• Title/Summary/Keyword: Reaction parameter

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Muscle-Induced Accelerations of Body Segments (근육의 힘이 신체 각 부분의 가속도에 미치는 영향)

  • Khang, Gon
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.15 no.6
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    • pp.1967-1974
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    • 1991
  • When the functional electrical stimulation is employed to recover mobility to the plegic, it is very important to understand functions of the selected muscles. I have investigated how a muscle acts to accelerate the body segments, since the body segements are connected by joints so that contraction of a muscle not only rotates the segments to which it is attached but also causes other segments to rotate by creation a reaction force at every joint, which is called the inertial coupling. I found that a single-joint muscle always acts to accelerate the spanned joint in the same direction as the joint torque produced by the muscle. However, a double-joint muscle can act to accelerate the spanned joint in the opposite direction to the joint torque produced by the muscle depending on (1) the body position, (2) the body-segmental parameters, and (3) the type of the movement. Investigating the condition number of the inertia matrix of the body-segmental model gave us some insights into how controllable the body-segmental system is for different values of the factors mentioned above. The results suggested that the upright position is the most undesirable position to independently control the three segments(trunk, thigh and shank) and that the controllability is the most sensitive to variation of the shank length and the trunk mass, which implies that accuracy is required particularly when we estimate these two body-segmental parameters before the paralyzed muscles are innervated by using electrical stimulation.

Development of the CAP Water Quality Model and Its Application to the Geum River, Korea

  • Seo, Dong-Il;Lee, Eun-Hyoung;Reckhow, Kenneth
    • Environmental Engineering Research
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    • v.16 no.3
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    • pp.121-129
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    • 2011
  • The completely mixed flow and plug flow (CAP) water quality model was developed for streams with discontinuous flows, a condition that often occurs in low base flow streams with in-stream hydraulic structures, especially during dry seasons. To consider the distinct physical properties of each reach effectively, the CAP model stream network can include both plug flow (PF) segments and completely mixed flow (CMF) segments. Many existing water quality models are capable of simulating various constituents and their interactions in surface water bodies. More complicated models do not necessarily produce more accurate results because of problems in data availability and uncertainties. Due to the complicated and even random nature of environmental forcing functions, it is not possible to construct an ideal model for every situation. Therefore, at present, many governmental level water quality standards and decisions are still based on lumped constituents, such as the carbonaceous biochemical oxygen demand (CBOD), the total nitrogen (TN) or the total phosphorus (TP). In these cases, a model dedicated to predicting the target concentration based on available data may provide as equally accurate results as a general purpose model. The CAP model assumes that its water quality constituents are independent of each other and thus can be applied for any constituent in waters that follow first order reaction kinetics. The CAP model was applied to the Geum River in Korea and tested for CBOD, TN, and TP concentrations. A trial and error method was used for parameter calibration using the field data. The results agreed well with QUAL2EU model predictions.

A Study of NH3 Adsorption/Desorption Characteristics and Model Based Control in the Urea-SCR System (Urea-SCR 시스템의 NH3 흡·탈착 특성 및 모델기반 제어 연구)

  • Ham, Yunyoung;Park, Suyeol
    • Transactions of the Korean Society of Automotive Engineers
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    • v.24 no.3
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    • pp.302-309
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    • 2016
  • Urea-SCR system is currently regarded as promising NOx reduction technology for diesel engines. SCR system has to achieve maximal NOx conversion in combination with minimal $NH_3$ slip. In this study, model based open loop control for urea injection was developed and assessed in the European Transient Cycle (ETC) for heavy duty diesel engine. On the basis of the transient modeling, the kinetic parameters of the $NH_3$ adsorption and desorption are calibrated with the experimental results performed over the zeolite based catalyst. $NH_3$ storage or surface coverage of SCR catalyst can not be measured directly and has to be calculated, which is taken into account as a control parameter in this model. In order to reduce $NH_3$ slip while maintaining NOx reduction, $NH_3$ storage control algorithm was applied to correct the basic urea quantity. If the actual $NH_3$ surface coverage is higher than the maximal $NH_3$ surface coverage, the urea injection quantity is significantly reduced in the ETC cycle. By applying this logic, the resulting $NH_3$ slip peak can be avoided effectively. With optimizing the kinetic parameters based on standard SCR reaction, it suggests that a simplified, less accurate model can be effective to evaluate the capability of model based control in the ETC cycle.

Kinetic Parameter Analysis of Hydrogen Diffusion Reaction for Hydrogen Storage Alloy of Fuel Cell System (연료전지의 수소저장용 합금에 대한 수소확산반응의 속도론적 해석)

  • Kim, Ho-Sung
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.20 no.2
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    • pp.45-49
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    • 2006
  • Electrochemical hydrogenation/dehydrogenation properties were studied for a single particle of a Mm-based(Mm : minh metal) hydrogen storage alloy($MmNi_{3.55}Co_{0.75}Mn_{0.4}Al_{0.3}$) for fuel cell and Ni-MH batteries. A carbon fiber microelectrode was manipulated to make electrical contact with an alloy particle, and the potential-step experiment was carried out to determine the apparent chemical diffusion coefficient of hydrogen atom($D_{app}$) in the alloy. Since the alloy particle we used here was a dense, conductive sphere, the spherical diffusion model was employed for data analysis. $D_{app}$ was found to vary the order between $10^{-9}\;and\;10^{-10}[cm^2/s]$ over the course of hydrogenation and dehydrogenation process. Compared with the conventional composite film electrodes, the single particle measurements using the microelectrode gave more detailed, true information about the hydrogen storage alloy.

Decomposition of Carbon Dioxide using $Zn_{x}Fe_{3-x}O_{4-{\delta}}$ (($Zn_{x}Fe_{3-x}O_{4-{\delta}}$를 이용한 이산화탄소의 분해)

  • Yang, Chun-Mo;Cho, Young-Koo;Rim, Byung-O
    • Journal of the Korean Applied Science and Technology
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    • v.17 no.1
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    • pp.55-61
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    • 2000
  • $Zn_{x}Fe_{3-x}O_{4}(0.00.<X<0.08)$ was synthesized by air oxidation method for the decomposition of carbon dioxide. We investigated the characteristics of catalyst, the form of methane by gas chromatograph after decomposition of carbon dioxide and kinetic parameter. $Zn_{x}Fe_{3-x}O_{4}(0.00.<X<0.08)$ was spinel type structure. The surface areas of catalysts($Zn_{x{Fe_{3-x}O_{4}(0.00.<X<0.08)$) were $15{\sim}27$ $m^{2}/g$. The shape of $Zn_{0.003}Fe_{2.997}O_{4}$ was sphere. The optimum temperature for the decomposition of carbon dioxide into carbon was $350^{\circ}C$. $Zn_{0.003}Fe_{2.997}O_{4}$ showed the 85% decomposition rate of carbon dioxide and the degree of reduction by hydrogen(${\delta}$) of $Zn_{0.003}Fe_{2.997}O_{4}$ was 0.32. At $350^{\circ}C$, the reaction rate constant and activation energy of $Zn_{0.003}Fe_{2.997}O_{3.68}$ for the decomposition of carbon dioxide into carbon were 3.10 $psi^{1-{\alpha}}/min$ and 0.98 kcal/mole respectively. After the carbon dioxide was decomposed, the carbon which was absorbed on the catalyst surface was reacted with hydrogen and it became methane.

Interactive Simulation between Rigid body and Fluid using Simplified Fluid-Surface Model (간략화된 유체 표면모델을 이용한 강체와 유체의 상호작용 시뮬레이션)

  • Kim, Eun-Ju
    • Journal of Korea Multimedia Society
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    • v.12 no.2
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    • pp.323-328
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    • 2009
  • Natural Phenomena are simulated to make computer users feel verisimilitude and be immersed in games or virtual reality. The important factor in simulating fluid such as water or sea using 3D rendering technology in games or virtual reality is real-time interaction and reality. There are many difficulties in simulating fluid models because it is controlled by many equations of each specific situation and many parameter values. In addition, it needs a lot of time in processing physically-based simulation. In this paper, I suggest simplified fluid-surface model in order to represent interaction between rigid body and fluid, and it can make faster simulation by improved processing. Also, I show movement of fluid surface which is come from collision of rigid body caused by reaction of fluid in representing interaction between rigid body and fluid surface. This natural fluid-surface model suggested in this paper is represented realistically in real-time using fluid dynamics veri similarly. And the fluid-surface model will be applicable in games or animation by realizing it for PC environment to interact with this.

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Strain-Softening Behavior of Circular Tunnel Excavated in Mohr-Coulomb Rock Mass (Mohr-Coulomb 암반에 굴착된 원형 터널의 변형률연화 거동해석)

  • Lee, Youn-Kyou
    • Tunnel and Underground Space
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    • v.16 no.6 s.65
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    • pp.495-505
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    • 2006
  • Calculating the distribution of stresses and displacements around a circular tunnel excavated in infinite isotropic rock mass subjected to hydrostatic stress condition is one of the basic problems in rock engineering. While closed-form solutions for the distribution are known if rock masses are considered as elastic, perfectly plastic, or brittle-plastic media, a few numerically approximated solutions based on various simplifying assumptions have been reported for strain-softening rock mass. In this study, a simple numerical method is introduced for the analysis of strain-softening behavior of the circular tunnel in Mohr-Coulomb rock mass. The method can also applied to the analysis of the tunnel in brittle-plastic or perfectly plastic media. For the brittle-plastic case where closed-formsolution exists, the performance of the present method is verified by showing an excellent agreement between two solutions. In order to demonstrate the strain-softening behaviors predicted by the proposed method. a parameter study for a softening index is given and the construction of ground reaction curves is carried out. The importance of defining the characteristics of dilation in plastic analysis is discussed through analyzing the displacements near the surface of tunnel.

Mechanical alloying behavior of PbTe thermoelectric materials (PbTe 열전재료의 기계적 합금화 거동)

  • O, Tae-Seong;Choe, Jae-Sik;Hyeon, Do-Bin
    • Korean Journal of Materials Research
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    • v.5 no.2
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    • pp.223-231
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    • 1995
  • Mechanical alloying behavior of the PbTe intermetallic compound, which is used for thermoelectric generation, has been investigated with milling time and ball-to-powder weight ratio. Formation of PbTe alloy was completed by mechanical alloying of the as-mixed Pb and Te powders for 2 minutes at ball-to-powder weight ratio of 2 : 1. In situ measurement of the abrupt temperature rise during the ball milling process indicated that the PbTe intermetallic compound was formed by a self-sustained reaction rather than diffusional reactions. Lattice constant of PbTe alloy fabricated by mechanical alloying, 0. 6462nm, was not varied with milling time and ball-to-powder weight ratio. This value of the lattice parameter is in excellent agreement with 0.6459nm, which was reported for PbTe powders processed by melting and grinding.

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Calculation of Low-Energy Reactor Neutrino Spectra for Reactor Neutrino Experiments

  • Riyana, Eka Sapta;Suda, Shoya;Ishibashi, Kenji;Matsuura, Hideaki;Katakura, Jun-ichi
    • Journal of Radiation Protection and Research
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    • v.41 no.2
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    • pp.155-159
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    • 2016
  • Background: Nuclear reactors produce a great number of antielectron neutrinos mainly from beta-decay chains of fission products. Such neutrinos have energies mostly in MeV range. We are interested in neutrinos in a region of keV, since they may take part in special weak interactions. We calculate reactor antineutrino spectra especially in the low energy region. In this work we present neutrino spectrum from a typical pressurized water reactor (PWR) reactor core. Materials and Methods: To calculate neutrino spectra, we need information about all generated nuclides that emit neutrinos. They are mainly fission fragments, reaction products and trans-uranium nuclides that undergo negative beta decay. Information in relation to trans-uranium nuclide compositions and its evolution in time (burn-up process) were provided by a reactor code MVP-BURN. We used typical PWR parameter input for MVP-BURN code and assumed the reactor to be operated continuously for 1 year (12 months) in a steady thermal power (3.4 GWth). The PWR has three fuel compositions of 2.0, 3.5 and 4.1 wt% $^{235}U$ contents. For preliminary calculation we adopted a standard burn-up chain model provided by MVP-BURN. The chain model treated 21 heavy nuclides and 50 fission products. The MVB-BURN code utilized JENDL 3.3 as nuclear data library. Results and Discussion: We confirm that the antielectron neutrino flux in the low energy region increases with burn-up of nuclear fuel. The antielectron-neutrino spectrum in low energy region is influenced by beta emitter nuclides with low Q value in beta decay (e.g. $^{241}Pu$) which is influenced by burp-up level: Low energy antielectron-neutrino spectra or emission rates increase when beta emitters with low Q value in beta decay accumulate Conclusion: Our result shows the flux of low energy reactor neutrinos increases with burn-up of nuclear fuel.

Kinetics of the Low-temperature Pyrolysis of Mixed Plastics in the Batch Reactor (회분식반응기에서의 혼합 플라스틱의 저온열분해 kinetics)

  • Cha, Wang Seog;Oh, Myung Seog;Jang, Hyun Tae;Tae, Beomseok
    • Korean Chemical Engineering Research
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    • v.46 no.3
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    • pp.540-544
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    • 2008
  • Pyrolytic characteristics of mixed plastics containing 22 wt.% HDPE, 17 wt.% LDPE, 27 wt.% PP, 12 wt.% PS, 16 wt.% ABS, 6 wt.% PVC have been studied in the batch-type microreactor of stainless steel. Thermal degradation experiments were performed at temperature of $410{\sim}450^{\circ}C$. The yield of each pyrolytic products were obtained by the weight measurement and molecular weight distribution of pyrolytic liquid products determined by the GC-SIMDIS method. It was shown that the yield and molecular weight of pyrolytic liquid product were decreased with the increase of reaction temperature and time. It was know that 20wt% of PVC composing of the mixed plastics was converted to the gas products of chloride during the pyrolysis process. The chain-end scission rate parameter was determined to be 50.2 kcal/mole of mixed plastics by the Arrhenius plot.