• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2017.05a
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• pp.251-253
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• 2017

Numerical study of air-blast type injector for low emission aircraft engines was conducted. Volume-of-fluids approach was used to track interface of fuel and air. Primary atomization of fuel stream was visualized, and thickness and mean velocity at the injector exit was calculated. Liquid fuel injected from fuel slots joined together as a thin film on preflimer surface, and interacted with swirling air. As instability on the fuel surface increased, separation of fuel as ligaments and droplets occured. The film thickness and velocity were used to as fuel injection boundary condition for reactive flow simulation. Primary reaction zone was formed in vicinity of the fuel nozzle, creating a stable flame inside the combustor.

• Transactions of the Korean hydrogen and new energy society
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• v.27 no.2
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• pp.220-229
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• 2016

A numerical study on lifted flame structure in impinging jet geometry with syngas composition ratio was investigated. The numerical calculations including chemical kinetic analysis were conducted using SPIN application of the CHEMKIN Package with Davis-Mechanism. The flame temperature and velocity profiles were calculated at the steady state for one-dimensional stagnation flow geometry. Syngas mixture compositions were adjusted such as $H_2:CO=10:90(10P)$, 20 : 80 (20P), 30 : 70 (30P), 40 : 60 (40P), 50 : 50 (50P). As composition ratios are changed from 10P to 50P, the axial velocity and flame temperature increase because the contents of hydrogen that have faster burning velocity increase. This phenomenon is due to increase in good reactive radicals such as H, OH radical. As a result of active reactivity, the burning velocity is more faster and this is confirmed by numerical methods. Consequently, combustion reaction zone was moved to burner nozzle.

• Journal of Korean Society of Occupational and Environmental Hygiene
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• v.22 no.3
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• pp.209-216
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• 2012

Objectives: Polyurethanes are usually formed by the reactions of liquid diisocyanate components with liquid polyol resin components. Although polyurethanes have advantageous properties, such as their versatility, the manufacturing process generates diisocyanates, which can cause asthma and respiratory irritation in exposed workers. This study compared the differences in diisocyante concentrations between two different (molded foam and slabstock foam) polyurethane foam manufacturing methods. Materials and Methods: Active samples and direct reading samples of diisocyanates (MDI, TDI) were collected in five polyurethane foam manufacturing companies. Results: Workers' exposure concentrations of diisocyanate (GM: 4.078 ppb, range: 1.190~23.770 ppb) in a slabstock foam manufacturing company were much higher than those (GM: 0.011 ppb, range: 0.001~0.055 ppb) in molded foam manufacturing companies. The results of the direct reading samples of diisocyanate indicated that the rapid reaction zone of the slabstock foam processes emitted large amounts of diisocyanates. Conclusions: The exposure levels of diisocyanates for all molded foam workers were much lower than the occupational exposure standard (5 ppb); however, exposure levels for many slabstock foam workers exceeded the standard.

• Journal of the Korean Society of Propulsion Engineers
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• v.22 no.1
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• pp.72-79
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• 2018

An experimental study was performed to investigate the chemiluminescence characteristics in the spray combustion of ultransonically atomized kerosene. The radical intensity of the spray flame was measured using an ICCD camera and the amount of fuel consumed was obtained by a precise flow-rate measurement technique during combustion. Fuel consumption increased linearly with the increase in carrier-gas flow rate, and typical group combustion, which is a characteristic of spray combustion, was observed. It was found from the analysis of chemiluminescence that the maximum emission intensities of OH and CH radicals decrease, and they move downstream resulting in the increase in a vivid reaction zone as the spray flow rate increases.

• International Journal of Railway
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• v.7 no.3
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• pp.85-89
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• 2014

The use of pozzolanic materials in concrete mixtures can enhance the mechanical properties and durability of concrete. By reactions with pozzolanic materials and calcium hydroxide in cement matrix, calcium-silicate-hydrate (C-S-H) increases and calcium hydroxide decreases in cement matrix of concrete. Consequently, the volume of solid materials increases. The pozzolanic particles also fill spaces between clinker grains, thereby resulting in a denser cement matrix and interfacial transition zone between cement matrix and aggregates; this lowers the permeability and increases the compressive strength of concrete. Moreover, the total contents of alkali in concrete are reduced by replacing cements with pozzolanic materials; this prevents cracks due to alkali-aggregate reaction (AAR). In this study, nanosilica is incorporated in cement pastes. The differences of microstructural compositions between the hydrated cements with and without nanosilica are examined using nanoindentation, XRDA and $^{29}Si$ MAS NMR. The results can be used for a basic research to enhance durability of concrete slab tracks and concrete railway sleepers.

• Korean Journal of Plant Resources
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• v.31 no.4
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• pp.342-354
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• 2018

Suaeda japonica is a halophytic plant that lives in mudflat at intertidal zone of western and southern coastal areas of Korea. The seawater-living plants showed a purple color during their whole life. In contrast, freshwater-living plants displayed a green color in leaves. When seawater-living plants were transferred to potting soil, the purple color was gradually changed to green in the leaves. The extracted purple pigment compound exhibited typical characteristics of betacyanin that were represented by water solubility, pH- and temperature-dependent color changes, sensitivity to light, UV-Vis spectra, and gel electrophoretic migration pattern. The LC-MS analysis of the extracted pigment compound showed the presence of two major protonated molecular ions ($[M+H]^+$) at m/z 651.1 and m/z 827.1. Antioxidant activity of the pigment compound was determined using stable free radical DPPH assay. It was found to have an antioxidant activity that is linearly increased in proportion to the reaction time for up to 30 min, and the activity was comparable to that of control BHA at 9.0 mg/ml. The anticancer activity against several tumor cell lines was also examined following the MTT assay. The significant growth inhibitory effect was observed on two tumor cell lines, SW-156 (human kidney carcinoma) and HEC-1B (human endometrial adenocarcinoma). Probably, the pigment compound may function as an osmolyte to uphold halotolerant physiological processes in saline environment.

• Computers and Concrete
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• v.23 no.1
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• pp.69-80
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• 2019

Modeling approach for mesoscopic model of concrete depicting mass transportation and physicochemical reaction is important since there is growing demand for accuracy and computational efficiency of numerical simulation. Mesoscopic numerical simulation considering binder, aggregate and Interfacial Transition Zone (ITZ) generally produces huge number of DOFs, which is inapplicable for full structure. In this paper, a three-dimensional multiscale approach describing three-phase structure of concrete was discussed numerically. An effective approach generating random aggregate in polygon based on checking centroid distance was introduced. Moreover, ITZ elements were built by parallel expanding the surface of aggregates on inner side. By combining mesoscopic model including full-graded aggregate and macroscopic model, cases related to diffusivity and thickness of ITZ, volume fraction and grade of aggregate were studied regarding the consideration of multiscale compensation. Results clearly showed that larger analysis model in multiscale model expanded the diffusion space of chloride ion and decreased chloride content in front of rebar. Finally, this paper addressed some worth-noting conclusions about the chloride distribution and rebar corrosion regarding the configuration of, rebar diameter, concrete cover and exposure period.

• Journal of the Korean Society of Propulsion Engineers
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• v.24 no.6
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• pp.53-60
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• 2020

In liquid-fuel spray combustion, an experimental study was conducted to observe the effect of ultrasonic excitation on the ultrasonically-atomized liquid fuel flame by controlling pressure field through an ultrasonic standing wave. Flame of the ultrasonically-atomized kerosene aerosol was visualized by using a high speed camera, DSLR, and Schlieren photography. The amount of fuel consumed was obtained by a precise flow-rate measurement technique during combustion, through which the ratio of carrier gas (air) to fuel mass was able to be obtained, too. As a result, it could be found that the combustion reaction-rate of the liquid-fuel aerosol was increased by applying an ultrasonic standing wave to the secondary flame zone of the flame.

• Journal of the Korean Society of Propulsion Engineers
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• v.26 no.1
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• pp.60-67
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• 2022

A study was conducted to analyze the behavioral change of the kerosene flame ultrasonically-atomized under an ultrasonic standing-wave. Combustion region was visualized through DSLR, ICCD camera and the Schlieren photography with high-speed camera. The fuel consumption was measured by a precise scale. As a result, in the case of ultrasonic standing-wave excitation, it was observed that the intensity of OH radical(OH^*) was enhanced and optimal combustion condition was formed around the upper edge of the standing-wave field.

• Economic and Environmental Geology
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• v.55 no.1
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• pp.97-109
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• 2022

This study focused on the physicochemical effects of bottom ash dissolved precipitation on the soil and groundwater environment. The iced column and percolation experiments showed that most of the bottom ash particles were drained as the ash-dissolved solution, while the charcoal powder was filtered through the soil. Ion species of Al, As, Cu, Cd, Cr, Pb, Fe, Mn, Ca, K, Si, F, NO₃, SO₄ were analyzed from the eluates collected during the 24 h column test. In the charcoal powder eluates, a high concentration of K was detected at the beginning of the reaction, but it decreased with time. The concentrations of Al and Ca were observed to increase with time, although they existed in trace amount. In the bottom ash eluates, the concentrations of Ca and SO₄ decreased by 30 mg·L^-1 and 67 mg·L^-1, respectively, over 24 h. It is regarded that the infiltration patterns of the bottom ash and biochar in the unsaturated zone were different owing to their particle sizes and solvent properties. It is expected that a significant amount of the bottom ash will mix with the precipitation and percolate below the water table, especially in the case of thin and highly permeable unsaturated zone. The biochar was filtered through the unsaturated zone. The biochar did not dissolve in the groundwater, although it reached the saturation zone. For these reasons, it is considered that the direct contamination by the bottom ash and biochar are unlikely to occur.