• Computers and Concrete
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• 제15권5호
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• pp.847-864
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• 2015

In this paper, a reaction-diffusion model of carbonation process in self-compacting concrete (SCC) was realized with a consideration of multi-field couplings. Various effects from environmental conditions, e.g. ambient temperature, relative humidity, carbonation reaction, were incorporated into a numerical simulation proposed by ANSYS. In addition, the carbonation process of SCC was experimentally investigated and compared with a conventionally vibrated concrete (CVC). It is found that SCC has a higher carbonation resistance than CVC with a comparable compressive strength. The numerical solution analysis agrees well with the test results, indicating that the proposed model is appropriate to calculate and predict the carbonation process in SCC. The parameters sensitivity analysis also shows that the carbon dioxide diffusion coefficient and moisture field are essentially crucial to the carbonation process in SCC.

• 연구논문집
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• 통권29호
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• pp.151-162
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• 1999

In general, manufacturing processes of thermosetting composites consist of mold filling and resin cure. The important parameters used in modeling and designing mold filling are the permeability of the fibrous preform and the viscosity of the resin. To consolidate a composite, resin cure or chemical reaction plays an essential role. Cure kinetics. Therefore, is necessary to quantify the extent of chemical reaction or degree of cure. It is also important to predict resin viscosity which can change due to chemical reaction during mold filling. There exists a heat transfer between the mold and the composite during mold filling and resin cure. Cure kinetics is also used to predict a temperature profile inside composite. In this study, a new scheme which can determine cure kinetics from dynamic temperature scaning was proposed. The method was applied to epoxy resin system and was verified by comparing measurements and predictions.

• 한국환경과학회지
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• 제6권4호
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• pp.351-357
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• 1997

In the Atmosphere under the various physical and chemical condition different chemical reactions occur and there are a number of air pollutants which are generated by photochemical reaction by absorbing solar energy. Therefor various testing simulation was done as foundation work to develop the numerical model for the prediction of concentration of air pollutants. It was shown change of msjor air pollutants concentration In according to variation of photodissociation speed constant, Kl and Initial condition of air pollutants concentration which plays major role In photochemical reaction. The photochemical reaction model which was used In this study Is found to be useful for understanding relationship among the concentration of reacting air pollutants and the prediction of concentration of air pollutants in urban atmosphere.

• 한국신재생에너지학회:학술대회논문집
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• 한국신재생에너지학회 2008년도 추계학술대회 논문집
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• pp.25-28
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• 2008

Steam reforming reaction is a matured technology to get hydrogen from hydrocarbon fuels compared with other reforming reactions such as partial oxidation(POX), autothermal reforming(ATR). It is so endothermic that it needs heat source to activate the reaction. Due to the reaction characteristics, heat transfer limitation phenomena generally occur in the steam reformer. As one of new ideas, the effect of discontinuous gas feeding is investigated based on heat transfer characteristics. The new operating method is usually favorable at high GHSV region(i.e. over $10,000h^{-1}$). In order to numerically simulate the physical issues, numerical approach is adopted based on heterogeneous reaction model, two-equation model in energy equation, and other constitutive models in porous media.

• 대한기계학회논문집
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• 제17권12호
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• pp.3187-3195
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• 1993

Combustion of liquid-fuelled combustion in a high-temperature vitiated-air stream was studied. The mathematical formulation comprise the application of Eulerian conservation equation to the gas phase and Lagrangian equation of droplet motion. The latter is coupled with a droplet-tracking technique (PSI-CELL Model) which regard the droplet phase as a source of mass, momentum, and energy to the gaseous phase. Reaction rate is determined by taking into account the Arrhenius reaction rate based on a single-step reaction mechanism. The calculated profiles show somewhat uncertainess at the upstream, but bases data for designing the combustor followed by 2-phase flow were obtained.

• KSBB Journal
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• 제5권2호
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• pp.133-139
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• 1990

1회의 회분실험 데이터로부터 효소반응 속도식의 매개 변수를 쉽게 추정할 수 있는 방법을 제시하였다. 여러 가지 반응패턴을 갖는 모델식에 있어서 효소반응 데이터를 적용시킨 결과 정확하고 간편하게 매개변수값을 추정할 수 있었다. 가역반응의 경우에는 3개의 매개변수를 갖는 모델식의 형태로 평형 기질농도 및 매개변수를 추정할 수 있었다. 또한 반응특성이 잘 알려져 있지 않은 효소 반응 시스템에 있어서는 효소반응이 기질이나 생산물의 저해작용을 받는지 여부와 그 저해패턴을 확인할 수 있었다.

• Bulletin of the Korean Chemical Society
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• 제18권11호
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• pp.1199-1203
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• 1997

The investigation of cure kinetics of biphenyl epoxy (4,4-diglycidyloxy-3,3,5,5-tetramethyl biphenyl)-xylok resin system with four different catalysts was performed by differential scanning calorimeter using an isothermal approach. All kinetic parameters of the curing reaction including the reaction order, activation energy and rate constant were calculated and reported. The results indicate that the curing reaction of the formulations using triphenylphosphine (TPP) and 1-benzyl-2-methylimidazole (1B2MI) as a catalyst proceeds through a first order kinetic mechanism, whereas that of the formulations using diazabicyloundecene (DBU) and tetraphenyl phosphonium tetraphenyl borate (TPP-TPB) proceeds by an autocatalytic kinetic mechanism. To describe the cure reaction in the latter stage, we have used the semiempirical relationship proposed by Chern and Poehlein. By combining an nth order kinetic model or an autocatalytic model with a diffusion factor, it is possible to predict the cure kinetics of each catalytic system over the whole range of conversion.

• International Journal of Naval Architecture and Ocean Engineering
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• 제12권1호
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• pp.723-732
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• 2020

A theoretical calculation model for ship stern bearings with large hull deformation is established and validated theoretically and experimentally. A hull simulation model is established to calculate hull deformations corresponding to the reaction force of stern bearings under multi-factor and multi-operating conditions. The results show that in the condition of wave load, hull deformation shows randomness; the aft stern tube bearing load obeys the Gaussian distribution and its value increases significantly compared with the load under static, and the probability of aft stern tube bearing load greater than 1 is 65.7%. The influence laws and levels between hull deformation and bearing reaction force are revealed, and suggestions for ship stern bearing specifications are proffered accordingly.

• Bulletin of the Korean Chemical Society
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• 제33권3호
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• pp.1020-1028
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• 2012

This work compares various models for geminate reversible diffusion influenced reactions. The commonly utilized contact reactivity model (an extension of the Collins-Kimball radiation boundary condition) is augmented here by a volume reactivity model, which extends the celebrated Feynman-Kac equation for irreversible depletion within a reaction sphere. We obtain the exact analytic solution in Laplace space for an initially bound pair, which can dissociate, diffuse or undergo "sticky" recombination. We show that the same expression for the binding probability holds also for "mixed" reaction products. Two different derivations are pursued, yielding seemingly different expressions, which nevertheless coincide numerically. These binding probabilities and their Laplace transforms are compared graphically with those from the contact reactivity model and a previously suggested coarse grained approximation. Mathematically, all these Laplace transforms conform to a single generic equation, in which different reactionless Green's functions, g(s), are incorporated. In most of parameter space the sensitivity to g(s) is not large, so that the binding probabilities for the volume and contact reactivity models are rather similar.

• 대한기계학회논문집
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• 제16권1호
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• pp.70-76
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• 1992

본 연구에서는 수소와 공기의 예혼합기체가 가열된 벽면에 노출되어 있는 경 우의 점화문제를 1차원 비정상상태로 예측하고자 하며 특히, 계산에서 가정하는 화학 반응기구가 갖는 정확성에 관하여 수치해석적으로 고찰하고자 한다.