrete application methods. It could put some outcome of studies to practical use for concrete products. The methods of crushing waste concrete are going diverse. In this study. the fundamental experiments and recycling application is investigated and analyzed with use of recycling aggregate which made of mechanical crush and underwater electrical impact crush, and the difference between underwater electrical impact crush, mechanical crush and natural aggregates is studied.