• Bulletin of the Korean Chemical Society
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• v.31 no.5
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• pp.1257-1261
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• 2010

The electrochemical performances of anode composites comprising elemental silicon (Si), silicon monoxide (SiO), and graphite (C) were investigated. The composite devoid of elemental silicon (SiO:C = 1:1) and its carbon coated composite showed reduced capacity degradation with measured values of 606 and 584 mAh/g at the fiftieth cycle. The capacity retention nature when the composites were cycled followed the order of Si:SiO:C = 3:1:4 < Si:SiO:C = 2:2:4 < SiO:C = 1:1 < SiO:C = 1:1 (carbon coated). A comparison of the capacity retention properties for the composites in terms of the silicon content showed that a reduced silicon content increased the stability of the composite electrodes. Even though the carbon-coated composite delivered low capacity during cycling compared to the other composites, its low capacity degradation made the anode a better choice for lithium ion batteries.

• Korean Chemical Engineering Research
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• v.49 no.5
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• pp.554-559
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• 2011

To improve the safety and electrode characteristics of lithium metal anode, physically coated electrodes on lithium metal surface by three kinds of carbon are prepared and their charge-discharge performances are investigated by adopting the C-Li electrodes as the anode of rechargeable lithium batteries. The lithium anode coated by the carbon powder with smaller particle size and higher surface area, which has higher packing density and lower surface roughness, shows better performance in charge-discharge characteristics. The carbon coating on lithium surface can be more effective in small-sized cells.

• Journal of Hydrogen and New Energy
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• v.8 no.4
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• pp.161-171
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• 1997

$AB_2$ type Zr-based Laves phase alloys have been studied for potential application as negative electrode in Ni/MH batteries. However, They have a serious disadvantage of poor activation behavior in KOH solution. In this work, a new method of alloy design method was tried for improving Zr-based alloy activation. this method has focused on phase controlling to make multi-phase microstructure. In the case of multi-phase Zr-V-Mn-Ni shows good performance in activation, but activation mechanism has not been known. So, we were in search of elucidating this mechanism, Using morphological and electrochemical analysis, we could find that surface morphology and electocatalytic activity of the alloy change during immersion in KOH solution. V-rich second phases are selectively corroded and dissolved and then become Ni-rich phases. Resulting from these surface reaction in KOH solution, self-hydrogen charging occurs through Ni-rich phase. However, the alloy has poor cyclic durability because of such a corrosion mechanism. Therefore, finally we developed durable alloys by substitution of other alloying element.

• Journal of the Korea Institute of Information and Communication Engineering
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• v.14 no.11
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• pp.2569-2574
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• 2010

In this paper, we introduce an efficient energy management using a notion of virtual energy system for shared solar-powered sensor network. Virtual energy system is an abstraction that allows sensor network applications on a node to reserve their own fractions of the shared solar cell and the shared rechargeable battery, hence achieving logically partition of a shared renewable power source. Our results show that our design and implementation are reliable, lightweight and efficient, allowing proper isolation of energy consumption among applications.

• Journal of the Korean Electrochemical Society
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• v.9 no.1
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• pp.29-33
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• 2006

A new porous separator based on poly(vinyl chloride) (PVC)/poly(vinylidene fluoride-co-hexafluoro-propylene) (P(VdF-co-HFP)/poly(methyl methacrylate) (PMMA) was prepared by a phase inversion method. To enhance mechanical property, the membrane was stretched uniaxially at high temperature. Tensile strength and ionic conductivity were measured for various draw ratios. The tensile strength and ionic conductivity were increased with increasing draw ratio. The tensile strength of the separator reached 52MPa after stretching to draw ratio of 5, and the ionic conductivity of the separator was increased from $1.9Xs10^{-4}S/cm\;to\;4.6X10^{-4}S/cm\;at\;25^{\circ}C$. The stretched separator immersed in liquid electrolyte was electrochemically stable up to 4.7 V. The cell based on the stretched separator was maintained at about 99% of the initial discharge capacity after 10th cycle operation at 0.2C rate.

• Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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• 2010.10a
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• pp.531-534
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• 2010

In this paper, we introduce an efficient energy management using a notion of virtual energy system for shared solar-powered sensor network. Virtual energy system is an abstraction that allows sensor network applications on a node to reserve their own fractions of the shared solar cell and the shared rechargeable battery, hence achieving logically partition of a shared renewable power source with no change in design and implementation. Our results show that our design and implementation are reliable, lightweight and efficient, allowing proper isolation of energy consumption among applications.

• Journal of the Korean Electrochemical Society
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• v.10 no.2
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• pp.82-87
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• 2007

New porous separators based on non-polyolefin materials including the blend of poly (vinyl chloride) (PVC)/poly (vinylidene fluoride-co-hexafluoropropylene) (P(VdF-co-HFP)/poly(methyl methacrylate) (PMMA), and the porous separator based on poly (vinylidene fluoride) (PVdF) were prepared by phase inversion method. The porosity and morphology were controlled with phase inversion rate, which is governed by the relative content of non-solvent and solvent in coagulation bath. To enhance tensile strength, the solvent pre-evaporation and uni-axial stretching processes were applied. The ionic conductivity was increased with increasing stretching ratio, and tensile strength was increased with increasing solvent pre-evaporation time and stretching ratio. The 200% stretched PVdF separator showed 56 MPa of tensile strength, and the ionic conductivity of the stretched PVdF separator was $8.6{\times}10^{-4}\;S\;cm^{-1}\;at\;25^{\circ}C$.

• Transactions of the Korean Society for Noise and Vibration Engineering
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• v.26 no.7
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• pp.881-887
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• 2016

In this study, the vibration-based tactile actuator for smart wear applications is presented by using piezoelectric ceramic transducers. The compact wireless actuation system is constructed with a high voltage piezoelectric amplifier, a microcontroller, wireless communication module, and rechargeable lithium-polymer battery. For the wireless communication between a hardware and an operator, the bluetooth-based wireless communication system is prepared and the user interface is provided via smart phone applications. From a series of experimental user studies, it is demonstrated that the proposed vibro-tactile actuator based on piezoelectric ceramic transducers can be effectively applied to smart wear applications.

• Bulletin of the Korean Chemical Society
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• v.31 no.9
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• pp.2519-2526
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• 2010

Silane-based self-assembly was employed for the surface modification of carbon-coated Si electrodes and their surface chemistry and electrochemical performance in battery electrolyte depending on the molecular structure of silanes was studied. IR spectroscopic analyses revealed that siloxane formed from silane-based self-assembly possessed Si-O-Si network on the electrode surface and high surface coverage siloxane induced the formation of a stable solid-electrolyte interphase (SEI) layer that was mainly composed of organic compounds with alkyl and carboxylate metal salt functionalities, and PF-containing inorganic species. Scanning electron microscopy imaging showed that particle cracking were effectively reduced on the carbon-coated Si when having high coverage siloxane and thickened SEI layer, delivering > 1480 mAh/g over 200 cycles with enhanced capacity retention 74% of the maximum discharge capacity, in contrast to a rapid capacity fade with low coverage siloxane.

• Journal of Power Electronics
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• v.16 no.2
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• pp.654-665
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• 2016

The pumping of electric power from photovoltaic (PV) farms is normally carried out using transformers, which require heavy mounting structures and are thus costly, less efficient, and bulky. Therefore, transformerless schemes are developed for the injection of power into the grid. Compared with the H4 inverter topology, the H6 topology is a better choice for pumping PV power into the grid because of the reduced common mode current. This paper presents how the perturb and observe (P&O) algorithm for maximum power point tracking (MPPT) can be implemented in the H6 inverter topology along with the improved sinusoidal current injected to the grid at unity power factor with the average current mode control technique. On the basis of the P&O MPPT algorithm, a power reference for the present insolation level is first calculated. Maintaining this power reference and referring to the AC sine wave of bus bars, a sinusoidal current at unity power factor is injected to the grid. The proportional integral (PI) controller and fuzzy logic controller (FLC) are designed and implemented. The FLC outperforms the PI controller in terms of conversion efficiency and injected power quality. A simulation in the MATLAB/SIMULINK environment is carried out. An experimental prototype is built to validate the proposed idea. The dynamic and steady-state performances of the FLC controller are found to be better than those of the PI controller. The results are presented in this paper.