• 대한화학회지
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• 제27권3호
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• pp.218-223
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• 1983

새로운 반응성염료 개발의 일환으로 trifluoro-s-triazine을 반응성분으로 이용하여 한 분자에 2개의 서로 다른 chromophore를 가지는 반응성염료를 합성한 다음, 이의 가수분해속도와 면섬유에 대한 염색성을 조사하였다. 이 염료의 유사 일차 가수분해속도상수, $k_w$는 pH=10.0, 온도 $60{\circ}C$에서 k_w=2.6{\times}10^{-2}min^{-1}$로서 monochlorotriazine 반응성염료보다 높은 값을 보였으며 염착률과 고착율 역시 monochlorotriazine 계 염료보다 우수하였다. 얻어진 반응성 염료는 황색계열로서 수율은 75%였다.

• 한국염색가공학회지
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• 제22권2호
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• pp.94-100
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• 2010

Colored compounds adsorption from the textile dyeing effluents on activated carbons produced from various indigenous vegetable sources by zinc chloride activation is studied. The most important parameters in chemical activation were found to be the chemical ratio of $ZnCl_2$ to feed (3:1), carbonization temperature (460-470 $^{\circ}C$) and time of activation (75 min). The absorbance at 511 nm (red effluent) and 615 nm (blue effluent) are used for estimation of color. It is established that at optimum temperature ($50^{\circ}C$), time of contact (30-40 min) and adsorbent loading (2 g/L), activated carbons developed from rain tree (Samanea saman) saw dust and blackberry (Randia formosa) tree saw dust showed great capability to remove color materials from the effluents. It is observed that adsorption of reactive dyes by all types of activated carbons is more than that of disperse dyes. It is explained that because of its acidic nature the activated carbon can adsorb better reactive dye particles containing large number of nitrogen sites and $-SO_3Na$ group in their structure. The use of activated carbons from the indigenous biomass would be economical, because saw dusts are readily available waste worldwide.

• 한국재료학회지
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• 제27권5호
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• pp.255-262
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• 2017

Reactive oxygen species (ROS) can be produced by interactions between sunlight and light-absorbing substances in natural water environments and can completely destroy various organic pollutants in waste water. In this study, we used graphene oxide modified $Ag_2Se$ nanoparticles to enhance photochemically generated oxygen (PGO) species activity. Surface area and pore volumes of the $Ag_2Se-graphene$ ($Ag_2Se-G$) samples showed catastrophic decrease due to deposition of $Ag_2Se$. The generation of reactive oxygen species was detected through the oxidation reaction of DPCI to DPCO. The photocurrent density and the PGO effect increase in the case of the use of modified graphene. The PGO effect of the graphene modified with $Ag_2Se$ composites increased significantly due to a synergetic effect between graphene and the $Ag_2Se$ nanoparticles. The photocatalytic activity of sample was evaluated by measuring the degradation of organic pollutants such as methylene blue (MB) and industrial dyes such as Texbrite BA-L (TBA) under visible light.

• KSBB Journal
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• 제17권2호
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• pp.189-194
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• 2002

Trametes sp.에서 생산되는 laccase는 CNBr-activated Sepharose-4B(CAS4B)에 고정화 되었고, 염료의 연속적인 분해를 위하여 테스트되었다. Laccase는 CAS4B에 효율적으로 고정화되었고, CAS4B에 고정화 된 laccase는 pH, 열, 단백질 구조적인 안정성 면에서 상당히 증가하였다. CAS4B에 고정화 된 accase의 최적 pH는 5, 온도는 4$0^{\circ}C$로서 free laccase와 비교하여 변화가 없었다 기질로서 Reactive Blue 19를 사용하였을 때 free laccase와 고정화 laccase의 $K_{m}$ ($\mu$mol/mL) 값은 각각 0.34와 2.0이었고,V$_{max}$($\mu$mol/mL.min) 값은 각각 0.12, 0.1이었다. Repeated-batch 반응에서 효소의 안정성과 높은 분해 효율 만족하는 조건은 pH 5, 3$0^{\circ}C$이였다. 또한 HBT에 의한 효소의 불활성은 크게 나타나지 않았다. Packed-bed reactor에서 최적으로 운전되었을 때 100 $\mu$M Reactive Blue 19과 0.1 mM HBT가 존재하는 50 $\mu$M Acid Red 57의 연속적인 분해에서 30시간 후에도 분해 효율이 70%로 유지되었다. 고정화 laccase는 Packed-bed reactor에서 azo 염료의 연속적인 분해를 매우 안정적으로 수행하였다.다.

• 약학회지
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• 제50권5호
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• pp.313-321
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• 2006

There are three kinds of liquid petroleum marker which is extracted by the basic or acidic, and both developer. Korean marker, Unimark 1494 DB (marker) have been spectrophotometrically analysed by the determination of absorbance at 582 nm after base extraction by Unimark 1494 DB Developer C-5 (developer). Some blue dyes which have same reactive radical of marker and can be changed deep blue color in base developer extraction (BDE), may be increased absorbance at 582 nm, but dyes or markers which can be increased the absorbance, were not unclear. In this experiment, effects of three dyes or marker such as Orimax Green 151 (the mixture of CI Solvent Yellow 16 and CI Solvent Blue 70), quinizarin and Orimax Blue 2N (CI Solvent Blue 35), and two solvent such as topasol (P-250) and lubricant (P-8) on the absorbance were studied by HITACHI Recording Spectrophotometer U-3300. It shows that all of them increased absorbance at 582 nm after BDE. Absorbance at 582 nm can be showed 0.0544 by Orimax Green 151 at the concentration of 3.96 mg/l, quinizarin at the concentration of 1.38 mg/l, and Orimax Blue 2N at the concentration of 2.73 mg/l in the artificial petroleum (normal diesel oil: topasol: lubricant=2 : 4: 4), respectively. Absorbance, 0.0544 indicates that concentration of marker is 1.64 mg/l in the reference curves, respectively. And also these results can be showed that the artificial petroleum have about 10% cheep fuel such as kerosene which have marker (16.0 mg/l). Absorbance of P-250 was 0.01361-0.22842 depending upon the purchasing date, and that of P-8 was 0.05644. pH of developer was 14.83, and so this result indicates that Unimark 1494 DB is a base extractable petroleum marker, phenylazophenol (US Patent No. 5,252,106). In the BDE, the slight color of Orimax Blue 2N, Orimax Green 151 and quinizarin in artificial petroleum changed to deep bright blue color, respectively. These result indicate that the absorbance at 582 nm by BDE may be increased not only by azo, diazo, amine and ketone (anthraquinone, coumarin) dyes or markers, but also the contaminants of P-250 and P-8 which have same as reactive radical of dyes or markers.

• Fibers and Polymers
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• 제6권3호
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• pp.224-228
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• 2005

This paper focuses on the application of a novel mathematical limit approach derived for K/S values in reactive dyeing of cotton fabrics. The relation obtained from Kubelka-Munk equation is used because the Kubelka-Munk equation is the basic relationship among fabric reflectance, fabric dye content and dyestuff characteristics. The limit approach derived in a former paper is applied to the laboratory dyeings and the dyeing behavior of some reactive dyes on cotton knitted fabric has been obtained. The results of the laboratory experiments are discussed using the new mathematical approach. When the actual K/S values obtained from the dyeings and the calculated K/S values derived by the limit approach are considered independently, it is observed that the limit relation is val id for low dye concentration applications. When the K/S values are calculated taking the K/S value of the initial dyeing concentration $(0.1\;\%\;owf)$ as the starting concentration by applying the result of the derived limit approach, the calculated K/S values fit with the ones obtained in actual dyeings. It is concluded that the novel approach presented in the paper can be used in calculating the K/S values when the initial dyeings at low dye concentrations are carefully carried out.

• 한국의류학회지
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• 제24권6호
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• pp.819-827
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• 2000

The purpose of this study is to produce cotton fabric having improved dyeability and colorfastness as well as retaining the desirable durable press property. When cotton fabric was treated with additives, nitrogen content was increased as the additive concentration was increased. DP ratings and wrinkle recovery properties of BTCA treated cotton fabrics were greatly increased. But DP rating was lowered slightly by adding additives and wrinkle recovery property was decreased with the increase of additive concentration. Tensile strength was decreased by BTCA treatment but increased as additive concentration was increased. Various BTCA/additive treatments produced great affinity for reactive and acid dyes when dyebaths were adjusted at pH 3. It was showed that dyeability was increased as additive concentration was increased. The most effective additive for improving the dyeing properties of the crosslinked cotton was TEAㆍHCl. In case of reactive dye, there was almost no improvement on the dyeability of finished cotton by adding salt. Color fastness to washing and light of finished and dyed cotton were low except for the washfastness of reactive dye. Dyeing the BTCA/additive treated cotton fabrics with reactive dye had no effect on the physical properties.

• 한국염색가공학회지
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• 제27권1호
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• pp.1-10
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• 2015

The aim of the current study is to identify the dimerization and decomposition kinetics of the F-$D_M$ type. The regeneration of F-VS from $F_iF_j-D_M$ or the reversibility of the dimerizations were investigated. The order of real rate constants of the dimerization('$K_D{^{ij}}$) would seem to be similar to that of rate constants of a dimerization($K_D{^{ij}}$) for VS dyes at a given pH because of the constancy of the equilibrium constants($K_a{^j}$-value). The reverse reactions of the $D_M$ types are appeared to occur in two steps, the deprotonation of ${\alpha}$-carbon of the $D_M$ types and disproportionation. The ratio of the decomposition of the $D_M$ type to F-Hy and F-VS appears to be related with the ratio of $K_i/K_j$. Similarities were also found among various other reactions, including homo- and mixed dimerization. VS dyes undergoing fast hydrolysis have difficulty in forming a dimer. The higher the reactivity with cellulose or hydroxide ion, the smaller the dimerization. The easiness of the dimerization was thus found to be inversely proportional to the rate of hydrolysis.

• 한국염색가공학회지
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• 제19권1호
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• pp.1-11
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• 2007

Dyeing of polyester/cotton blends is usually carried out through the two-bath or one-bath two-step dyeing method using proper disperse dyes and reactive dyes for each fiber. However, the dyeing requires relatively long and complicated procedure as well as there are some problems such as lower dyeability. In the present study, new one-bath one-step dyeing process was investigated using disperse dyes having amino groups and hetero-bifunctional bridge compound(DBDCBS) including dichloro-s-triazinyl groups and ${\alpha},{\beta}$-dibromopropionylamido groups to improve the dyeability of cotton component in polyester/cotton blends. And the one-bath dyeing properties of polyester/cotton blends was evaluated by various dyeing conditions such as pH, temperature and dye concentration, The optimum dyeing condition was pH 4 and $110-120^{\circ}C$. Color fastness were relatively good because of the colvalent bond formation between DBDCBS-reacted cotton fiber and disperse dye.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
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• pp.190.1-190.1
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• 2016

One of the most serious problems faced by billions of people today is the availability of fresh water. According to statistics, 15% of the world's total output of dye products is discharged into the environment as dye wastewater, which seriously pollutes groundwater resources. For the treatment of chemically and biologically contaminated water the advanced oxidation processes (AOPs) shows the promising action. The main advantage with AOPs is the ability to degrade the organic pollutants to $CO_2$ and $H_2O$. For this degradation process the AOPs generation of powerful and non-selective radicals that may oxidize majority of the organic pollutants present in the water body. To generate the various reactive chemical species such as radicals (${\bullet}OH$, ${\bullet}H$, ${\bullet}O$, ${\bullet}HO_2$) and molecular species ($H_2O_2$, $H_2$, $O_2$) in large amount in water, we have used the atmospheric pressure plasma. Among the reactive and non-reactive species, the hydroxyl radical (${\bullet}OH$) plays important role due to its higher oxidation potential (E0: 2.8 V). Therefore, in this work we have checked the degradation of various dyes such as methyl orange, methylene blue and congo red using different type of atmospheric pressure plasma sources (Indirect jet and direct jet). To check the degradation we have used the UV-visible spectroscopy, HPLC and LC-MS spectroscopy. Further, to estimate role of ${\bullet}OH$ on the degradation of dyes we have studied the molecular dynamic simulation.