• Title/Summary/Keyword: Reactor Operating Condition

Search Result 185, Processing Time 0.034 seconds

Hydrogen Production with High Temperature Solar Heat Thermochemical Cycle Using Dual-zone Reactor and CeO2/ZrO2 Foam Device (Dual-zone reactor와 CeO2/ZrO2 Foam Device를 이용한 고온 태양열 열화학 싸이클의 수소 생산)

  • Cho, Ji-Hyun;Seo, Tae-Beom
    • Journal of the Korean Solar Energy Society
    • /
    • v.37 no.5
    • /
    • pp.27-37
    • /
    • 2017
  • In this study, an artificial solar simulator composed of a 2.5 kW Xe-Arc lamp and mirror reflector was used to carry out the solar thermal two step thermochemical water decomposition cycle which can produce high efficiency continuous hydrogen production. Through various operating conditions, the change of hydrogen production due to the possibility of a dual-zone reactor and heat recovery were experimentally analyzed. Based on the reaction temperature of Thermal-Reduction step and Water-Decomposition step at $1,400^{\circ}C$ and $1,000^{\circ}C$ respectively, the hydrogen production decreased by 23.2% under the power off condition, and as a result of experiments using heat recovery technology, the hydrogen production increased by 33.8%. Therefore, when a thermochemical two-step water decomposition cycle is conducted using a dual-zone reactor with heat recovery, it is expected that the cycle can be operated twice over a certain period of time and the hydrogen production amount is increased by at least 53.5% compared to a single reactor.

Effect of Bioaugmentation on Performance of Intermittently Aerated Sewage Treatment Plant (Bioaugmentation이 간헐폭기 오수처리장치의 운전효율에 미치는 영향)

  • Jeong, Byung-Gon
    • Journal of Environmental Health Sciences
    • /
    • v.34 no.3
    • /
    • pp.233-239
    • /
    • 2008
  • In order to improve reactor performance of existing sewage treatment plants, the feasibility of enhancing reactor performance by bioaugmentation using EM as bioaugmentation agent and the effects of anoxic: oxic time ratio on reactor performance were investigated. Continuous and intermittent aeration modes were compared under the 6 hr of HRT. Three different types of intermittent aeration modes, that is, 15 min, of anoxic:45 min of oxic, 30 min of anoxic: 30 min of oxic, and 45 min of anoxic: 15 min oxic respectively were chosen as test modes to study the effects of anoxic : oxic time ratios on reactor performance. The optimum anoxic: oxic time ratio was 30 min:30 min when considering simultaneous removal of organic, nitrogen and phosphorus. When applying EM into a continuously aerated reactor under the varying dosing rates of 50-200 ppm, reactor performance in terms of organic and nitrogen removal efficiencies was not improved at all. Nitrogen removal efficiency was increase when the EM dosing rate was increased. However the degree of improvement was slight when the EM was injected above 100 ppm. However optimum phosphorus removal was found at the EM dosing of 200 ppm. Thus it was found that optimum injection concentration of EM is 200 ppm. It is apparent that putting EM into a sewage treatment plant significantly affects the T-N removal efficiency of the reactor by enhancing denitrification efficiency especially in operational conditions of relatively long anoxic periods. To achieve reciprocal condition in a reactor with intermittent aeration it is necessary to enhance the reactor performance by EM injection. In the case of modifying existing continuously aerated reactors into intermittent aerated reactors, it is obvious that operating costs of aeration would be reduced by reducing aeration time when compared with existing conventional sewage treatment plants.

Evaluation of Operating Parameters of Reject Water Treatment System with Pilot-scale Biofilm Nitritation Plant at Field Condition (반류수처리를 위한 현장 pilot plant 생물막 아질산화 반응조에서 운전인자 평가)

  • Han, Jinhee;Kwon, Min;Han, Jonghun;Yun, Zuwhan;Nam, Haiuk;Ko, Joohyung
    • Journal of Korean Society on Water Environment
    • /
    • v.23 no.5
    • /
    • pp.636-641
    • /
    • 2007
  • A pilot-scale biofilm nitiritation reactor was operated with the reject water from a large wastewater treatment plant. The effects of various operating parameters including pH, temperature, dissolved oxygen, solids and organic concentrations were examined. A stable nitritation was achieved at operating pH range of 7.3 to 8.8 with an alkalinity addition. Higher operating temperature of $35{\pm}0.7^{\circ}C$ achieved more stable nitritation compared to $30{\pm}0.2^{\circ}C$. It has been noticed that nitrite accumulation maintained with DO, solids and organic concentrations range of 0.8 to 3.9 mg/L, 3,400 to 11,000 mg/L, and 86 to 572 mg/L, respectively. It seems that the accumulation of nitrite was caused by both the inhibition of $NO_2{^-}$ oxidizers due to free ammonia and the maintenance of the high operating temperature of $35^{\circ}C$ which promote to accumulate the $NH_4{^+}$ oxidizers in the reactor. According to microbial community analysis of fluorescence in situ hybridization and INT-Dehydrogenase measurements, more nitrifiers were presented in attached form compared to suspended growth.

An Operating Strategy of In-house Power Supply Systems in the Permanent Shutdown Nuclear Power Plant (원자력발전소 영구정지 시 소내전력공급계통 운영방안)

  • Lim, Hee-Taek;Lee, Kwang-Dae;Jeon, Dang-Hee;Youn, Jong-Hyun;Joo, Ik-Deok
    • The Transactions of The Korean Institute of Electrical Engineers
    • /
    • v.67 no.2
    • /
    • pp.337-342
    • /
    • 2018
  • Spent fuel is moved from the reactor into the spent fuel pool when nuclear power plant permanently shutdown. The sole function of a permanently defueled facility is to store spent fuel in a quiescent state. The function of electric system and loads are reduced. It is necessary to establish an operating strategy of electric system in the permanent shutdown nuclear plant. This paper reviews required loads and design criteria considering transition to permanent shutdown. An operating strategy of onsite electric system is proposed considering decommissioning strategy and stage of defueled condition.

Effects of Environmental Factors on Nitrite Accumulation in a Strong Nitrogen Removal System (고농도 질소폐수 처리 공정에서 환경인자가 아질산염 축적에 미치는 영향)

  • Park, Noh-Back;Choi, Woo-Yung;Yoon, Ae-Hwa;Jun, Hang-Bae;Park, Sang-Min
    • Journal of Korean Society of Water and Wastewater
    • /
    • v.24 no.1
    • /
    • pp.51-62
    • /
    • 2010
  • The high concentration of N in the wastewater from livestock farming generally renders the efficiency of the wastewater treatment. Therefore, removal of N in livestock wastewater is crucial for successful treatment. The current study was conducted to investigate the optimum conditions for partial nitrification under anaerobic condition following nitritation in TPAD-BNR(two-phase anaerobic digestion-biological nitrogen removal) operating system. Sequential operating test to stimulate partial nitrification in reactor showed that partial nitrification occurred at a ratio of 1.24 in $NO_2{^-}$-N:$NH_4{^+}$-N. With this result, a wide range of factors affecting stable nitritation were examined through regression analysis. In the livestock wastewater treatment procedure, the hydraulic retention time (HRT) and pH range for optimum nitrite accumulation in the reactor were 1-1.5 days and 7-8, respectively. It was appeared that accumulation of $NO_2{^-}$-N in the reactor is due to inhibition of the $NO_2{^-}$-N oxidizer by free ammonia (FA) while the effect of free nitrous acid was minimal. Nitrification was not influenced by DO concentration at a range of 2.0-3.0 mg/L and the difference in the growth rate between $NH_4{^+}$-N oxidizer and $NO_2{^-}$-N oxidizer was dependent on the temperature in the reactor.

Numerical Calculations for the Optimal Performance of Regenerative Catalytic Oxidation(RCO) (축열식 촉매 산화(RCO) 반응의 성능 최적화를 위한 전산 해석)

  • Jung, Yu-Jin;Lee, Jae-Jeong;Jung, Jong-Hyeon;Kim, Jin-Uk;Shon, Byung-Hyun
    • Journal of the Korea Academia-Industrial cooperation Society
    • /
    • v.12 no.11
    • /
    • pp.5384-5391
    • /
    • 2011
  • The computational fluid dynamics was analyzed for the pressure distribution, stream velocity distribution, stream line field, retention time and temperature distribution which are applied to the catalyst layer in the RCO reactor to derive the optimum operating condition of the heat condensing type catalytic oxidation (RCO) reactor. The results from the computational analysis revealed that the pressure loss due to the ceramic honeycomb in the catalytic bed of the reactor which is operating currently is not significant and the stream velocity (1.8~2.7 m/s) after the ceramic filter is working in stability without big channeling. To improve the stream velocity distribution of the air stream, it is necessary to extension of the connecting range between the plenum and catalytic bed inside the facility. However, the method of attaching the air stream guide vane or the perforated plate inside the reactor was not so effective.

Numerical analysis of the coupled heat and mass transfer phenomena in a metal hydride hydrogen storage reactor(I) - Model development of analyzation for hydrogen absorption reaction using the $LaNi_5$ bed (금속수소화물 수소저장 용기 내부의 열 및 물질전달 현상에 대한 수치적 연구(I) - $LaNi_5$ 베드를 이용한 수소 흡장반응 해석 모델 개발)

  • Nam, Jinmoo;Ju, Hyunchul
    • 한국신재생에너지학회:학술대회논문집
    • /
    • 2010.06a
    • /
    • pp.225.1-225.1
    • /
    • 2010
  • Within recent years attention has been focused on the method of hydrogen storage using metal hydride reactor due to its high energy density, durability, safety and low operating pressure. In this paper, a numerical study is carried out to investigate the coupled heat and mass transfer process for absorption in a cylindrical metal hydride hydrogen storage reactor using a newly developed model. The simulation results demonstrate the evolution of temperature, equilibrium pressure, H/M atomic ratio and velocity distribution as time goes by. Initially, hydrogen is absorbed earlier from near the wall which sets the cooling boundary condition owing to that absorption process is exothermic reaction. Temperature increases rapidly in entire region at the beginning stage due to the initial low temperature and enough metal surface for hydrogen absorption. As time goes by, temperature decreases slowly from the wall region due to the better heat removal. Equilibrium pressure distribution appears similarly with temperature distribution for reasons of the function of temperature. This work provides a detailed insight into the mechanism and corresponding physicochemical phenomena in the reactor during the hydrogen absorption process.

  • PDF

A Study on Performance and Reactor Behavior of Chemical Refrigerator (화학식 냉동기의 성능 및 반응기 거동에 관한 연구)

  • Park, Seung-Hoon;Lee, Jong-Ho
    • Journal of Energy Engineering
    • /
    • v.6 no.1
    • /
    • pp.87-95
    • /
    • 1997
  • A chemical heat pump based on the reversible reactions between metal chlorides and ammonia gas is attractive alternative to compression system and liquid absorption systems in cooling and refrigerating fields. The advantages of chemical heat pump are no regulatory constants due to CFC refrigerants, utilization of gas, industrial waste heat, electricity, fuel oil etc. as heat sources and wide applications to energy storage system, large-scale energy managements for industrial process. The scale-up of chemical heat pump from laboratory prototype to pilot plants necessitates the interpretation of system performance and evaluation of dynamic behavior in the chemical reactor. This study contains the prediction of performance of chemical refrigerator according to operating condition, the dynamic simulations through reactor modelling, which is used for the calculation of reactive medium temperature and the conversion variation with reactor cooling temperature, and the effect survey of block parameters on the power of refrigerator.

  • PDF

Effect of operating conditions of high voltage impulse on generation of hydroxyl radical (고전압 펄스의 수중인가 조건이 하이드록실 라디칼 생성에 미치는 영향)

  • Cho, Seung-Yeon;Chang, In-Soung
    • Journal of Korean Society of Water and Wastewater
    • /
    • v.31 no.6
    • /
    • pp.611-618
    • /
    • 2017
  • Recently, applications of high voltage impulse (hereafter HVI) technique to desalting, sludge solubilization and disinfection have gained great attention. However, information on how the operating condition of HVI changes the water qualities, particularly production of hydroxyl radical (${\cdot}OH$) is not sufficient yet. The aim of this study is to investigate the effect of operating conditions of the HVI on the generation of hydroxyl radical. Indirect quantification of hydroxyl radical using RNO which react with hydroxyl radical was used. The higher HVI voltage applied up to 15 kV, the more RNO decreased. However, 5 kV was not enough to produce hydroxyl radical, indicating there might be an critical voltage triggering hydroxyl radical generation. The concentration of RNO under the condition of high conductivity decreased more than those of the low conductivities. Moreover, the higher the air supplies to the HVI reactor, the greater RNO decreased. The conditions with high conductivity and/or air supply might encourage the corona discharge on the electrode surfaces, which can produce the hydroxyl radical more easily. The pH and conductivity of the sample water changed little during the course of HVI induction.

Hydrogen production by catalytic decomposition of methane over carbon black catalyst in a fluidized bed on pressurized bench-scale condition (가압유동층 반응기에서 카본블랙 촉매를 이용한 메탄의 촉매분해에 의한 수소제조)

  • Seo, Hyung-Jae;Lee, Seung-Chul;Lee, Gang-In;Han, Gui-Young
    • 한국신재생에너지학회:학술대회논문집
    • /
    • 2009.06a
    • /
    • pp.791-793
    • /
    • 2009
  • Hydrogen has been recognized of the energy source for the future, in terms of the most environmentally acceptable energy source. A pressurized fluidized bed reactor made of carbon steel with 0.076 m I.D. and 1.0 m in height was employed for the thermocatalytic decomposition of methane to produce amount of $CO_2$ - free hydrogen with validity from a commercial point of view. The fluidized bed was proposed for withdrawing of product carbons from the reactor continuously. The methane decomposition rate with the carbon black N330 catalyst was rapidly reached a quasi-steady state and remained for several hour. The methane thermocatalytic decomposition reaction was carried out at the temperature range of 850 - 950 $^{\circ}C$, methane gas velocity of 2.0 $U_{mf}$ and the operating pressure of 1.0 -3.0 bar. Effect of operating parameters such as reaction temperature, pressure on the reaction rates was investigated and predicted the effect of a change in conditions on a chemical equilibrium thermodynamically, according to Le Chatelier's principle.

  • PDF