• 제목/요약/키워드: Reactive Material

검색결과 705건 처리시간 0.029초

InP 광도파로의 식각 특성 (Fabrication and Characteristics of InP-Waveguide)

  • 박순룡;김진우;오범환;우덕하;김선호
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2000년도 하계학술대회 논문집
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    • pp.824-827
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    • 2000
  • Fabrication of InP-based photonic devices by dry etch Process is important for clear formation of waveguide mesa structure. We have developed more efficient etch process of the inductively coupled plasma (ICP) with low damages and less polymeric deposits for the InP-based photonic devices than the reactive ion etching (RIE) technique. We report the tendency of etch rate variation by the process parameters of the RF power, pressure, gas flow rate, and the gas mixing ratio. The surface roughness of InP-based waveguide structure was more improved by the light wet etching in the mixed solution of H$_2$SO$_4$:H$_2$O (1:1)

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Asymmetric Ring Opening of Epoxides Catalyzed by Novel Heterobimetallic Schiff-Bases Containing Transition Metal Salts

  • Kawthekar, RahulB;Bi, Wentao;Kim, Geon-Joong
    • Bulletin of the Korean Chemical Society
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    • 제29권2호
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    • pp.313-318
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    • 2008
  • An enantioselective ring opening of racemic terminal epoxides has been achieved by using heterobimetallic cobalt salen complexes with variety of nucleophiles. They were proven to be highly enantioselective and reactive for the synthesis of valuable chiral building blocks in enantio-riched forms up to 98% ee.

DC reactive sputtering 증착법을 이용한 초전도테이프의 $Y_2O_3$ 단일완충층 증착 ($Y_2O_3$ single buffer layer deposition using DC reactive sputtering for the superconducting coated conductor)

  • 김호섭;고락길;오상수;김태형;송규정;하홍수;양주생;박유미
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2005년도 하계학술대회 논문집 Vol.6
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    • pp.52-53
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    • 2005
  • $Y_2O_3$ film was directly deposited on Ni-3at%W substrate using DC reactive sputtering technique. Metallic yttrium was used for DC sputtering target and water vapor was used for oxidizing the deposited metallic Yttrium atoms on the substrate. The window of the water vapor turned out to be broad. The minimum partial pressure of water vapor was determined by sufficient oxidation of the $Y_2O_3$ film, and the maximum partial pressure of water vapor was determined by the non-oxidation of the target surface. As the sputtering power was increased, The deposition rate increased without narrowing the window. The fabricated $Y_2O_3$ films showed good texture qualities and surface morphologies. The YBCO film deposited directly on the $Y_2O_3$ buffered Ni-3at%W substrate showed $T_c$, $I_c$ (77 K, self field), and $J_c$ (77 K, self field) of 89 K, 64 A/cm and 1.l $MA/cm^2$, respectively.

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Generation of a Human Monoclonal Antibody to Cross-Reactive Material 197 (CRM197) and Development of a Sandwich ELISA for CRM197 Conjugate Vaccines

  • Kim, Dain;Yoon, Hyeseon;Kim, Sangkyu;Wi, Jimin;Chae, Heesu;Jo, Gyunghee;Yoon, Jun-Yeol;Kim, Heeyoun;Lee, Chankyu;Kim, Se-Ho;Hong, Hyo Jeong
    • Journal of Microbiology and Biotechnology
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    • 제28권12호
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    • pp.2113-2120
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    • 2018
  • Cross-reactive material 197 ($CRM_{197}$) is a non-toxic mutant of diphtheria toxin containing a single amino acid substitution of glycine 52 with glutamic acid. $CRM_{197}$ has been used as a carrier protein for poorly immunogenic polysaccharide antigens to improve immune responses. In this study, to develop a sandwich ELISA that can detect $CRM_{197}$ and $CRM_{197}$ conjugate vaccines, we generated a human anti-$CRM_{197}$ monoclonal antibody (mAb) 3F9 using a phage-displayed human synthetic Fab library and produced mouse anti-$CRM_{197}$ polyclonal antibody. The affinity ($K_D$) of 3F9 for $CRM_{197}$ was 3.55 nM, based on Bio-Layer interferometry, and it bound specifically to the B fragment of $CRM_{197}$. The sandwich ELISA was carried out using 3F9 as a capture antibody and the mouse polyclonal antibody as a detection antibody. The detection limit of the sandwich ELISA was <1 ng/ml $CRM_{197}$. In addition, the 3F9 antibody bound to the $CRM_{197}$-polysaccharide conjugates tested in a dose-dependent manner. This ELISA system will be useful for the quantification and characterization of $CRM_{197}$ and $CRM_{197}$ conjugate vaccines. To our knowledge, this study is the first to generate a human monoclonal antibody against $CRM_{197}$ and to develop a sandwich ELISA for $CRM_{197}$ conjugate vaccines.

Oxidative stress on anaerobes

  • Takeuchi, Toru;Shi, Minyi;Kato, Naoki;Watanabe, Kunitomo;Morimoto, Kanehisa
    • Journal of Photoscience
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    • 제9권2호
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    • pp.142-145
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    • 2002
  • A strict anaerobe, Prevotella melaninogenica is highly sensitive to oxidative stress. Oxidative stress such as exposure to oxygen or addition of hydrogen peroxide, increased 8-hydroxydeoxyguanosine (80HdG), a typical of oxidative DNA damage, and decreased the bacterial cell survival rate. We could detect the generation of reactive oxygen species in P. melaninogenica after exposure to oxygen. UVA irradiation also increased 80HdG in the bacterium. On the other hand, such oxidative stress did not increase 80HdG in a facultative anaerobe. These findings suggest that P. melaninogenica is a suitable material to study the biological effects of oxidative stress, to evaluate antioxidants, and to study the effects of oxygen or reactive oxygen species on molecular evolution.

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TCE제거를 위한 반응층과 고정화층의 결합 실험

  • 조현희;박재우
    • 한국지하수토양환경학회:학술대회논문집
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    • 한국지하수토양환경학회 2002년도 추계학술발표회
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    • pp.67-70
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    • 2002
  • Remediation of groundwater contaminated with chlorinated organics, nitro aromatics, and heavy metals using zero valent iron (ZVI) filings has paid considerable attention in recent years. When the contaminants of high concentration leaked abundantly in subsurface environment, permeable reactive barrier technology using iron filing is taken a long time for the remediation of contaminated groundwater, The problem of contaminant shock is able to be solved using surfactant (hexadecyltrimethylammonium, HDTMA) modified bentonite (SMB) as immobilizing material. Therefore, the purpose of this research was to develop the combined remediation technology using conventional permeable reactive and immobilizing barrier for the enhanced decontamination of chlorinated compounds. Four column experiments were conducted to assess the performance of the mixed reactive materials with Ottawa sand, iron filing, and HDTMA-bentonite for trichloroethylene (TCE) removal under controlled groundwater flow conditions. TCE reduction rates with sand/iron filing/HDTMA-bentonite were highest among four column due to dechlorination of TCE by iron filing and sorption of TCE by SMB.

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콘크리트 시험체 시험법을 통한 고강도 콘크리트의 알칼리골재 반응성 (The Possibility of Alkali-Aggregate Reaction of High Strength Concrete by Concrete Bar Test)

  • 권영진;김무한
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 1996년도 봄 학술발표회 논문집
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    • pp.137-140
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    • 1996
  • The deterioration of concrete due to alkali-aggregate reaction is dependent on the total alkali content per unit volume of concrete. It was reported that the expansion of high alkali concrete with the reactive aggregate increased easily due to high alkali of concrete with the reactive aggregate increased easily. And it has been confirmed that the addition of pozzolanic material prevents the concrete with reactive aggregate from deterioration caused by alkali-aggregate reaction. It is the aim of this study to provide the fundamental data on the possibility of alkali-aggregate reaction of high strength concrete and its preventing and repair technic.

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TCO Workfunction Engineering with Oxygen Reactive Sputtering Method for Silicon Heterojunction Sola Cell Application

  • 봉성재;김선보;안시현;박형식;이준신
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2014년도 제46회 동계 정기학술대회 초록집
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    • pp.492-492
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    • 2014
  • On account of the good conductivity and optical properties, TCO is generally used in silicon heterojunction solar cell since the emitter material, hydrogenated amorphous silicon (a-Si:H), of the solar cell has low conductivity compare to the emitter of crystalline silicon solar cell. However, the work function mismatch between TCO layer and emitter leads to band-offset and interfere the injection of photo-generated carriers. In this study, work function engineering of TCO by oxygen reactive sputtering method was carried out to identify the trend of band-offset change. The open circuit voltage and short circuit current are noticeably changed by work function that effected from variation of oxygen ratio.

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Strength and Microstructure of Reactive Powder Concrete Using Ternary Pozzolanic Materials

  • So, Hyoung-Seok;Janchivdorj, Khulgadai;Yi, Je-Bang;Jang, Hong-Seok;So, Seung-Young
    • 한국건축시공학회지
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    • 제13권1호
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    • pp.48-57
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    • 2013
  • To consider the practicality and economic feasibility of developing reactive powder concrete (RPC), the strength and microstructure properties of RPC using ternary pozzolanic materials (silica fume, blast furnace slag, fly ash) were investigated in this study. Through the investigation, it was found that the compressive strength of RPC using ternary pozzolanic materials was increased significantly compared to that of the original RPC containing silica fume only. A considerable improvement in the flexural strength of RPC using ternary pozzolanic materials was found, and then the utilization of a structural member subjected to bending was expected. The X-ray diffractometer (XRD) analysis and Scanning Electronic Microscope (SEM) revealed that the microstructure of RPC was denser using the ternary pozzolanic materials than the original RPC.

Various Pattern-Forming States of Nematic Liquid Crystal Based on the Sign Inversion of Dielectric Anisotropy

  • Kang, Shin-Woong;Chien, Liang-Chy
    • Macromolecular Research
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    • 제15권5호
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    • pp.396-402
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    • 2007
  • The dielectric properties and various pattern-forming states of dual-frequency material in a nematic phase, as well as its mixture containing low concentrations of reactive monomers, are reported. The dielectric relaxation behaviors of nematic MLC 2048 are presented and compared to its mixture containing both mesogenic and nonmesogenic reactive monomers. The sign-inversion frequency of the dielectric anisotropy was significantly shifted on the addition of small amounts of the reactive monomers. However, all three mixtures used in this study essentially exhibited the same field-induced instabilities at different frequencies and voltage domains of the applied electric field. A broad band of modulated states were found to exist above a critical voltage and within a voltage dependent frequency band in the vicinity of the sign-inversion frequency, $f_I$, of the dielectric anisotropy. As the $f_I$ of the mixtures shifted, so did the bands of the modulated state of the different mixtures and the temperatures, which were well matched with the measured $f_I$ value.