• Title/Summary/Keyword: Recycled Cement

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A Study on the Method for Quantifying CO2 Contents in Decarbonated Slag Materials by Differential Thermal Gravimetric Analysis (DTG 분석법을 활용한 슬래그류 비탄산염 재료의 CO2 정량 측정방법 연구)

  • Jae-Won Choi;Byoung-Know You;Yong-Sik Chu;Min-Cheol Han
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.12 no.1
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    • pp.8-16
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    • 2024
  • Limestone (CaCO3, calcium carbonate), which is used as a raw material in the portland cement and steel industry, emits CO2 through decarbonation by high temperatures in the manufacturing process. To reduce CO2 emissions by the use of raw materials like limestone, it has been proposed to replace limestone with various industrial by-products that contain CaO but less or none of the carbonated minerals, that cause CO2 emissions. Loss of Ignition (LOI), Thermogravimetric analysis (TG), and Infrared Spectroscopy (IR) are used to quantitative the amount of CO2 emission by using these industrial by-products, but CO2 emissions can be either over or underestimated depending on the characteristics of by-product materials. In this study, we estimated CO2 contents by LOI, TG, IR and DTG(Differential Thermogravimetric analysis) of calcite(CaCO3) and samples that contain CO2 in the form of carbonate and whose weight increases by oxidation at high temperatures. The test results showed for CaCO3 samples, all test methods have a sufficient level of reliability. On the other hand, for the CO2 content of the sample whose weight increases at high temperature, LOI and TG did not properly estimate the CO2 content of the sample, and IR tended to overestimate compared to the predicted value, but the estimated result by DTG was close to the predicted valu e. From these resu lts, in the case of samples that contain less than a few percent of CO2 and whose weight increases during the temperature that carbonate minerals decompose, estimating the CO2 content using DTG is a more reasonable way than LOI, TG, and IR.

Fundamental Properties of Low Strength Concrete Mixture with Blast Furnace Slag and Sewage Sludge (고로슬래그미분말 및 하수슬러지를 활용한 저강도 콘크리트의 기초적 물성)

  • Kwon, Chil Woo;Lim, Nam Gi
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.17 no.3
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    • pp.136-144
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    • 2013
  • In this study, in order to establish a plan that will enable safe use of renewable resources such as diverse industrial by-products and urban recycled materials, we conducted experiments that focused on flow, bleeding, compressive strength and environmental pollution evaluation to evaluate the material properties of low strength concrete using BFS and SS. In the case of low strength concrete using BFS and SS, blending of at least BFS 6000 within a 30% range regardless of the type of sand used was found to be the most effective approach for improving the workability by securing the minimum unit quantity of water, restraining the bleeding ratio and establishing compressive strength by taking account of the applicability at the work site. In particular, in view of the efficient use of SS, the optimal mixing condition was found to be the mixing of BFS 8000 with in the 30% range, not only for improving the workability restraining the bleeding ratio and establishing the compressive strength but also for application to the work site. Further, the results of tests on hazardous substance content and those of elution tests conducted on soil cement using SS indicated that all values satisfied the environmental standards without any harmful effects on the surrounding environment.

A Model for Lifecycle CO2 Assessment of Building Structures Considering the Mixture Proportions of Concrete (콘크리트 배합설계를 고려한 구조물의 전과정 CO2평가 모델)

  • Yang, Keun-Hyeok;Seo, Eun-A
    • Journal of the Korea Concrete Institute
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    • v.26 no.2
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    • pp.201-210
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    • 2014
  • The present study proposes a phased model to assess the lifecycle $CO_2$ amount of concrete structures. The considered system boundary is from cradle to recycling, which includes constituent material, transportation, batching and mixing in ready-mixed concrete plant, use and demolition of structure, and crushing and recycling of demolished concrete. The $CO_2$ uptake of concrete by carbonation during lifetime (40 years) of a structure and the recycling life (20 years) after demolition is estimated using a simple approach generalized to predict the carbonation depth from the surfaces of concrete element and recycled aggregates. Based on the proposed phased model, a performance evaluation table is realized to straightforwardly examine the lifecycle $CO_2$ amount of concrete structures. The proposed model demonstrates that the contribution of ordinary portland cement (OPC) to lifecycle $CO_2$ emission of the concrete structure occupies approximately 85%. Furthermore, the $CO_2$ uptake is estimated to be approximately 15~18% of the lifecycle $CO_2$ emissions of concrete structures, which corresponds to be 19~22% of the emissions from OPC production. Overall, the proposed $CO_2$ performance table is expected to be practically useful as a guideline to determine the $CO_2$ emission or uptake at each phase of concrete structures.

Eco-Friendly Backfill Materials with Bottom Ash (바톰애시를 이용한 환경친화적 뒤채움재)

  • Lee, Kwan-Ho;Kim, Seong-Kyum
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.13 no.3
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    • pp.1385-1390
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    • 2012
  • Couple of laboratory for controlled low strength materials with bottom ash and recycled in-situ soil have been carried out. The optimum mix ratios for 4 cases with flowability and unconfined compressive strength were determined. The optimim mixing ratios were 25 to 45% of insitu soil, 30% of bottom ash, 10 to 20% of fly ash, 0 to 3% of crumb rubber, 3% of cement and 22% of water. Each mixture was satisfied the standard specification, minimum 20cm of flowability and 127 kPa of unconfined compressive strength. Two different curling methods, at room temperature and wet condition, were adopted. The average secant modulus(E50) was 0.07 to 0.08 * $q_u$. The compressive strength at wet condition showed 10% larger than at room temperature. The range of internal friction angle and cohesion for mixtures were 36.5o to 46.6o and 49.1 to 180 kPa, respectively. The mixture with crumb rubber(case 4) showed higher choesion and lower internal friction angle than the others. The pH of all the mixtures was over 12 which is strong alkine.

Development of Concrete and Evaluation of Properties of Combined Steel making Slag Aggregates for Offshore Structure Production (I) (해양구조물 제조를 위한 제강슬래그 골재 조합별 물성평가 및 콘크리트 개발( I ))

  • Jung, Won-Kyong;Hwang, Yun-Seok;Park, Dong-Cheon;Cho, Bong-Suk
    • Resources Recycling
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    • v.25 no.2
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    • pp.49-59
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    • 2016
  • Steel slag is being recycled into industrial by-products for civil generated inevitably in the seasonal course, road and cement raw materials. However, the field of recycling most of the bottom portion is concentrated in the areas that are required to take advantage of the situation in various fields taking advantage of the steel slag. But various studies to take advantage of the steel slag as aggregate for concrete made for limiting slag was a situation that most of the studies are incomplete research on the suitability of as aggregate for concrete practical relates to an expandable suppressed. In this study, the separation of the slag aggregate according to the production methods to assess the feasibility aggregate for concrete aggregates, including through Steel making slag, a total of seven kinds of steel slag aggregate. Studies show that ordinary concrete, steel slag aggregate for aggregate and on the equally to take advantage of grading, chloride content standards such as to what is lacking, although appropriate aggregate of concrete include the deployment of only in special sectors through the combination was assessed to have a very high.

Flowability and Strength Properties of Mortar and Self-Compacting Concrete Mixed with Waste Concrete Powder (폐콘크리트 분말을 혼합한 모르타르 및 자기충전 콘크리트의 유동 및 강도특성)

  • Choi, Yun-Wang;Jung, Moon-Young;Moon, Dae-Joong;Kim, Sung-Su
    • Journal of the Korea Concrete Institute
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    • v.18 no.4 s.94
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    • pp.517-526
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    • 2006
  • In this study, in order to utilize waste concrete powder(WCP) which is occurred in manufacturing high quality recycled aggregate as an admixture for self-compacting concrete(SCC), the properties of cement paste, mortar, and concrete that were mixed two types of WCP, 928 and 1,360 $cm^2/g$ of surface area, were analyzed. As a result of experiment, we have found that WCP was a porous material with angle. When WCP was utilized as an admixture for SCC, its flowability and viscosity increased in proportion to the increase of a replacement ratio, and that a replacement ratio of WCP was proper within 15%. The compressive strength at 28 days mixed respectively with WCP2, 15 and 30%, showed about 36 and 28 MPa, and it showed a similar trend with a function suggested in CEB-FIP for the relationship of compressive strength and elastic modulus. According to the results, it is judged that WCP2 can be utilized as an mineral admixture of normal strength SCC.

Research on Fire Safety of Mortar-Containing Waste Tire Powders and Flame Retardant (폐타이어 분말과 난연제가 혼입된 모르타르의 화재안전에 관한 연구)

  • Park, Jeong-Jin;Son, Ki-Sang
    • Fire Science and Engineering
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    • v.24 no.4
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    • pp.12-17
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    • 2010
  • The purpose of this study is to determine how effectively waste tire recycled material mixed with flame retardant work in combating fire. As discovered in the previous study, waste tire mixed with cement mortar has more insulation capacity. However, this mortar is weak against fire. Therefore flame retardant, with a specific proportional mix, will be added to increase its fire prevention capacity. Tests will be made in accordance with ISO 5657 procedures for measuring fire ignition time, flame and shape variation of test pieces at the Building Material Test Institute. The test piece will be set up with horizontal levels having a constant radiation heat of $1{\sim}5W/cm^2$. Temperature transfers and increases from the surface into the interior. Combustible gases result due to pyrolysis, and regular contact is maintained between the fire source and the center of the test piece for assessment purposes. Ignition has not been occurred without adding retardant meaning that there is almost no possibility of ignition of waste tire particle. This fact can be considered as fire load to appreciate a volume of combustion materials. Flame is not occurred due to heat-absorbing effect by adding non-organic series retardant into waste tire particle. Conclusions have been summarized as follows; 1) Combustion of building material can be decreased by adding retardant to waste tire-mixing mortar. But compressive strength and insulation capacity of the material should be measured later. 2) Firing prevention and ignition are main points of building fire. Reasonable fire engineering assessment of interior material should be made for establishing effective disaster prevention system.

Development and Commercialization of Artificial Reefs from Waste Mulch Plastic Films (농업용(農業用) 멀칭 폐(廢)비닐로부터 인공어초(人工魚礁) 개발(開發) 및 상용화(商用化))

  • Kim, Hea-Tae;Shon, Sang-Jin;Kim, Myoung-Ho;Choi, Mi-Ran;Baek, Wook-Jin
    • Resources Recycling
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    • v.16 no.5
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    • pp.19-24
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    • 2007
  • Reefs are the marine structure that can give resting, inhabiting, feeding and nursing spaces for a variety of fishes. Usually artificial reefs are made of cement and steels respectively in Japan as well as in Korea. However since resources deficiency has been getting serious, other materials are taken into consideration for the basic bodies of artificial reefs. About 300 thousand tons of waste agricultural plastic films are generated every yew in Korea, but no effective recycling techniques have been developed. In this sense, artificial reefs made of waste agricultural plastic films are the most representative symbol of the recycled products in the Resource Recycling Era. In particular, since these reefs could be made of the semi-cleaned waste agricultural plastic films that still contain high portion of soil, it is very environmentally friendly not only in manufacturing process but also in using under water. Furthermore they have some evident advantages as follows; 1) high fish swarming effect 2) good initial attachment of the marine growths 3) extremely low corrosion to brine 4) easy adjustment of the gravity 5) economical manufacture, transportation and jettison 6) excellent safety to ecosystem caused by lower elution of toxic substances 7) good recyclable property after application and so on.

Investigation of Tar/soot Yield of Bituminous and Low Rank Coal Blends (발전용 역청탄과 저열량탄 혼소시 Tar/Soot의 배출 특성 연구)

  • Lee, Byung Hwa;Kim, Jin Ho;Kim, Gyu Bo;Kim, Seng Mo;Jeon, Chung Hwan
    • Journal of Energy Engineering
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    • v.23 no.2
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    • pp.42-48
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    • 2014
  • Soot and tar which were derived from combustion or pyrolysis processes in Puverized Coal(PC) furnace or boiler have been significantly dealing in a radiative heat transfer and an additional source of NOx. Furthermore, the increasing for the use of a coal with low caloric value gives rise to a lot of tar-soot yield and LOI in a recycled ash for using cement materials. So, the ash with higher tar-soot yield and LOI can not recycle due to decreased strength of concrete. In this study, tar-soot yields and flame structures were investigated using the LFR for a blending combustion with bituminous coal and sub-bituminous coal. Also, The investigation were conducted as each single coals and blending ratio. The coals are used in a doestic power plant. In the experimental results, sub-bituminous coal with high volatile contents shows longer soot cloud length than bituminous coal, but overall flame length was shorter than bituminous coal. Tar-soot yields of sub-bituminous coal is lower than those of bituminous coal. Combustion characteristics are different between single coal and blended coal. Therefore, finding an optimal coal blending ratio according to coal rank effects on tar-soot yields.

A Study on the Estimation of Optimal Unit Content of Binder for the Soil Stabilizer Using the Recycled Resource in DMM (심층혼합공법에서 순환자원을 활용한 지반안정재의 최적 단위결합재량 산정에 관한 연구)

  • Seo, Se-Gwan;Lee, Khang-Soo;Kim, You-Seong;Cho, Dae-sung
    • Journal of the Korean Geosynthetics Society
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    • v.18 no.2
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    • pp.37-44
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    • 2019
  • The compressive strength of the soil stabilizer in the deep mixing method (DMM) depends on kinds of soil, particle size distribution, and water content. Because of this, Laboratory test has to perform to estimate the unit weight of binder to confirm the satisfaction of the design strength. In this study, uniaxial compression strength was measured by mixing the soil stabilizers developed in the previous study with clay in Busan, Yeosu, and Incheon area. And the strength enhancement effect was evaluated comparing with blast furnace slag cement (BFSC). Also, the relationship between the unit content of binder and uniaxial compressive strength was investigated in order to easily calculate the unit weight of binder required to ensure the stability of the ground at the field. As the results of the analysis, the relationship between the unit content of binder and the uniaxial compressive strength are ${\gamma}_B=(108.93+0.0284q_u){\pm}35$ when W/B is 70%, and ${\gamma}_B=(122.93+0.0270q_u){\pm}40$ when W/B is 80%.