• Title/Summary/Keyword: Recovered Product

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Rare earth removal from pyroprocessing fuel product for preparing MSR fuel

  • Dalsung Yoon;Seungwoo Paek;Chang Hwa Lee
    • Nuclear Engineering and Technology
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    • v.56 no.3
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    • pp.1013-1021
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    • 2024
  • A series of experiments were performed to produce a fuel source for a molten salt reactor (MSR) through pyroprocessing technology. A simulated LiCl-KCl-UCl3-NdCl3 salt system was prepared, and the U element was fully recovered using a liquid cadmium cathode (LCC) by applying a constant current. As a result, the salt was purified with an UCl3 concentration lower than 100 ppm. Subsequently, the U/RE ingot was prepared by melting U and RE metals in Y2O3 crucible at 1473 K as a surrogate for RE-rich ingot product from pyroprocessing. The produced ingot was sliced and used as a working electrode in LiCl-KCl-LaCl3 salt. Only RE elements were then anodically dissolved by applying potential at - 1.7 V versus Ag/AgCl reference electrode. The RE-removed ingot product was used to produce UCl3 via the reaction with NH4Cl in a sealed reactor.

Synthesis of TiCx Powder via the Underwater Explosion of an Explosive

  • Tanaka, Shigeru;Bataev, Ivan;Hamashima, Hideki;Tsurui, Akihiko;Hokamoto, Kazuyuki
    • Metals and materials international
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    • v.24 no.6
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    • pp.1327-1332
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    • 2018
  • In this study, a novel approach to the explosive synthesis of titanium carbide (TiC) is discussed. Nonstoichiometric $TiC_x$ powder was produced via the underwater explosion of a Ti powder encapsulated within a spherical explosive charge. The explosion process, bubble formation, and synthesis process were visualized using high-speed camera imaging. It was concluded that synthesis occurred within the detonation gas during the first expansion/contraction cycle of the bubble, which was accompanied by a strong emission of light. The recovered powders were studied using scanning electron microscopy and X-ray diffraction. Submicron particles were generated during the explosion. An increase in the carbon content of the starting powder resulted in an increase in the carbon content of the final product. No oxide byproducts were observed within the recovered powders.

Influence of Adding Recovered Protein from Processing Wastewater on the Quality of Mechanically Separated Chicken Meat Surimi Like-Material

  • Cortez-Vega, William Renzo;Fonseca, Gustavo Graciano;Bagatini, Daniela Cardozo;Prentice, Carlos
    • Food Science of Animal Resources
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    • v.37 no.2
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    • pp.162-167
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    • 2017
  • Functional and nutritional soluble proteins can be recovered from surimi (and surimi-like material) processing wastewater, reducing environmental problems and the cost of an irresponsible waste disposal. Recovered proteins may be added back at a low percentage to surimi products. The aim of this work was to evaluate the effect of the addition of soluble recovered proteins (RP), obtained from mechanically separated chicken meat surimi-like material (MSCM-SLM) processing wastewater by acidic pH-shifting, on the composition and texture of RP-MSCM-SLM, with RP contents of 0, 10, 20 and 30% (w/w) in the mixture. For that, proximate composition and gel properties were evaluated. The fat content of the MSCM-SLM was significantly reduced to 11.98% and protein increased to 83.64% (dry basis) after three washing cycles. The addition of 30% RP in the MSCM-SLM significantly augmented the protein content to 93.45% and reduced fat content from to 2.78%. On the other hand, the addition of RP was responsible for a drastic decrease in texture parameters, reaching 252.36 g, 185.23 g.cm, and 6.97 N for breaking force, gel strength and cutting strength, respectively, when 30% of RP was included in the MSCM-SLM. It was concluded that the obtained intermediary product (RP-MSCM-SLM) is a good option to applications in processed meat products where high texture parameters are dispensable, e.g., emulsified inlaid frankfurter-type sausages, but high protein content and low fat content desired.

Characterization of a Chalcosyltransferase (gerGTII) in Dihydrochalcomycin Biosynthesis

  • Pageni, Binod Babu;Oh, Tae-Jin;Thuy, Ta Thi Thu;Sohng, Jae Kyung
    • Molecules and Cells
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    • v.26 no.3
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    • pp.278-284
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    • 2008
  • An open reading frame, designated GerGTII and located downstream of the polyketide synthase genes, has been identified as a chalcosyltransferase by sequence analysis in the dihydrochalcomycin biosynthetic gene cluster of Streptomyces sp. KCTC 0041BP. The deduced product of gerGTII is similar to several glycosyltransferases, authentic and putative, and it displays a consensus sequence motif that appears to be characteristic of a sub-group of these enzymes. Specific disruption of gerGTII within the S. sp. KCTC 0041BP genome by insertional in-frame deletion method, resulted complete abolishment of dihydrochalcomycin and got the 20-O-mycinosyl-dihydrochalconolide as intermediate product in dihydrochalcomycin biosynthesis which was confirmed by electron spray ionization-mass spectrometry and liquid chromatography-mass spectrometry. Dihydrochalcomycin also was recovered after complementation of gerGTII.

The Application of Perfluorinated Cation-exchange Membrane in the Catalytic Process (촉매공정에서 양이온 교환 분리막의 응용)

  • 변홍식
    • Membrane Journal
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    • v.2 no.1
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    • pp.49-58
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    • 1992
  • Functionalized organic polymers have been used as supports for heterogenized homogeneous catalytic process[1]. Sprcific advantages of using these resins as support reagents have been reviewed[2-4]. These include: -ease of by-product separation from the main reaction product usuallyby simple filtration. -prevention of intermolecular reaction of reactive species or functional groups by simulating high dilution conditions[5]. -utility of the "fish-hook" principle in which a minor component in fished out of a large excess substrate by the insoluble polymer[6]. -the possibility of reusing recovered reagents as well as eliminating the use of volatile or noxious substances[7]. Catalysis by ion-exchange membranes is perhaps one of the latest examples of the use of a polymer-supported species. Conceptually, catalysts on membrane supports offer several possible advantages over traditional powder type systems. They are: (1) Membranes immobilize the catalyst, preventing agglomeration. (2) Filtration is unnecessary for the catalyst separation and so complete catalyst recovery is facilitated. (3) Catalytyic and separation processes can be combined, allowing membrane supported catalysts for the continous flow reactors. reactors.

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The Acid Sensitivity of Gulose and Mannose in Chemically-Reduced Alginates Obtained from Pseudomonas syringae

  • Ashby, Richard D.;Day, Donal F.;Kim, Du-Woon
    • Food Science and Biotechnology
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    • v.15 no.4
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    • pp.555-558
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    • 2006
  • The chemical reduction of Pseudomonas syringae subsp. phaseolicola alginates produces neutral polymers of D-mannose and L-gulose in source specific ratios. L-Gulose was highly sensitive to degradation by 1N HCl at $100^{\circ}C$. As hydrolysis time increased, gulose recovery decreased to 22% after 4 hr, whereas 98% of the D-mannose was recovered under the same conditions. Thin layer chromatography showed the formation of a second product upon L-gulose acid hydrolysis. This new product had a rate of flow (Rf) value of 0.58, identical to that of 1,6 anhydro-${\beta}$-D-mannopyranose and very close to that of 1,6 anhydro-${\beta}$-D-glucopyranose (Rf=0.60). Because of the difference in acid sensitivity between L-gulose and D-mannose, normal acid hydrolytic techniques applied to reduced alginates produces erroneous mannuronic acid (M): guluronic acid (G) ratio's unless one accounts for the differential rates of destruction of each sugar.

Factory Automation(FA) in Korea firms and Development Strategy (한국산업의 공장자동화와 발전전략)

  • 이근희;안문영
    • Journal of Korean Society of Industrial and Systems Engineering
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    • v.14 no.23
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    • pp.71-100
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    • 1991
  • Investment in FA facilities has been accerelated since 1986, turning point by labor strife in Korea firms. Most commonly adopted automation tech, in their manufacturing process consists of NC. Robotics, PLC, CAD/CAM now on and further confused system oriented FMS, CIM, etcs. undergoing. But for all their remarkable notices in manufacturing systems, The competitive position on product cost, quality, shorten delivery and profit has never been recovered in global swing market. To make some empirical suggestions with a view to competitive strategy of Korea firms by FA, to the conclusion largely FA tech. adoption can be justified only when its application on new product productions and improved the structure of products comparatively. Because of when it was applied in old production process. The effectiveness is very doubtful to the lacks of consistent and integrate manufacturing policy with the strategy of the fim and their poor standardization level in shop floors.

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U/RE Recovery Using Large-Scale LCC Electrowinning System

  • Kim, Si Hyung;Shim, Joon-Bo;Jang, Junhyuk;Kwon, Sang-Woon;Lee, Young Sang;Kwon, Youngwoo;Kim, Gha-Young;Lee, Sung-Jai
    • Proceedings of the Korean Radioactive Waste Society Conference
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    • 2018.05a
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    • pp.53-54
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    • 2018
  • U/RE was electrochemically recovered to LCC at $50mA/cm^2$ from LiCl-KCl salt containing $0.5wt%UCl_3$, $0.22wt%NdCl_3$, 0.15wt%$CeCl_3$ and $0.07wt%LaCl_3$. The Cd in the LCC deposit was removed during the distillation using Cd distiller. U/RE product of 107g obtained from the distiller was installed to TG and then heated to $1200^{\circ}C$ to be consolidated. Dense U/RE metal ingot was not acquired through the consolidation process because U/RE product had been partially already oxidized during the distillation process.

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A study on the Identification of Sources for Benzene Detected in the Casting Process (주조공정에서의 벤젠 발생원 규명에 관한 연구)

  • Oh, Doe Suk;Lee, Seong Min;Lee, Byoung Jae;Kim, Young Ju
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.16 no.1
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    • pp.27-35
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    • 2006
  • The aim of this study was to identify the sources of benzene detected in airborne of casting workplace where benzene was not used as raw material. We have identified benzene by GC/FID and GC/MSD. In this pilot test, small size iron chamber(diameter 30 cm, height 20 cm) was used. As the raw materials, new sand, recovered sand, and mixed casting sand(new sand + solidifying agent + organic resin + coating material) was tested, respectively. In the new sand benzene was not detected, but in the recovered sand and the mixed casting sand was detected. Xylenesulfonic acid(solidifying agent), one of the mixed casting sand ingredients was thought to product benzene by thermal decomposition above $400^{\circ}$..., but the other raw materials(organic resin and coating material) were thought not to product benzene. In this experiment, the most of benzene by thermal decomposition was produced within 1 hour after pouring the iron solution($1560^{\circ}$...) in small size iron chamber. When the mixed casting sand with coating material was used, the concentration of the produced benzene was average 2.91 ppm(range 1.98~3.72 ppm), and without coating material, benzene concentration was average 0.11 ppm(range 0.08~0.14 ppm).

A CONCEPTUAL STUDY OF PYROPROCESSING FOR RECOVERING ACTINIDES FROM SPENT OXIDE FUELS

  • Yoo, Jae-Hyung;Seo, Chung-Seok;Kim, Eung-Ho;Lee, Han-Soo
    • Nuclear Engineering and Technology
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    • v.40 no.7
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    • pp.581-592
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    • 2008
  • In this study, a conceptual pyroprocess flowsheet has been devised by combining several dry-type unit processes; its applicability as an alternative fuel cycle technology was analyzed. A key point in the evaluation of its applicability to the fuel cycle was the recovery yield of fissile materials from spent fuels as well as the proliferation resistance of the process. The recovery yields of uranium and transuranic elements (TRU) were obtained from a material balance for every unit process composing the whole pyroprocess. The material balances for several elemental groups of interest such as uranium, TRU, rare earth, gaseous fission products, and heat generating elements were calculated on the basis of the knowledge base that is available from domestic and foreign experimental results or technical information presented in open literature. The calculated result of the material balance revealed that uranium and TRU could be recovered at 98.0% and 97.0%, respectively, from a typical PWR spent fuel. Furthermore, the anticipated TRU product was found to emit a non-negligible level of $\gamma$-ray and a significantly higher level of neutrons compared to that of a typical plutonium product obtained from the PUREX process. The results indicate that the product from this conceptual pyroprocessing should be handled in a shielded cell and that this will contribute favorably to retaining proliferation resistance.