• Title/Summary/Keyword: Reaction stability

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Synthesis and Characterization of Lithium Dual Complex Grease (Lithium Dual Complex 그리이스의 합성 및 특성연구)

  • 최웅수;권오관;문탁진;유영홍
    • Tribology and Lubricants
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    • v.1 no.1
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    • pp.80-87
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    • 1985
  • Lithium dual complex grease was prepared through the second continuous saponification reaction of a complex gellant system whose essential components comprised of a selected hydroxy fatty acid, lithium hydroxide monohydrate and boric acid to have a fiber structure of chemical, thermal and mechanical stability at high temperatures. An optimum amount of complex gellant was found to be 14% (NLGI #2), and an addition of castor wax of 1.5% provided an excellent performance properties, especially. The oil separation, oxidation stability, water wash-out property, shear stability, extreme pressure and wear property of thus prepared were tested by the ASTM and KS methods, and a characteristic result was obtained.

Flame Stability of Dual Swirl Combustor with variable SNG composition using the Chemiluminescence Measurement (자발광 계측을 통한 모사 SNG 수소함량에 따른 이중선회 버너의 화염 안정화 특성)

  • Choi, Inchan;Oh, Kwangchul;Lee, Keeman
    • 한국연소학회:학술대회논문집
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    • 2014.11a
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    • pp.147-148
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    • 2014
  • This article describes an investigation of flame stability characteristics with various compositions of synthetic natural gas (SNG) in dual swirl combustor. The objective of this study is to investigate the flame stabilization, flame structure, fuel compatibility using chemiluminescence measurement in SNG with varying fuel compositions. As experimental conditions, hydrogen content was adjusted from 0 to 11%. Experimental results show that the addition of hydrogen has a major effect on flame behavior due to the higher burning rates associated with hydrogen consequently, The higher reaction activity of hydrogen has extended lean blow-off limit. Especially, DI flame limit has improved more 12.1%.

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Synthesis and Thermal Stability of Polyol Esters (폴리올에스테르의 합성 및 열안정성)

  • Baek, Jin-Wook;Chung, Keun-Wo;Kim, Young-Wun;Seo, In-Ok;Han, Jung-Sik
    • Proceedings of the Korean Society of Tribologists and Lubrication Engineers Conference
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    • 2002.05a
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    • pp.130-134
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    • 2002
  • Polyol esters were synthesized by condensation reaction of polyols (PE and DIPE) and linear acids such as valeric acid, caproic acid, heptylic acid and caprylic acid. The structures of polyol esters were confirmed by gas chromatography. Hot tube test was used to measure thermal stability of polyol esters and its thermal properties depended on the structure of acid moiety contained in polyol esters.

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Studies on Semisolid Infant Foods( ll ) - Storage Stability of The Home -Prepared Infant Foods - (반고체 이유보충식(離乳補充食)에 관한 연구(硏究) (II) -가정용(家庭用) Formula의 저장성(貯藏性)-)

  • Yoon, Suk-Kyong;Lee, Young-Chun
    • Journal of Nutrition and Health
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    • v.18 no.1
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    • pp.55-62
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    • 1985
  • The storage stability of the developed Formula of infant foods was investigated. The results are summarized as follows : When formula A and B were stored at room temperature and refrigeration temperature, there was no remarkable changes in consistency. In frozen state, formula A showed more stability in consistency than formula B and formula A could be stored for 6 months without problems due to retrogradation of starch. The heat treatment of both A and B resulted in the increase of a-value, while L-and b-value showed no such change. But from the 4th month at room temperature, and 5th to 6th month at refrigeration appeared an increase in a -value, hence the browning reaction, while frozen samples did not show noticeable changes in surface color. The heat treatment also caused an increase in POV on both formula. The extent of changes in POV during storage varied with storage temperatures and samples.

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Thermal and Electrochemical Studies of Tris(2,4,6-trimethoxyphenyl)Phosphine as a Flame Retardant Additive for Li-ion Battery (리튬이차전지 난연성 전해액 첨가제로서의 Tris(2,4,6-trimethoxyphenyl)Phosphine의 열적, 전기화학적 특성)

  • Ahn, Se-Young;Kim, Ke-Tack;Kim, Hyun-Soo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.12
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    • pp.1130-1134
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    • 2008
  • Thermal and electrochemical properties were discussed with tris(2,4,6-trimethoxyphenyl)Phosphine (TTMPP) as a flame retradant additive for Li-ion battery. TTMPP showed excellent thermal stability with charged cathodes. Addition of 1 wt.% of the additive to the electrolyte improved the thermal stability without damaging the performance of the battery. The oxygne evolution reaction delayed nearly by $60^{\circ}C$. The capacity retention ratio in cycle life tests of the battery with 1 wt.% TTMPP was slightly improved comparing to the no additive cells.

Nonlinear Optical Polymers Possessing Thermal and Temporal Stability: Potentials and Prospect

  • Kim, Dong-Wook;Ju, Hyun-Kyung;Ahn, Soo-Mi;Yoon, Sung-Cheol;Lim, Jong-Sun;Park, Seung-Ku;Lee, Chang-Jin
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.165-165
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    • 2006
  • We prepared nonlinear optical (NLO) polymers possessing thermal and temporal stability, which were based on the polyimides appended with NLO chromophores. NLO chromophores with a terminal hydroxyl group have been synthesized by coupling between aminobenzene or julolidine donor and phenylene bridge, and then subsequent coupling between the resulting product and tricyanofuran acceptor. The chromophores were chemically bonded to the polyimides backbone through Mitsunobu reaction. The NLO polymers showed $160-170^{\circ}C$ of Tgs and were thermally stable up to $200^{\circ}C$. We obtained optical quality films by spincoating and evaluated their electro-optical properties and temporal stability.

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OUTPUT FEEDBACK SLEWING CONTROL OF FLEWIBLE SPACECRAFT BY LYAPUNOV STABILITY THEORY

  • Kim, Dae-Sik;Kim, Chun-Hwey;Bang, Hyo-Choong
    • Journal of Astronomy and Space Sciences
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    • v.14 no.2
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    • pp.367-374
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    • 1997
  • Slewing maneuver and vibration suppression control of flexible spacecraft model by Lyapunov stability theory are considered. The specific model considered in this paper consists of a rigid hub with an elastic appendage attached to the central hub and tip mass. Attitude control to point and stabilize single axis using reaction wheel type device is tested. To control all flexible modes is so critical to designing an active control law. We therefore considered an direct output feeback control design by using Lyapunov stability theory. It is shown that the ouput feedback control law design with proposed configuration gives satisfactory result in slewing performance and vibration suppression control.

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Synthesis and Thermal Stability of Polyol Esters (폴리올 에스테르의 합성 및 열 안정성)

  • Chung, Keun-Wo;Baek, Jin-Wook;Kim, Young-Wun;Seo, In-Ok;Han, Jeong-Sik
    • Tribology and Lubricants
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    • v.18 no.5
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    • pp.319-323
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    • 2002
  • Polyol esters were synthesized by condensation reaction of polyols (PE and DiPE) and linear acids such as valeric acid, caproic acid, heptylic acid and caprylic acid. The structures of polyol esters were confirmed by gas chromatography. Hot tube test was used test was used to measure thermal stability of polyol esters and its thermal properties depended on the structure of acid moiety contained in polyol esters.

Nanostructure of core-shell support for enhanced electrochemical activity in PEMFC (코어-쉘 구조의 지지체를 이용한 성능 향상에 대한 연구)

  • Kim, Doyoung;Han, Sangbeom;Lee, Youngwoo;Kim, Sijin;Park, Kyungwon
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.11a
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    • pp.93-93
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    • 2011
  • Nanostructures consisting of $TiO_2$ particles as a core and carbon as a shell ($TiO_2$@C) were prepared by heat treatment of $TiO_2$ nanoparticles at high temperature in a methane atmosphere. X-ray diffraction and transmission electron microscopy showed that a carbon shell layer was formed well. These structures were used as supports for platinum nanoparticles and the hybrid particles exhibit improved catalytic activity and stability toward ORR compared to Pt on a carbon black (Vulcan XC-72R). It is likely that enhanced catalytic properties of the Pt on $TiO_2$@C could be due to the stability of the core-shell support in comparison with carbon black support.

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