• Title/Summary/Keyword: Reaction zone

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A Study on the Smoldering Zone Spread of the Heaped Saw-Dust (퇴적 목분의 훈소층 전파에 관한 연구)

  • 정국삼;강민호
    • Journal of the Korean Society of Safety
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    • v.12 no.3
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    • pp.90-96
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    • 1997
  • This paper was concerned with temperature aspect in the smoldering time of the accumulated each saw-dust sample of larch, oregon, aromatic trees which was formed with heaped cone-shape. The smoldering time and temperature of each sample was measured under the wind velocity of 0.10~0.15 m/s and circumstance relative humidity of 60%. As a result, the very lowest heat beginning temperature was detected in aromatic. The effective smoldering phenomena in the sample were detected when the larch saw-dust of [-20+40mesh] and the aromatic saw-dust of [-40+50mesh, -50+60mesh]. Finally the larger a particle size of saw-dust was the better a smoldering time was short. Also, it showed more increasing temperature above $70^{\circ}C$in the smoldering reaction.

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Analysis of Group Ignition of Pulverized Coal Particles (미분탄의 집단점화 해석)

  • Suh, K.K.;Kim, H.Y.
    • Journal of the Korean Society of Combustion
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    • v.4 no.2
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    • pp.1-10
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    • 1999
  • Pulverized coal is widely used as the source of electrical power generation and industrial processes. Numerical analysis on the transient ignition process of the cloud of pulverized coal particles in various cases is carried out. Particle radius, initial particle temperature, number density are chosen as major parameters that influence the characteristics of ignition and combustion. The result can be summarized as follow. The ignition occurs at the position that is closed to the surface of the cloud. Maximum temperature and velocity appear at ignition point, and the concentrations of gaseous fuel and oxidizer decrease rapidly near the ignition point. The chemical reaction takes place in wider zone as number density and particle radius decrease. The ignition delay is shortest when particle radius is about $50\;{\mu}m$, and tends to be shorter as number density and initial ambient temperature increase.

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Synthesis and Characteristics of W-l5wt%Cu Nanocomposite Powder by Oxide Reduction (산화물환원에 의한 W-15wt%Cu 나노복합분말의 합성과 특성)

  • 윤의식
    • Journal of Powder Materials
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    • v.4 no.4
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    • pp.304-309
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    • 1997
  • The synthesis of W-l5wt%Cu nanocomposite powder by hydrogen reduction of ball milled W-Cu oxide mixture was investigated in terms of powder characteristics such as particle size, mixing homogeneity and micropore structure. It is found that the micropores in the ball milled oxide (2-50 nm in size) act as an effective removal path of water vapor, followed by the formation of dry atmosphere at reaction zone. Such thermodynamic condition enhances the nucleation of W phase but suppresses the growth process, being in favor of the formation of W nanoparticles (about 21 nm in size). In addition, the superior mixing homogeneity of starting oxide mixture turned out to Play a significant role for forming extraordinary chemical homogeneity of W-l5wt%Cu nanocomposite powder.

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Oxidation of Methane via Microwave Plasmas (마이크로웨이브 플라즈마를 통한 메탄의 산화반응)

  • Ahn, Beom-Shu
    • Journal of the Korean Applied Science and Technology
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    • v.17 no.2
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    • pp.89-93
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    • 2000
  • The oxidation of methane was carried out in six different configurations of plasma reactors in order to study the radical reactions inside and outside of the plasma zone and to explore the method to control them. Various radicals and reactive molecules, such as CH, $CH_{2}$, $CH_{3}$, H, and O(from $O_{2}$) were generated in the plasma. A variety of products were produced through many competing reaction pathways. Among them. partial oxidation products were usually not favored, because the intermediates leading to the partial oxidation products could be oxidized further to carbon dioxides easily. It is important to control the free radical reactions in the plasma reactor by controlling the experimental conditions so that the reactions leading to the desired products are the major pathways.

Liftoff mechanisms in hydrogen turbulent non-premixed jet flames (수소 난류확산화염에서의 부상 메커니즘에 대한 연구)

  • Oh, Jeong-Seog;Kim, Mun-ki;Choi, Yeong-Il;Yoon, Young-Bin
    • 한국연소학회:학술대회논문집
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    • 2007.05a
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    • pp.7-12
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    • 2007
  • To reveal the newly found liftoff height behavior of hydrogen jet, we have experimentally studied the stabilization mechanism of turbulent, lifted jet flames in a non-premixed condition. The objectives of the present research are to report the phenomenon of a liftoff height decreasing as increasing fuel velocity, to analyse the flame structure and behavior of the lifted jet, and to explain the mechanisms of flame stability in hydrogen turbulent non-premixed jet flames. The velocity of hydrogen was varied from 100 to 300m/s and a coaxial air velocity was fixed at 16m/s with a coflow air less than 0.1m/s. For the simultaneous measurement of velocity field and reaction zone. PIV and OH PLIF technique was used with two Nd:Yag lasers and CCD cameras. As results, it has been found that the stabilization of lifted hydrogen diffusion flames is related with a turbulent intensity, which means that combustion occurs where the local flow velocity is valanced with the turbulent flame propagation velocity.

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Formation of TiC Composite Layer on Ductile Iron by Laser Surface Modification (레이저 처리에 의한 구상흑연주철의 TiC 복합화에 관한 연구)

  • Kim, Woo-Yeol;Park, Heung-Il
    • Journal of Korea Foundry Society
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    • v.18 no.6
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    • pp.593-603
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    • 1998
  • Commercial ductile iron was coated with titanium and aluminum powders by low pressure plasma spraying and then irradiated with a $CO_2$ laser to produce anti-corrosive TiC composite layer. TiC carbides were precipitated homogeneously in a laser alloyed layer by in-situ reaction between carbon existed in the base metal and titanium with thermal sprayed coating. The formation of gas pores and brittle limited mixing zone with ledeburite microstructure in TiC composite layer were surpressed by the complementary alloying of aluminum. The hardness of TiC composite layer obtained by addition of titanium and aluminum was between 600 and 660 Hv, which was three times as high as the hardness of ferritic ductile iron. From the results of isothermal oxidation at 1123k for 24 hours in air, high temperature oxidation resistance of the TiC composite layer with aluminum was improved and doubled when compared with the TiC composite layer without aluminum.

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Modification of Hydroxyapatite/gelatin Nanocomposite with the Addition of Chondroitin Sulfate

  • Chang, Myung-Chul
    • Journal of the Korean Ceramic Society
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    • v.45 no.10
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    • pp.573-578
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    • 2008
  • In the preparation of hydroxyapatite(HAp)/gelatin(GEL) nanocomposite, GEL matrix was modified by the introduction of chondroitin sulfate(ChS) to obtain a strongly organized composite body. The formation reaction of the HAp/GEL-ChS nanocomposite was then investigated via XRD, DT/TGA, FT-IR, TEM and SEM. The organic-inorganic interaction between HAp nanocrystallites and GEL molecules was confirmed from DT/TGA and FT-IR. According to the DT/TGA results, the exothermal temperature zone between 300 and $550^{\circ}C$ showed an additional peak temperature that indicated the decomposition of the combined organics of the GEL and ChS. From the FT-IR analysis, calcium phosphate(Ca-P) was covalently bound with the GEL macromolecules modified by ChS. From TEM and ED, the matrix of the GEL-ChS molecules was mineralized by HAp nanocrystallites and the dense dried nanocomposite body was confirmed from SEM micrographs.

A Study on Combustion Characteristics using Forced Pulsating Flow (강제 맥동류를 이용한 연소특성 연구)

  • Yang, Young-Joon
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.11 no.5
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    • pp.109-114
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    • 2012
  • The combustion characteristics using forced pulsating flow were experimentally investigated with confined premixed flames stabilized by a reward-facing step. The intermittent combustion has many merits, for instance, such as high load combustion, high heat transfer, low emission gas, compared with those of continuous combustion. For these purposes, data processing of binary image was conducted to reveal the differences between intermittent and continuous combustion. As the results, it was possible to calculate the reaction zone using OH-emission band and, therefore, showed that forced pulsating flow was useful in combustion technology.

Restraint of carbon deposition in diesel ATR using fuel atomizer (연료 미립화기를 이용한 디젤 자열개질기 내 탄소침적 억제)

  • Yoon, Sang-Ho;Kang, In-Yong;Bae, Joong-Myeon
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.11a
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    • pp.67-70
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    • 2007
  • Diesel autothermal reforming has several problems such as carbon deposition in reforming reactor, sulfur poisoning of catalyst, difficulty of aromatics decomposition and mixing problems of reactants(diesel, steam, oxygen). Severe carbon deposition causes the rapid performance degradation of reformer. Carbon deposition is formed from ethylene, carbon precursor. Ethylene was generated at the homogeneous reaction zone of the reactor entrance. This phenomenon is closely linked to the mixing of reactants. In this investigation, we try to minimize the ethylene generation at the reactor entrance atomization technique.

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1차원 현장 soil column 실험을 통한 SAT 반응 모델 검증

  • ;Jeongkon Kim
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2003.09a
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    • pp.83-86
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    • 2003
  • Soil Aquifer Treatment (SAT) is a technique in which secondary- or tertiary-treated wastewater is infiltrated through unsaturated soil and stored in the saturated zone. In SAT, contaminants are removed by physical and biochemical reactions taking place in soils. In this study, a numerical model was developed to predict changes in water quality during SAT operations. The contaminant species considered in the model were ammonium, nitrate, dissolved organic carbon, and dissolved oxygen. The model was calibrated against experimental data obtained from one dimensional soil column tests conducted for 84 days. The calibrated model will be used to find out optimum conditions for the pilot- and regional-scale SAT operations to be scheduled for the next phase of this project.

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