• 제목/요약/키워드: Reactive dyeing

검색결과 135건 처리시간 0.035초

Effect of Processing and Reactive Dyeing on Swelling and Pore Structure of Lyocell Fibers

  • Sasaki, Hiroaki;Donkai, Nobuo;Kasahara, Katusji
    • 한국섬유공학회:학술대회논문집
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    • 한국섬유공학회 2003년도 The Korea-Japan Joint Symposium
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    • pp.33-34
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    • 2003
  • Lyocell yarns were treated with NaOH, liquid ammonia, high pressure steam and polycarboxylic acids, and dyed with five reactive dyes. The water content of the samples was also measured by the centrifugal and chromatographic techniques. The total pore volume w as substantially increased by NaOH treatment, while decreased by high pressure steaming. The pore size distributions for the dyed samples were affected by the dyes used.

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Reactive Black Dyes containing Acetoxyethyl sulfone moiety

  • Kim, Tae-Kyung;Oh, Sea-Wha;Shin, Seung-Rim
    • 한국염색가공학회:학술대회논문집
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    • 한국염색가공학회 2001년도 춘계학술발표회 논문집
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    • pp.62-65
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    • 2001
  • This thesis related to a reactive black dyes containing acetoxyethyl sulfone moiety which is characterized by lessening the loss of dyes in filtering process owing to the low solubility by introducing the aminophenyl- $\beta$ -acetoxyethyl sulfone moiety, saving the cost for waste water treatment by using a small amount of salt in salting-out process and furthermore obtaining bright color with high dyeing yield and substantivity.

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견직물의 물성과 염색성 개선에 관한 연구 (A Study on the Improvement of Physical and Dyeing Properties of Silk Fabrics)

  • 장병호;박성윤
    • 한국염색가공학회지
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    • 제4권3호
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    • pp.122-130
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    • 1992
  • To improve the physical properties and the dyeing properties of silk, the silk fabric was treated with urea resin and reactive dyeing. The effects of urea resin concentration, pH of padding bath and curing condition were investigated in order to find optimum condition and the following results are obtained The optimum condition for the crease recovery of silk fabric was urea resin concentration of 80 g/ι, pH of 7, the curings temperature of about 135$^{\circ}C$, and the curing time of 3 minutes. The crease recovery and the thermal insulation ratio of silk fabric were increased by the above treatment. K/S increased as the adding amount of Na$_2$SO$_4$ increased, K/S, however was not affected by the adding amount of Na$_2$CO$_3$. Co1or fastness of the dyed fabrics treated with urea resin were improved slightly compared with untreated ones.

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Removal of EDCs from Industrial Sludge by Electron Beam

  • Han, Bumsoo;Kim, Jinkyu;Kim, Yuri;Jung, Seungtae;Park, Junhyung;Choi, Jangseung
    • 방사선산업학회지
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    • 제8권2호
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    • pp.71-76
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    • 2014
  • Endocrine disrupting chemicals (EDCs) and potential EDCs are mostly man-made, found in various materials such as pesticides, additives or contaminants in food, and personal care products. The high energy ionizing radiation has the ability to remove the EDCs with a very high degree of reliability and in a clean and efficient manner. The ionizing radiation interacts with EDCs both directly and indirectly. Direct interaction takes place with EDCs and the structure of EDCs is destroyed or changed. During indirect interaction, radiolysis products of water result in the formation of highly reactive intermediates which then react with the target molecules, culminating in structural changes. To confirm the radiation reduction of EDCs in industrial sludge, a pilot scale experiment up to 50 kGy of electron beam (EB) was conducted with samples from the textile dyeing industries. The experimental result showed the over 90% of reduction of Nonylphenol (NP) and Di(2-ethylhexyl) phthalate (DEHP) at around 10 kGy of absorbed doses.

Photoinitiator-free Photo-reactive Coloration of Wool Fabrics Using C.I. Reactive Black 5

  • Dong, Yuanyuan;Jang, Jin-Ho
    • 한국염색가공학회지
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    • 제24권2호
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    • pp.97-105
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    • 2012
  • Compared with conventional adsorption-based coloration, the photoreactions of dyes such as photo-copolymerization and photo-crosslinking under UV irradiation can be employed for the coloration of textiles, which can be carried out without salt addition at room temperature. C.I. Reactive Black 5, a homo-bifunctional reactive dye containing two sulfatoethylsulfone groups, is used as a photo-reactive dye for wool fibers. Upon UV irradiation, the photo-reactive dye was grafted onto wool fabrics without photoinitiators. Since the disulfide bonds in the cystine residues of wool can be easily photodecomposed to active thiyl radicals which initiate the polymerization, the dye can be polymerized to an oligomeric dye of a degree of polymerization of 12 or more. The grafted fabrics reached a grafting yield of 2.3% o.w.f. and a color yield (K/S) of 18.2 by the photografting of an aqueous dye concentration of 9% using a UV energy of 25J/$cm^2$. Furthermore, the photochemically dyed wool fabric showed higher colorfastness properties to light, laundering and rubbing comparable to conventional reactive dyeing.

캐티온화제 처리한 면섬유에 대한 반응성 염료의 염색성 (A Study on Dyeing Properties of Cafionicagent Treated Cotton Fibre with Reactive Dye)

  • Jung, Young Jin;Lee, Young Hee;Kim, Kyung Hwan
    • 한국염색가공학회지
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    • 제6권4호
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    • pp.46-53
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    • 1994
  • Polymer cationic agent was prepared by the initial polymerisation of epichlorohydrin followed by amination with diethylamine. Cotton fibre treated with the polymer (6~8% o.w.f.) is highly cationic and exhibit increased substantivity for reactive dyes under neutral to weakly acid conditions. The modified substrate could be dyed with reactive dyes without salt or a little salt from dye bath. The increased concentration of cationic agents resulted in an increase the colour yield. Futhermore, treated cotton has an electropositive surface charge. Adsorption of Reactive dye can be attributed to both van der waals force and electrostatic attraction.

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대두와 면 혼방직물의 염색에 따른 태의 비교 (Hand Value Assessment of Soybean/Cotton Blended Fabric after Natural and Synthetic Dyeing)

  • 송경헌;김정화;홍영기;구지영
    • 한국생활과학회지
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    • 제16권5호
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    • pp.979-986
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    • 2007
  • The purpose of this study is to investigate the dyeability, and the hand of soybean/cotton blended fabric after dyeing with natural and synthetic dyes. Soybean/cotton blended fabrics dyed with extracted solution from turmeric, sappan wood, gardenia and synthetic dyes(weak-acid dyes, reactive dyes, direct dyes). The hand value of soybean/cotton blended fabrics dyed with 6 different dyes was measured using Kawabata Evaluation System. The results are as follows; 1. The K/S value of the soybean/cotton blended fabric dyed with sappan wood extracts was the highest. 2. The color fastness of the soybean/cotton blended fabric dyed with reactive dyes was excellent. The fastness to the light of the same fabric was much better than the other fabrics. 3. Linearity of load-extension and tensile energy of the soybean/cotton blended fabric dyed with sappan wood extracts showed very high. Shear stiffness of the soybean/cotton blended fabric dyed with weak-acid dyes was much higher than that of fabric of dyed with reactive dyes. Bending property of the fabrics dyed with natural colorants(sappan wood, gardenia) showed very high, but that the fabric dyed with reactive dyes was very poor. 4. In the primary hand value, stiffness and anti-drape stiffness of the fabric dyed with weak-acid dyes showed the highest. Fullness and softness of the fabric dyed with weak-acid dyes showed very low.

s-Triazine계 반응성 염료에 관한 연구 (제3보). 2개의 발색단을 포함한 Monofluorotriazine 반응성 염료에 합성 (Studies on the s-Triazinyl Reactive Dyes (III). Synthesis of Dichromophoric Monofluorotriazinyl Reactive Dye)

  • 남계춘;김원태;박상우
    • 대한화학회지
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    • 제27권3호
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    • pp.218-223
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    • 1983
  • 새로운 반응성염료 개발의 일환으로 trifluoro-s-triazine을 반응성분으로 이용하여 한 분자에 2개의 서로 다른 chromophore를 가지는 반응성염료를 합성한 다음, 이의 가수분해속도와 면섬유에 대한 염색성을 조사하였다. 이 염료의 유사 일차 가수분해속도상수, $k_w$는 pH=10.0, 온도 $60{\circ}C$에서 k_w=2.6{\times}10^{-2}min^{-1}$로서 monochlorotriazine 반응성염료보다 높은 값을 보였으며 염착률과 고착율 역시 monochlorotriazine 계 염료보다 우수하였다. 얻어진 반응성 염료는 황색계열로서 수율은 75%였다.

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