• 제목/요약/키워드: Reactive blue 4

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Decolorization of synthetic dyes by Rhodopseudomonas palustris P4

  • Oh, You-Kwan;Kim, Yeon-Hee;Park, Sung-Hoon
    • 한국생물공학회:학술대회논문집
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    • 한국생물공학회 2003년도 생물공학의 동향(XII)
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    • pp.403-408
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    • 2003
  • A newly isolated Rhodopseudomonas palustris P4 could decolorize various synthetic dyes containing different chromogenic groups such as azo linkage (Crocein Orange G, New Coccine, Chromotrope FB, Congo Red, Remazol Black B), anthraquinone Reactive blue 2, or indigo Indigo Carmine. Among them, the degradation rate of Black B was studied in detial. Degradation of Black B followed the Arrhenius equation in 25 - $40^{\circ}C$ with an activation energy of 7.79 kcal/mol. Optimum pH was 8. Glucose in the range of 5 - 50g/l did not affect the Black B decolorization. When Black B increased from 25 mg/l to 2000 mg/l, decolorization activity increased almost linearly but the extent of decolorization was constant at about 86% irrespective of dye concentration. Analyses by HPLC revealed that the Black B molecules were partially degraded and some chromogenic intermediates were produced. These results indicate that Rps. palustris P4 has an outstanding capability to degrade various dyes.

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Characterization of Dye Decolorization in Cell-Free Culture Broth of Trametes versicolor CBR43

  • Ryu, Hyun;Ryu, Hee Wook;Cho, Kyung-Suk
    • Journal of Microbiology and Biotechnology
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    • 제27권1호
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    • pp.155-160
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    • 2017
  • The dye decolorization rate in a cell-free culture broth of the white-rot fungus Trametes versicolor CBR43 was studied, including the effects of inhibitors of NaCl, Zn(II), and Cd(II) on dye decolorization activity. The maximum rates of dye decolorization in cell-free culture broth were 1,410, 44.7, 41.2, and $0.19{\mu}mol{\cdot}l^{-1}{\cdot}min^{-1}$ for Acid Blue 62, Acid Black 175, Reactive Blue 4, and Acid Red 114, respectively. The inhibition effects of NaCl, Zn(II), and Cd(II) on dye decolorization were quantitatively compared using the half maximal inhibition concentration ($IC_{50}$), which indicates the concentration of an inhibitor required for 50% inhibition. Based on $IC_{50}$ values, dye decolorization in the cell-free culture broth of CBR43 was most potently inhibited by Cd(II), whereas the inhibitory effect of NaCl was relatively low. The dye decolorization rates and $IC_{50}$ data can be used in the design and development of a dye-wastewater treatment process using T. versicolor CBR43 and its operating factors.

Effects of Antioxidants Supplement in Porcine Sperm Freezing on in vitro Fertilization and the Glutathione and Reactive Oxygen Species Level of Presumptive Zygotes

  • Park, Sang-Hyoun;Jeon, Yubyoel;Yu, Il-Jeoung
    • 한국수정란이식학회지
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    • 제32권4호
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    • pp.337-342
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    • 2017
  • The present study was aimed to determine the effects of green tea extract (GTE) and beta-mercaptoethanol (${\beta}-ME$) supplementation in boar sperm freezing extender on in vitro fertilization (IVF) and reactive oxygen species (ROS) and glutathione (GSH) levels of presumptive zygotes (PZs). Experimental groups were allocated into lactose egg yolk (LEY) without antioxidant (control), GTE (1,000 mg/l in LEY) and ${\beta}-ME$ ($50{\mu}M$ in LEY). In freezing, spermatozoa extended with LEY were cooled to $5^{\circ}C$ for 3 h and then kept at $5^{\circ}C$ for 30 min following dilution with LEY containing 9% glycerol and 1.5% Equex STM. The final sperm concentration was $1{\times}10^8/ml$. Spermatozoa were loaded into straws and frozen in nitrogen vapor for 20 min. For IVF, oocytes were matured in NCSU-23 medium and co-cultured with spermatozoa following thawing at $37^{\circ}C$ for 25 sec. At 12 h following IVF, IVF parameters (sperm penetration and monospermy) were evaluated. In addition, GSH and ROS levels of PZs were determined by Cell Tracker Blue CMF2HC and DCHFDA, respectively. IVF parameters did not show any significant difference among the experimental groups. GSH and ROS levels of PZs were not significantly different between groups. In conclusion, antioxidant supplementation in boar sperm freezing could not influence IVF parameters, ROS and GSH levels of PZs.

Enhanced Visible Light Activity and Stability of TiO2 Nanopowder by co-doped with Mo and N

  • Hu, Shaozheng;Li, Fayun;Fan, Zhiping
    • Bulletin of the Korean Chemical Society
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    • 제33권4호
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    • pp.1269-1274
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    • 2012
  • A visible light responsive N, Mo co-doped $TiO_2$ were prepared by sol-gel method. X-ray diffraction, TEM, $N_2$ adsorption, UV-vis spectroscopy, photoluminescence, and X-ray photoelectron spectroscopy were used to characterize the prepared $TiO_2$ samples. Doping restrained the phase transformation from anatase to rutile and reduced the particle sizes. The band gap was much narrowed after N, Mo co-doping. The photocatalytic activities were tested in the degradation of an aqueous solution of a reactive dyestuff, methylene blue, under visible light. The photocatalytic activities of doped $TiO_2$ were much higher than that of neat $TiO_2$. The photocatalytic stability of N, Mo co-doped $TiO_2$ was much better than that of N doped $TiO_2$.

Rayon과 Tencel 섬유의 염색 견뢰도 고찰 (The Study On the dye fastness of the Rayon & Tencel Fiber)

  • 안찬희
    • 대한가정학회지
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    • 제34권5호
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    • pp.283-292
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    • 1996
  • This study examines the character of "Tencel" named as Ecology Fiber and investigates the fitness of it as the textile and the satisfaction in dress when its fastness is compared with that of Rayon classified into Celulose textile. Dye experiment selected 100% Tencel, Rayon for the samples, which were dyed into the direct dye and Turky Blue and Blue of the rective dye and were washed twelve times by the automatic washer. After that, the dye experiment examines the light, laundering, perspiration, rubbing and the composite fastness of the perspiration and hight in the lists of the dye fastness. The results are as follows: 1. The experiment of the color fastness, especially in T-blue of the direct dyestuff, requiring the twelve times-repeatedly-washing by the detergent says that the color fastness of Tencel is superior to that of the cellulose textile ; Rayon. 2. The experiment of the light fastness says that the fastness of Tencel is superior to that of Rayon. 3. The experiment of the laundering fastness says that all of Tencel, Rayon shows the excellent result in the direct dye than in the reactive dye. 4. The experiment of the rubbing fastness says that although Tencel, Rayon show the remarkable result in the desiccant experiment than in the humid one, the rubbing fastness of Tencel is superior to that of others. 5. The experiment of perspiration fastness says that Tencel, Rayon have the closely tightened tendency not to be altered through the acid and alkali perspirations. 6. The experiment of the composite fastness of perspiration and light indicates that the artifical perspirations, though the light lets the fastness of textiles weeken, do very slightly make them loosen, which does not offer the outstanding result. This whole result show that the fastness of Tencel is superior to that of Rayon. The Korean Fiber Enterprise in clothing should make the new and ecological fiber "Tencel" by means of the large amount of investment, and the technique of handing and controlling about it, considering that the dangerous needle of environmental pollution has been slackening the close-related ecological knots of the global environment. global environment.

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폐MDF를 이용한 염색재생섬유 제조 (Manufacture of Dyed Recycling Wood Fiber Using Waste MDF)

  • 주선경;노정관
    • Journal of the Korean Wood Science and Technology
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    • 제45권3호
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    • pp.297-307
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    • 2017
  • 폐MDF 재생섬유를 인테리어 소품 제조용 원료로 이용하기 위해 MDF 제조용 리기다소나무 버진섬유와 MDF를 제조한 후 재해섬한 재생섬유에 대해 빨강, 노랑 및 파랑색 계열의 Bis-monochlorotriazine (MCT)계와 Vinyl sulfone(VS)계의 반응성염료, Anthraquinone계의 배트염료, Diazo계열의 직접염료 및 치자와 소목의 천연염료에 의한 염색 특성 및 일광견뢰도를 검토하였다. 염색 전의 버진섬유와 재생섬유의 색상은 각각 4.2YR과 4.4YR로 약간의 적색기가 있는 황색을 나타내고 있었으며, 재생섬유가 버진섬유에 비해 $L^*$의 값이 작아 약간 더 어두웠다. 적, 청, 황색계의 MCT계와 VS계의 반응성염료, 배트 염료, 직접염료 모두 버진섬유와 재생섬유에 관계없이 염색은 매우 양호하게 잘 이루어졌다. 재생섬유가 버진섬유보다 염착량은 약간 높았고, $L^*$와 V의 값은 약간 감소하였으나, 큰 차이는 없었다. 일광견뢰도는 염료에 따라 약간의 차이는 있으나 버진염색섬유가 재생염색섬유보다 더 큰 색차를 보이고 있어 불량하였다. 소목으로 염색한 재생섬유와 버진섬유의 색상은 각각 4.4YR과 4.0YR로 염색 전의 미염색 섬유와 거의 차이가 없었으나, 치자로 염색한 섬유의 색상은 각각 7.4YR과 6.9YR로 황색계의 반응성염료, 배트염료 및 직접염료보다 큰 색차를 보여 염색성은 우수하였으나 일광견뢰도는 불량하였다.

Effects of Nitric Oxide Modulating Drugs on Acrosome Reaction in Mouse Spermatozoa

  • Gye, Myung Chan
    • Animal cells and systems
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    • 제4권2호
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    • pp.151-155
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    • 2000
  • Nitric oxide (NO) is a reactive free radical which plays important roles in animal physiology. To investigate involvement of NO in acrosome reaction (AR), effects of drugs which modulate the intracellular NO level were examined in mouse spermatozoa. N (G)-nitro-L-arginine (L-NA), a potent inhibitor of NO synthesis, decreased AR in a reversible manner, On the other hand, sodium nitroprusside (SNP), an NO generating agent, increased spontaneous AR. Preincubation of sperm in the presence of L-NA potentiated AR after sperm transfer into plain- or SNP-media. Methylene blue, a NO scavenging agent, decreased spontaneous AR. Taken together, it is concluded that NO positively controls AR.

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Enhanced Cathodoluminescence of KOH-treated InGaN/GaN LEDs with Deep Nano-Hole Arrays

  • Doan, Manh-Ha;Lee, Jaejin
    • Journal of the Optical Society of Korea
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    • 제18권3호
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    • pp.283-287
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    • 2014
  • Square lattice nano-hole arrays with diameters and periodicities of 200 and 500 nm, respectively, are fabricated on InGaN/GaN blue light emitting diodes (LEDs) using electron-beam lithography and inductively coupled plasma reactive ion etching processes. Cathodoluminescence (CL) investigations show that light emission intensity from the LEDs with the nano-hole arrays is enhanced compared to that from the planar sample. The CL intensity enhancement factor decreases when the nano-holes penetrate into the multiple quantum wells (MQWs) due to the plasma-induced damage and the residues. Wet chemical treatment using KOH solution is found to be an effective method for light extraction from the nano-patterned LEDs, especially, when the nano-holes penetrate into the MQWs. About 4-fold CL intensity enhancement factor is achieved by the KOH treatments after the dry etching for the sample with a 250-nm deep nano-hole array.

Performance evaluation of submerged membrane bioreactor for model textile wastewater treatment

  • Guembri, Marwa;Saidi, Neila;Neifar, Mohamed;Jaouani, Atef;Heran, Marc;Ouzari, Hadda-Imene
    • Membrane and Water Treatment
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    • 제11권2호
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    • pp.123-130
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    • 2020
  • Submerged Membrane bioreactor (SMBR) is one of the last techniques that allow a high quality of treated industrial effluents by coupling biological treatment and membrane separation. Thus, this research was an effort to evaluate performance of a SMBR treating a model textile wastewater (MTWW). Different SMBR operating parameters like mixed liquor suspended solids (MLSS) and Dissolved oxygen concentration, hydraulic retention time (HRT), and nutrients addition (N and P) have been investigated. MTWW (influent to the SMBR) was generated using the reactive azo-dye, Novacron blue FNG (100mg/L feed concentration). Results of MTWW treatment using SMBR under optimal operating conditions (MLSS, 4.2-13.3g/L; HRT, 4 days; pH, 6.9-7.2; conductivity, 400-900 μS/cm and temperature, 19.4-22.2 ℃) showed that COD and blue colour treatment performances are between 94-98% and 30-80%, respectively. It is concluded that SMBR can be used in large scale textile wastewater treatment plants to improve effluent quality in order to meet effluent discharge standards.

Dyeing of Cotton and Polyester/Cotton Blend with Disperse Dyes Using Sodium 2-(2,3-dibromopropionylamino)-5-(4,6-dichloro-1,3,5-triazinylamino)-benzenesulfonate

  • Kim, Mi-Kyung;Yoon, Seok-Han;Kim, Tae-Kyeong;Bae, Jin-Seok;Yoon, Nam-Sik
    • Fibers and Polymers
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    • 제7권4호
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    • pp.352-357
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    • 2006
  • The cotton fabrics were pretreated by sodium 2-(2,3-dibromopropionylamino)-5-(4,6-dichloro-1,3,5-triazinylamino) benzenesulfonate (DBDCBS) at alkaline condition ofroom temperature and then dyed with four disperse dyes having amino groups (C.I. Disperse Yellow 9, C.I. Disperse Red 11, C.I. Disperse Blue 56 and C.I. Disperse Violet 1) at acidic condition of high temperature. A novel hetero-bifunctional bridge compound, DBDCBS, has two reactive groups such as dichloro-striazinyl group and ${\alpha},\;{\beta}$-dibromopropionylamido group. The first has reactivity towards hydroxy group of cellulosic fiber and the second shows reactivity towards amino groups of disperse dye containing amino groups. The results indicate that it is possible to dye polyester/cotton blend at one-bath dyeing using one kind of disperse dye containing amino groups. Therefore, two kinds of dyeing methods such as two-bath process one-bath dyeing and one-bath process one-bath dyeing were investigated and their dyeabilities were compared. The differences between these two methods were negligibly small so that perfect one-bath one-step dyeing of polyester/cotton blend by one kind of disperse dye was achieved.