• Title/Summary/Keyword: Recovery percentage

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Recovery of Palladium from a Mixture of Pt, Pd and Rh by Solvent Extraction

  • Kim, berly S. Svalstad;Kim, Nam-Soo;Kenneth N. Han
    • Proceedings of the IEEK Conference
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    • 2001.10a
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    • pp.482-488
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    • 2001
  • Platinum group metals (pgm) are useful to many industries such as chemical, dental and medical, petroleum, refining, electrical and electronic, and automotive. Researchers at the South Dakota School of Mines and Technology and PGM Recovery Ltd. have developed jointly an environmentally sound and metallurgically efficient process for extracting these metals from secondary sources. Once these metals have been dissolved in the leach liquor, the individual metals mainly platinum, palladium, and rhodium, should be separated in order to recover the individual metals with high purity. During this investigation, solvent extraction has been chosen as the method used to achieve the separation and extraction of platinum, palladium, and rhodium from the leach liquor. There were three solutions used throughout this procedure: 1) Synthetic solution (200 ppm Pt 80 ppm Pd 20 ppm Rh; 300 ppm Pt, 180 ppm Pd 50 ppm Rh), and 2) Auto catalyst leach liquors (100 ppm Pt, 30 ppm Pd, 20 ppm Rh). The solvents investigated included Lix 84(2-hydroxy-5-nonylacetonphenone oxime in a mixture with 5-dodecylsalicyloxime), Lix 84-I, ACORGA CLX-50 (diester of pyridine 3,5 dicarboxylic acid), and di-hexyl sulfide. The extraction values achieved using ACORGA CLX-50, Lix 84, and Lix 84-I were respectively Pt (25%, 0% 0%), Pd (100%, 99.8%, 95.3%), and Rh (99.1%, 35.5%, 4.25%). The stripping processes for the Lix 84, and Lix 84-I were proven to be more involved than others. The solutions were required to be simultaneously heated and stirred. The percentages acquired through these processes yielded unsatisfactory results. The stripping procedure for the ACORGA CLX-50 was easier to execute, yet the percentage recovered from this process was also unsatisfactory. Overall the di-hexyl sulfide has proved to be the most successful organic for this procedure. The average percent extracted for palladium was excellent with 99.9% - 100% with very little Platinum and rhodium extracted. The ability of stripping palladium in ammonia solution was also found to be excellent.

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A STUDY ON PHYSICAL PROPERTIES OF INTEROCCLUSAL RECORDING MATERIALS (악간 기록재료의 물리적 특성에 관한 연구)

  • Kang, Jeong-Kil;Yu, Hyoung-Woo;Ahn, Seung-Geun;Song, Kwang-Yeob;Park, Charn-Woon
    • The Journal of Korean Academy of Prosthodontics
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    • v.34 no.4
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    • pp.657-664
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    • 1996
  • The purpose of this study was to compare the dimensional stability, compression resistance, elastic recovery and surface hardness of elastomeric interocclusal recording materials. Five commonly used elastomeric interocclusal recording materials(Ramitec, Regisil, Blue-Mousse, Stat-Br, Coltoflax) were selected for this study. According to ADA specification No. 19, two types of specimen were fabricated. Cylinder type specimens were used to test compression resistance and elastic recovery and plate type specimens were used to evaluate dimensional stability and surface hardness. Paired t-test was applied to detect significance among the occlusal registration materials. The obtained results were as follows: 1. There were statistical difference in dimensional stability between the elastic interocclusal recording materials. The dimensional stability of silicone was higher than that of polyether tested(p<0.05). 2. Coltoflax was significantly less resistance to compression than the other elastic interocclusal recording materials(p<0.001). 3. The elastic recovery capacity of Blu-Mousse and Stat-Br is better than that of Coltoflax (p<0.01). 4. The surface hardness of Coltoflax was lower than that of Blu-Mousse and Stat-Br(p<0.05). 5. The percentage dimensional change of alll materials was acceptable according to the limid of 0.5% suggeted by ADA specificatin No. 19.

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Effect of Oxygenation of Cardioplegic Solution on Electrical Stability and Postischemic Recovery of Cardiac Function after Ischemic Arrest in Isolated Rat Heart[ I ] (백서의 적출된 심장에서 심정지액의 산소화가 허혈성 심정지후 심기능 회복에 미치는 영향[I])

  • 윤재도
    • Journal of Chest Surgery
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    • v.25 no.2
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    • pp.125-130
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    • 1992
  • To evaluate the effect of oxygenation[95% O2+5% CO2] of St. Thomas Hospital No.2 cardioplegic solution[Plegisol], 20 isolated perfused rat hearts were studied under hyp-othermic[20oC] ischemic arrest for 2 hours with infusion of cardioplegic solution every 30 minutes throughout the ischemic period. Ten isolated hearts were studied with the oxygenated cardioplegic solution and 10 another isolated hearts with the nonoxygenated one. Mean oxygen tensions of the nonoxygenated and oxygenated cardioplegic solutions were 150mmHg and 470mmHg, respectively. Two in 10 hearts infused with the nonaxygenated cardioplegic solution were not recovered from nonworking heart due to persistent ventricular fibrillation. In comparing hem-odynamic parameters between both groups, the mean postischemic recovery[expressed as a percentage of its preischemic control value] was significantly greater with the oxygenated solution[in 10 recovered hearts] than the nonoxygenated solution[in 8 recovered hearts] [95.9$\pm$1.8% compared with 88.5$\pm$2.9% in peak aortic pressure, p<0.05, 75.7$\pm$5.2% compared with 43.5$\pm$6.5% in aortic flow, p<0.01, 75.5$\pm$4.6% compared with 54.1$\pm$5.6% in cardiac output, p<0.01, 78.3$\pm$4.6% compared with 60.3$\pm$4.6% compared with 60.3$\pm$6.2% in stroke volume, p<0.05, and 80.4$\pm$5.3% compared with 58.6$\pm$7.0% in dP/dT, p<0.05]. It is concluded that oxygenation of St. Thomas Hospital No.2 cardioplegic solution improves cardiac electrical stability and postischemic hemodynamic recovery after ischemic arrest in the isolated perfused rat heart.

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Recovery of Tin and Copper from Waste Solder Stripper by Oxalate Precipitation (옥살레이트 침전법에 의한 폐솔더 박리액에서 주석 및 구리의 회수)

  • Ryu, Seong-Hyung;Ahn, Jae-Woo;Ahn, Hyo-Jin;Kim, Tae-Young
    • Resources Recycling
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    • v.23 no.3
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    • pp.37-43
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    • 2014
  • A study has been made on the recovery of tin and copper from waste solder stripper by oxalate precipitation. With the increasing of the oxalic acid addition, tin was precipitated effectively and removed above 99.5% of tin when the oxalic acid, in an amount 1.0-1.5 times the stoichometric requirement, was added. But, in this case, only 2.0% of copper was precipitated and lead, iron were not precipitated. So, tin was selectively removed from the waste solution. With the increasing of the reaction temperature, the removal percentage of tin was increased and maximum value at arounf $60^{\circ}C$ and decreased with increase in the temperature any more. After filtering the precipitate and drying in oven, $SnO_2$ was obtained from the precipitate. After removal of tin in stripping solution, above 91% of copper was selectively removed by Cu-oxalate by addition of oxalic acid.

The Effects of Semi-Fowler's position on Post-Operative Recovery and Pain for Patients with Laparoscopic Abdominal Surgery (복강경 수술 후 반좌위가 수술회복성과 통증에 미치는 영향)

  • Choi, Un Jong;Ha, Tae Uk;Kang, Ji Sook
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.5
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    • pp.412-419
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    • 2017
  • Purpose:This study was conducted to identify the effects of theSemi-Fowler's position on post-operative recovery and pain for patients with laparoscopic abdominal surgery Methods: This study utilized a non-equivalent control group non-synchronized design to validate the effects of theSemi-Fowler's position. After IRB approval, 56 patients took part in this study, 29 in the experimental group and 27 in the control group. Consent was obtained from the participants. The Semi-Folwer's position was applied to experimental group and the supine position was applied to the control group for 24 hours after surgery. All data were reviewed retrospectively from April to June 2016. Collected data, frequency, percentage, average, standard deviation, chi-squared test, independent t-test and repeated measures ANOVA were conducted using SPSS 20.0. Results: There was no significant difference between the experimental and control group with regard to recovery outcomes; however, there was a significance differencebetween groups and among check times with regard to post operational pain. Conclusion:The results of this study provide information that will be usefulto the development of strategies for improving recovery outcomes and pain for laparoscopic operation patients.

Effect of Soil Sulfur treatment on Apple Valsa Canker (유황토분 처리가 사과 부란병에 미치는 영향)

  • Chun, Ik-Jo;Park, Seung-Min
    • Korean Journal of Organic Agriculture
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    • v.25 no.1
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    • pp.125-134
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    • 2017
  • This study was carried out to examine the effects of soil sulfur mixture on the control apple valsa canker in apple orchard for two years. In organic apple orchard, The recovery percentages of apple valsa canker were compared among control (no treatment), lime sulfur, and soil sulfur in organic orchards. In conventional apple orchards, those of recovery percentages were compared among control, neoasozin, lime sulfur, and soil sulfur. Compared with control, soil sulfur treatments significantly improved the recovery percentages of apple valsa canker infected trees in organic orchard. However, there were no differences between lime sulfur and soil sulfur treatment in organic apple orchard, except BongHyun orchard experiment in 2013. Compared with control fruit qualities, fruit skin red color and fruit firmness were improved in lime sulfur and soil sulfur treatment, respectively. In conventional orchard, apple trees treated with lime sulfur, soil sulfur or neoasozin improved recovery percentages, compared with those of control trees. Soil sulfur treatments recovered 87.5~97.5% of infected 'Fuji'/MM106 apple trees in organic and conventional apple orchards. The trees applied with neoasozin showed significant lower shoot growth than those of soil sulfur treatment in conventional orchard. Soli sulfur treatment improved fruit red color, but did not affected fruit weight, fruit firmness, soluble solids concentrations, and titratable acidity.

Evaluation of Vegetation Recovery after Restoration Works at the Jungbong and Nuebong Area, Mudeungsan National Park (무등산국립공원 중봉과 누에봉 복원공사지역 식생회복 평가)

  • Kim, Young-Sun;Shim, Seok-Young
    • Korean Journal of Environment and Ecology
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    • v.33 no.1
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    • pp.64-74
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    • 2019
  • The purpose of this study is to assess the degree of vegetation recovery such as the vegetation change and the effect of artificial restoration measures according to the number of years since the restoration works at the damaged Jungbong and Nuebong area in Mudeungsan National Park. We set up a total of 21 survey areas including 11 monitoring areas to analyze the flora, relative dominance, species diversity, and similarity in the restored site after relocation of Zungbong army base in 1996 and the restored site after the demolition of Neeebong telecommunication facility in 1999 and 10 control areas in the adjacent natural forest to assess the vegetation recovery in the restored sites and the nearby natural forest. The Mean Similarity Index of seed composition was relatively low at 3.5% in the Jungbong restoration site 17 years after the restoration, and the height of shrub layer, in which azaleas and furred azaleas appeared, recovered to the level of 82.6%. We concluded that it is necessary to continue monitoring the restored sites to develop the recovery assessment method and recovery work technology for sub-alpine areas in Mudeungsan National Park and other national park areas.

Reduction of oocyte lipid droplets and meiotic failure due to biotin deficiency was not rescued by restoring the biotin nutritional status

  • Tsuji, Ai;Ikeda, Yuka;Murakami, Mutsumi;Kitagishi, Yasuko;Matsuda, Satoru
    • Nutrition Research and Practice
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    • v.16 no.3
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    • pp.314-329
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    • 2022
  • BACKGROUND/OBJECTIVES: Oocyte lipid droplets play a crucial role in meiosis and embryo development. Biotin is associated with fatty acid synthesis and is the coenzyme for acetyl-CoA carboxylase (ACC). The effects of a biotin deficiency on the oocyte lipid metabolism remain unknown. This study examined the effects of a biotin deficiency and its replenishment on murine 1) oocyte lipid droplet levels, 2) ovary lipid metabolism, and 3) oocyte meiosis. MATERIALS/METHODS: Mice were divided into 3 groups: control, biotin deficient (BD), and recovery groups. The control and BD groups were fed a control diet or BD diet (0.004 or 0 g biotin/kg), respectively. The recovery group mice were fed a BD diet until day 21, and were then fed the control diet from days 22 to 64. This study then quantified the oocyte lipid droplet levels, assessed the oocyte mitochondrial function, and examined the ability of oocytes to undergo meiosis. Ovarian phosphorylated ACC (p-ACC), lipogenesis, β-oxidation, and ATP production-related genes were evaluated. RESULTS: The BD group showed a decrease in lipid droplets and mitochondrial membrane potential and increased p-ACC levels. In the recovery group, the hepatic biotin concentration, ovarian p-ACC levels, and mitochondrial membrane potential were restored to the control group levels. On the other hand, the quantity of lipid droplets in the recovery group was not restored to the control levels. Furthermore, the percentage of oocytes with meiotic abnormalities was higher in the recovery group than in the control group. CONCLUSIONS: A biotin deficiency reduced the oocyte lipid droplet levels by downregulating lipogenesis. The decreased lipid droplets and increased oocyte meiosis failure were not fully restored, even though the biotin nutrition status and gene expression of lipid metabolism was resumed. These results suggest that a biotin deficiency remains robust and can be long-lasting. Biotin might play a crucial role in maintaining the oocyte quality.

Performance Characteristics of Refrigeration Cycles with Ejector using Refrigerants (이젝터를 적용한 냉동사이클의 냉매종류별 성능특성)

  • Yoon, Jung-In;Kim, Chung-Lae;Son, Chang-Hyo
    • Journal of Power System Engineering
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    • v.21 no.1
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    • pp.24-29
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    • 2017
  • Studies in liquid-vapor ejector, which performs a great efficiency in refrigeration cycle is highly concerned. This paper is based on basic refrigeration cycle and three ejector refrigeration cycles and the comparison and contrasts about when 6 different refrigerants are applied to such refrigeration cycles. All cycles had a percentage increase of COP from 4 to 74% when ejector was applied, and the source of increasement was the decrease of total work done due to ejector's pressure recovery function. When R-245fa is applied to cycle (d), results showed that COP was the most superior in such cycle, R-245fa showed high volume entrainment ratio in all cycles. Future studies in refrigeration cycles will require more knowledge and experiments on ejector's appliance to refrigeration cycles and the actuation of such functions.

Post-Damage Repair of Prestressed Concrete Girders

  • Ramseyer, Chris;Kang, Thomas H.K.
    • International Journal of Concrete Structures and Materials
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    • v.6 no.3
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    • pp.199-207
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    • 2012
  • Concrete is an economical construction material and for that reason it is widely used in buildings and infrastructures. The use of deicing salts, expansion joint failure, and freeze-thaw cycles have led to concrete bridge girders experiencing corrosion of steel reinforcement and becoming unsafe for driving. The goal of this research is to assess the effectiveness of current and possible repair techniques for the end region of damaged prestressed concrete girders. To do this, three American Association of State Highway and Transportation prestressed concrete girders were tested to failure, repaired, and retested. Three different repair materials were tested including carbon fiber, glass fiber, and surface mounted rods. Each different repair material was also tested with and without injected epoxy. Comparisons were then made to determine if injecting epoxy had a positive effect on stiffness and strength recovery as well as which repair type regained the largest percentage of original strength.