• Title/Summary/Keyword: Reaction zone

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Heat Transfer analysis for Self-propagating High Temperature Synthesis of $MoSi_{2}$ (고온자전 반응에 의한 $MoSi_{2}$ 합성법의 열전달 해석)

  • 채수원;조해규;김용석
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 1994.10a
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    • pp.303-308
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    • 1994
  • The finite element method has been used to model and analyze the heat transfer phenomena during manufacturing process of MoSi $_{2}$ by SHS. For this urpose nonlinear transient heat transfer analyses by using ANSYS have been performed to compute the temperature distributiuon and the peak temperature in the test specimen. The effects of manufacturing process parameters such as a pre-heating temperature, the velocity of reaction zone have also been investigated. The results of the analysis have been compared with the experimental results.

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Measurement of Laminar Flame Speeds of Dimethyl Ether-Air Mixtures at High Pressure (고압에서 DME-Air 혼합기의 화염속도 측정)

  • Lee, Su Gak;Lee, Ki Yong
    • 한국연소학회:학술대회논문집
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    • 2013.06a
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    • pp.103-105
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    • 2013
  • Spherically expanding flames are used to measure flame speeds, which are derived the corresponding laminar flame speeds at zero stretch. Dimethyl Ether-Air mixtures at high pressure are studied over an extensive range of equivalence ratios. The classical shadowgraph technique is used to detect the reaction zone. In analytical methodology the optimization process using least mean squares is performed to extract the laminar flame speeds. Laminar flame speeds are compared with results reported in the literature.

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Flame Propagation Characteristics Through Suspended Combustible Particles in a Full-Scaled Duct (이송 배관 내 분진폭발의 화염전파특성)

  • Han, OuSup
    • Korean Chemical Engineering Research
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    • v.47 no.5
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    • pp.572-579
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    • 2009
  • This study is to investigate experimentally the flame structure and propagation mechanism in dust explosions and to provide the fundamental knowledge. Upward propagating laminar dust flames in a vertical duct of 1.8 m height and 0.15 m square cross-section are observed and flame front is visualized using by a high-speed video camera. Also, the thicknesses of preheated and reaction zone have been determined by a schlieren, electrostatic probe and thermocouple. The thickness of preheated zone in lycopodium dust flame is observed to be 4~13 mm, about several orders of magnitude higher than that of premixed gaseous flames. From the experimental results by a PIV(Particle Image Velocimetry) system, a certain residence time of the unburned particle in preheated zone is needed to generate combustible gas from the particle. The residence time will depend on preheated zone thickness, particle velocity and flame propagation velocity.

A Petrological Study on the Southwestern Contact Zone of the Boeun Granodiorite, Ogcheon Zone (보은화강섬록암(報恩花崗閃綠岩) 서남부(西南部) 접촉대(接觸帶)에 관(關)한 암석학적(岩石學的) 연구(硏究))

  • Lee, Dai Sung;Park, Jong Sim
    • Economic and Environmental Geology
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    • v.14 no.2
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    • pp.55-76
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    • 1981
  • Southwestern contact zone of the Boeun granodiorite occurs near the thrust fault between the Ogcheon Group and Majeonri Limestone Formation. Ogcheon Group, metasediments composed of the Munjuri Formation, Changri Formation, and unconformably overlying Hwanggangri Formation, belongs to greenschist facies of regional metamorphism accompanied with deformation of two fold axes, $N10^{\circ}E$ and $N45-65^{\circ}E$ directions. Basic metamorphic rocks occurring in the Changri and Limestone Formations are the meta-basalts and meta-diabases of tholeiitic basalt series. The meta-basalts intruded in the Changri Formation as sills, whereas the meta-diabases in the Changri and Limestone Formations as stocks in appearance. They are considered to have emplaced before the formation of two fold axes and related with the thrust fault, based on the geologic setting of the area. The metamorphic facies are identified to be greenschist facies to epidote-amphibolite facies for the meta-basalt, and epidote-amphibolite facies for the meta-diabases. It is interpreted that such a variety of facies was related from the combination of earlier deuteric alteration and later regional metamorphism. The metasediments in southwestern contact zont of the Boeun granodiorite which is a product of later syntectonic intrusion of middle Jurassic in age, show pyroxene-hornfels facies near the contact and amphibole-horenfels facies away from the contact to the mineral zoning in the contact metamorphic aureole of the Limestone Formation, based on the paragenetic analysis of mineral assemblages. The Limestone in the area appears to be considerably $SiO_2-CaO-MgO-CO_2-H_2O$ can be adopted to evaluate equilibrium conditions of the mineral assemblages in each mineral zone. It is revealed that a temperature gradient was existed accross the contact aureole ranging from the higher igneous side to lower sedimentary side, whereas no clear trend of $XCO_2$ variation appears but high mole fraction. The tremolite diopside-quartz-calcite assemblages occurs in common through the most mineral zones of contact aureole that is in good agreement with the equivalent reaction curve which extends over a wide range of $T-XCO_2$ conditions.

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High-Temperature Structural Analysis of a Small-Scale PHE Prototype - Analysis Considering Material Properties in Weld Zone - (소형 공정열교환기 시제품 고온구조해석 - 용접부 물성치를 고려한 해석 -)

  • Song, Kee-Nam;Hong, Sung-Deok;Park, Hong-Yoon
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.36 no.10
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    • pp.1289-1295
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    • 2012
  • A process heat exchanger (PHE) in a nuclear hydrogen system is a key component for transferring the considerable heat generated in a very high temperature reactor (VHTR) to a chemical reaction that yields a large quantity of hydrogen. A performance test on a small-scale PHE prototype made of Hastelloy-X is underway in a small-scale gas loop at the Korea Atomic Energy Research Institute. Previous research on the high-temperature structural analysis of the small-scale PHE prototype had been performed using base material properties. In this study, a high-temperature structural analysis considering the mechanical properties in the weld zone was performed, and the obtained results were compared with those of the previous research.

Histological Observation of Osteochondrosis Dissecans Occurred in Mandibular Condyle (하악과두에 생긴 박리성 뼈연골증의 조직학적 관찰)

  • Choung, Pill Hoon;Kim, Soung Min;Lee, Suk Keun
    • The Korean Journal of Oral and Maxillofacial Pathology
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    • v.42 no.5
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    • pp.145-152
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    • 2018
  • A 57 years old female complained of severe pain on the right temporomandibular joint (TMJ) area. Her right condyle had been partly resected under surgical operation 13 years ago due to condyle hypertrophy, thereafter she felt dull pain on TMJ area and recently the lesion became severely swelled and painful leading to cancer phobia. The present radiological views showed slightly enlarged and sclerosed condyle with increased radiopacity, but its articular sliding function was almost disable during mouth opening. The patient's TMJ lesion was carefully managed with conservative physiotherapy and pain treatment. The microsection of condyle head obtained from the previous operation was re-evaluated histologically, and it was finally diagnosed as osteochondrosis dissecans (OCD), exhibiting hyperplastic proliferation of cartilage in condyle head and marked vascular dilatation in epiphyseal zone. This abnormal cartilage tissue was distinguishable from normal cartilage tissue found in the peripheral cartilaginous cap of the same microsection. The involved cartilage cap showed thick hypertrophic chondrocyte zone with horizontal and vertical clefts accompanying diffuse hyaline degeneration. The superficial fibrous zone of cartilage cap was thickened and frequently peeled off, while lower hypertrophic zone of cartilage cap was highly cellular and proliferative. Consequently, the endochondral ossification became aberrant and resulted pre-mature apoptosis of many hypertrophic chondrocytes, followed by diffuse and mild inflammatory reaction in the underlying marrow tissue. Therefore, it was suggested that this hypertrophic condyle lesion, OCD, be differentiated depending on radiological and histological features from ordinary condyle hyperplasia, osteochondroma, and osteoarthritis, and that the pathological confirmation of OCD may provide a reliable modality for dental and medical treatment of chronic and painful TMJ lesion.

Partial Correlation between Hydrological, Geochemical and Microbiological Processes in Groundwater-stream Water Mixing Zone in a Rural Area (농촌지역 지하수-지표수 혼합구간에서 수리, 지구화학 및 생물학적 기작 사이의 편상관분석)

  • Kim, Heejung;Lee, Jin-Yong;Lee, Kang-Kun
    • Journal of Wetlands Research
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    • v.14 no.4
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    • pp.489-502
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    • 2012
  • Biogeochemical processes in groundwater-stream water mixing zone are recently of great interest because biodegradation and natural attenuation of aquatic contaminants may occur through the processes. The objectives of this study are to investigate the hydrologic and biogeochemical processes at the groundwater-stream water mixing zone through which surface water-driven nitrate may be naturally attenuated, and to examine the effect of the vertical flow exchange flux on biogeochemical processes using correlation analysis. To examine the direction of vertical water flow in the zone, vertical hydraulic gradients were measured at several depths using mini-piezometers. Microbial populations in soil samples of the zone were also analyzed by means of the polymerase chain reaction (PCR) and Cloning methods. In addition, partial correlations among vertical flow exchange, nitrate concentration and microbial activity was investigated to examine their mutual interaction. The results showed the significant interaction among the three parameters, resulting in natural attenuation of nitrate. This study showed an example of the biogeochemical fuction of groundwater-stream water mixing zone, which can be predictable from the examination of the interaction among microbial activities, concentration of contamination and vertical flow exchange flux. temperature show a significant difference in adjacent streambed, Also, the results shows that distribution of temperature was more affected by groundwater direction than intensity of flux.

Evaluation of Apparent Chloride Diffusion Coefficient of Fly Ash Concrete by Marine Environment Exposure Tests (해양 환경 폭로 시험을 통한 FA 콘크리트의 겉보기 염화물 확산계수 평가)

  • Yoon, Yong-Sik;Lim, Hee-Seob;Kwon, Seung-Jun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.23 no.3
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    • pp.119-126
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    • 2019
  • In case of RC(Reinforced Concrete) structures which are constructed in coastal areas, chloride ions in sea water corrode the steel rebar in concrete. Especially in coastal areas, RC structures are affected by not only immersion of sea water, but also tidal of sea water and airborne chloride ions. In this study, marine environment exposure tests are conducted, considering 3 types of exposure environments(immersion zone, tidal zone, splash zone) and the exposure periods of 180 days, 365 days, and 730 days. Also, the concrete mixtures for this study are established, considering 3 levels of W/B(Water to Binder) ratio(0.37, 0.42, 0.47) and 2 levels of substitution rate of Fly ash(0 %, 30 %). In all exposure environments, Fly ash concrete has lower apparent chloride diffusion coefficients than OPC concrete. It is thought that fly ash's pozzolan reaction improves chloride resistance of concrete. Fly ash concrete has up to 63.5 % of decreasing rate in 180 days of exposure and up to 55.8 % of decreasing rate in 730 days of exposure, based on diffusion coefficients of OPC concrete. As a result of evaluation about effects of exposure environments, apparent chloride diffusion coefficients of fly ash concrete are evaluated in order of tidal zone, immersion zone, and splash zone. In tidal zone, It is thought that repeated cycles of wetting and drying of sea water cause the diffusion of chloride ions rapidly.

Effects of Lewis Number and Preferential Diffusion in Syngas Flame Diluted with He and Ar (He와 Ar으로 희석된 합성가스 화염에서 루이스 수와 선호확산효과)

  • Kim, Tae Hyung;Park, Jeong;Kwon, Oh Boong;Park, Jong Ho
    • Journal of the Korean Society of Combustion
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    • v.19 no.4
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    • pp.28-34
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    • 2014
  • Numerical study is conducted to grasp flame characteristics in $H_2/CO$ syngas counterflow diffusion flames diluted with He and Ar. An effective fuel Lewis number, applicable to premixed burning regime and even to moderately-stretched diffusion flames, is suggested through the comparison among fuel Lewis number, effective Lewis number, and effective fuel Lewis number. Flame characteristics with and without the suppression of the diffusivities of H, $H_2$, and He are compared in order to clarify the important role of preferential diffusion effects through them. It is found that the scarcity of H and He in reaction zone increases flame temperature whereas that of $H_2$ deteriorates flame temperature. Impact of preferential diffusion of H, $H_2$, and He in flame characteristics is also addressed to reaction pathways for the purpose of displaying chemical effects.

The Effect of Cooling method on the Surface Reaction Zone of CP Titanium Casting Body (티타늄 주조체 냉각방법이 표면반응층에 미치는 영향)

  • Moom, Soo;Choi, Seog-Soon;Moon, Il
    • Journal of Technologic Dentistry
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    • v.23 no.2
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    • pp.203-210
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    • 2002
  • This test is to conduct applied research the reaction area of the Ti-cast metal body which is made use of Dental Phosphate-silica alumina bonded investment material selling at a market, and the cooling method is how to effect on the acicular. The experimentation is as followings, 1. Experimental specimens After invest with Dental Phosphate-silica alumina bonded investment material, the $10{\times}10{\times}1.0mm^3$ wax pattern was casted by Dental high vacuum argon centrifugal casting machine. 2. Test We can analyze SEM/EDS, XRD utilize the fractography(an optical microscope). 3. Conclusion The pure cast metal body constituted of reaction products layer, stability layer and contamination layer. This pure cast have no connection with the cooling condition. The pure Titanium shows difference in a component distribution according to the cooling condition. Through this experimentation we can establish that acicular in the pure Ti-cast metal is consist of Hexagonal structure a=2.9505$\AA$, c=4.6826$\AA$.

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