• Proceedings of the Korean Society for Technology of Plasticity Conference
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• 2001.10a
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• pp.301-304
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• 2001

Hot-compression tests were carried out to investigate the hot workability of Ti64 and Ti6246 alloys at different temperatures and strain rates. Processing maps were developed on the basis of the dynamic material model unifying the relationship among constitutive behavior, hot workability and microstructure development. Stable regions, defined on the basis of four stability criteria 0${\delta}log(m)/\frac{\bot}{\varepsilon})<0$, s<1 and ${\delta}log(s)/\frac{\bot}{\varepsilon})<0$, were found to be associated with dynamic recovery and recrystallization.

• Journal of Power System Engineering
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• v.22 no.1
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• pp.87-93
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• 2018

Specimens were machined out from hot-rolled AZ31 magnesium alloy, and deformed at 623K with rolling reduction of 30%. After hot rolling, specimens were annealed at various range of temperature and time. In this study, static recrystallization was occurred during heat treatment, however, variation of main component and intensity of texture was not revealed. The results of microstructure observation, damping capacity test and dislocation mechanism indicated that increasing of damping capacity was caused by grain growth. It means that grain size is effective factor to damping capacity.

• Transactions of Materials Processing
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• v.13 no.8
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• pp.704-709
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• 2004

The effect of annealing temperature on microstructures and mechanical properties of the 5052 Al sheets rolled 88% reduction at cryogenic temperature was investigated for the annealing temperature of 150 ~ $300^{\circ}C$, in comparison with those rolled at room temperature. The presence of equiaxed grains, whose size is about 200nm in a diameter, was observed in the alloy deformed 88% and annealed $200^{\circ}C$ for an hour. When compared with the deformation at room temperature, the deformation at cryogenic temperature showed the higher strengths and equivalent elongation after annealing at the annealing temperature below $200^{\circ}C$. However, for annealing above $250^{\circ}C$ materials deformed at cryogenic temperature showed the lower strength than those deformed at room temperature. This behavior might be attributed to the higher rate of recrystallization and growth in materials deformed at cryogenic temperature during annealing, due to the lager density of dislocations accumulated during the deformation.

• Journal of Surface Science and Engineering
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• v.48 no.1
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• pp.27-32
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• 2015

Advanced high strength steels undergo recrystallization annealing in reducing gas atmosphere before galvanizing to improve mechanical properties. The selective oxidations of elements such as Mn, Si, Cr and Al during annealing decrease wettability of liquid zinc, resulting in bare spots and other defects. In this work, Fe-3wt%Mn steel sheet was annealed at $780^{\circ}C$ for 1200 sec. in 5% $H_2-N_2$ atmosphere and then dipped into zinc bath held at $460^{\circ}C$, which contained 0.2wt% dissolved Al. MnO crystallines in the average size of 200 nm were formed on the surface after annealing. It is estimated that MnO has been detached into bath with the formation and growth of inhibition layer with longer immersion time during galvanizing. No evidence of aluminothermic reduction of MnO has been found in this study.

• Korean Journal of Materials Research
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• v.3 no.1
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• pp.50-57
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• 1993

Abstract The sintering behavior of the mechanically alloyed AI-8wt%Fe power during vacuum hot pressing was investigated and high temperature deformation behavior of the sintered specimen was studied through compression tests at various strain rates in the temperature range between 35$0^{\circ}C$ and 45$0^{\circ}C$. In 'addition, thermal stablity of the sintered specimem was examined by hardness measurement after annealing the spcimem for 60 hours in the temperature range of 30$0^{\circ}C$ ~50$0^{\circ}C$. The compressive stress increased rapidly with strain and reached the maximum point at the strain about 3%. With slight decrement after reaching the maximum point, the flow stress became constant up to the strain of 30% and it was considered to be due to equilibrium between work hardening and dynamic recrystallization. The hardness of the 60 hrs annealed specimens began to decrease rapidly at 40$0^{\circ}C$ .

• Transactions of Materials Processing
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• v.17 no.4
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• pp.240-248
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• 2008

The effect of alloying elements(Mn, S, Mo, B) on the high temperature deformation behavior of Fe-29%Ni-17%Co (Kovar) alloy were investigated. And the effect of high temperature oxidation on the hot ductility was also studied. The hot ductility of Kovar alloy was drastically increased with the addition of Mn and lowering of S content. It has been found that the brittle intergranular fracture at high temperature cracking is closely associated with the FeS sulfide along the grain boundary. When Mn was added, the type of sulfide was changed to MnS from FeS and ductile intergranular fracture and transgranular fracture were promoted. The formation of oxide layer was found to have minimized the hot ductility of the Kovar alloy significantly. Grain boundary micro-cracks in the internal oxide region were noted following deformation due to high temperature, one of which acting as a notch that caused the poor hot workability of the oxidized specimen. The addition of Mo to the Kovar alloy could also retard the decrease in the hot ductility of the oxidized specimen through the prevention of notching due to internal oxidation. Hot ductility was remarkably improved by the addition of Boron. The improvement of hot ductility results from the grain boundary migration mainly due to the dynamic recrystallization at lower temperature range ($900{\sim}1000^{\circ}C$).

• Korean Journal of Materials Research
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• v.4 no.3
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• pp.357-363
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• 1994

The irradiation growth of the Zircaloy-4 cladding in the KOFA fuel loaded in the Kori-2 nuclear plant was measured to evaluate the irradiation growth behavior and to be compared with that of the Siemens cladding having different manufacturing process. Due to the partial recrystallization by final heat treatment, the KOFA Zircaloy-4 cladding showed a two step irradiation growth behavior such as the growth saturation and the accerlation which is typical of the fully annealed Zircaloy cladding. The difference in the measured irradiation growth rate between the KOFA and the Siemens cladding could be explained by the difference in the cladding texture which depends on the manufacturing process. From the measured irradiation growth data of Kori-2 KOFA fuel, a two-step irradiation growth model of the KOFA Zircaloy-4 cladding was derived, the accuracy of which can be more clearly verified as the measured data of the irradiation growth are accumulated in the future.

• Journal of Applied Reliability
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• v.16 no.2
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• pp.155-161
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• 2016

Purpose: Purpose of this study is to analyze the effect of particle size as well as number of pass on surface microstructure and hardness of SiC(p)/AZ31 surface composite fabricated by friction stir process (FSP). Method: SiC(p)/AZ31 surface composite containing different size of SiC particle (i. e., $2{\mu}m$ and $8{\mu}m$) was fabricated by multi-pass FSP. Microstructure was observed by scanning electron microscope and surface hardness was determined by Vickers hardness tester. Results: For all the FSPed specimens with and without hardening particles, grain size was refined due to dynamic recrystallization behavior. Surface hardness was observed to increase with decreasing particle size in the composite layer. Increasing number of FSP pass was effective for homogeneous distribution of the hardening particles and for resulting increase in surface hardness. Conclusion: FSP was effective to modify surface microstructure for improving surface hardness of SiC/AZ31 composite.

• Bulletin of the Korean Chemical Society
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• v.31 no.8
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• pp.2223-2227
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• 2010

Reaction of [(bpy)Pd]$(PF_6)_2$ (bpy = 2,2'-bipyridine) with racemic bis(isonicotinoyl)-1,1'-bi-2-naphtholate (L) in acetone, and followed by addition of chloroform and solvent evaporation allows to form amorphous micro-bowl morphology consisting of $[(bpy)PdL]_2(PF_6)_4$ without any template or additive. In contrast, the reaction and recrystallization in acetone for 1 week produce parallel-piped single crystals consisting of $[(bpy)_3Pd_3({\mu}_3-HPO_4)_2](PF_6)_2$. The formations of micro-bowl and parallel-piped single crystal morphologies appear to be primarily associated with the kinetic and thermodynamic control, respectively. The formation of micro-bowls may be attributed to eruption of organic solvents. Cosolvent effects and chemical properties on the formation of micro-bowl morphology have been observed.

• Transactions of Materials Processing
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• v.13 no.1
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• pp.53-58
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• 2004

The microstructural changes of Al-Zn-Mg-Cu alloy containing Sc during hot extrusion and post heat treatment were investigated. Two kinds of Al-Sc alloys with different alloying elements (B1, B2) were hot extruded to make T-shape bars at extrusion temperature of $380^{\circ}C$, then the bars were solution treated at $480^{\circ}C$ for 2hrs followed by artificial aging at $120^{\circ}C$ for 24hrs. The interior microstructure of as extruded bar consisted of elongated grains, however, fine equiaxed grains were also observed around surface. The microstructural gradient suggested that different restoration process could proceed during the hot extrusion. For B1 and B2, different grain growth behaviors were found around the surface during the post heat treatment. Rapid grain growth behavior was observed for B1 around the surface, however, it was not observed for B2. Orientation pinning, which was related with the evolution of preferred orientation, and precipitation were thought to be responsible for the rapid grain growth.