• Title/Summary/Keyword: Reaction model

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Development of a 3-Dimensional Turbulent Reaction Computer program for the Incineration of a Carbon Tetrachloride($CCl_4$) ( I ) (사염화탄소($CCl_4$) 소각을 위한 로타리 킬른 소각로 3차원 난류반응 컴퓨터 프로그램 개발( I ))

  • 엄태인;장동순
    • Journal of the Korean Society of Safety
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    • v.9 no.1
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    • pp.100-109
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    • 1994
  • In this study, it is investigated that the possibility of the numerical simulation for the incineration of the hazardous material, crbon tetrachloride($CCl_4$). A 3-dimensional numerical technology is applied for turbulent reacting flows of the full-scale Dow Chemical incinerator. The calculations are made by a CRAY-2S, super computer. The major parameters considered in this study are kiln revolution rate (rpm), filling ratio of the solid waste(f), burner Injection velocity and angle, and turbulent air jets for swirl. And the employed turbulent reaction model is the eddy break-up model which is a kind of fast chemistry model assuming general equilibrium and used for a premixed flame. The calculated flow fields are presented and discussed. 1) The presence of turbulent air nozzles for swirl gives rise to visible increase of the convective motion over the region of the solid waste. This implies the possibility to enhance the mixing of the waste with the surrounding all and thereby to reduce thermal and species stratification, which were reported in a large rotary kiln operation. 2) Considering that the location of the recirculation region has a strong relation with the heating rate of the solid waste, the control of the recirculation region by the burner injection angle Is quite desirable in the sense of the flexible design of the rotary kiln incinerator for a carbon tetrachloride. 3) Finally, it is found that the eddy break-up model Is not suitable for carbon tetrachloride($CCl_4$) because this model is not incorporated the flame inhibition trend due to the presence $CCl_4$compound.

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MATHEMATICAL MODEL OF SULFUR UTILIZING AUTOTROPHIC DENITRIFICATION IN AN UP-FLOW PACKED-BED REACTOR BASED ON BIOMASS DISTRIBUTION

  • Park, Woo-Shin;Ahn, Yoeng-Hee;Jung, Kyung-Ja;Tatavarty, Rameshwar;Kim, In-S.
    • Environmental Engineering Research
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    • v.10 no.4
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    • pp.191-198
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    • 2005
  • A novel technology for the removal of nitrogen from wastewater, an autotrophic denitrification process with sulfur particles, has been developed. A respirometer was employed to monitor the nitrogen gas produced in the reactor, while 4',6-diamidino-2-phenylindole staining was employed to investigate the biomass distribution in terms of cell number according to the reactor height. From the respirometric monitoring, the denitrification reaction was defined as a first order reaction. The reactor was divided into 7 sections and biomass was analyzed in each section where cell number was ranged from $4.8\;{\times}\;10^6\;to\;8.7\;{\times}\;10^7$ cells/g dry weight of sulfur. Cells placed mostly in the lower layer ( < 10 cm of height). A function for biomass distribution was obtained with non-linear regression. Then a mathematical model has been developed by combining a plug-flow model with the biomass distribution function. The model could make a vertical profile of the up-flow packed-bed reactor resulting in a reasonable comparison with measured nitrate concentration with 5% of error range.

An Artificial Emotion Model for Expression of Game Character (감정요소가 적용된 게임 캐릭터의 표현을 위한 인공감정 모델)

  • Kim, Ki-Il;Yoon, Jin-Hong;Park, Pyoung-Sun;Kim, Mi-Jin
    • 한국HCI학회:학술대회논문집
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    • 2008.02b
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    • pp.411-416
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    • 2008
  • The development of games has brought about the birth of game characters that are visually very realistic. At present, one sees much enthusiasm for giving the characters emotions through such devices as avatars and emoticons. However, in a freely changing environment of games, the devices merely allow for the expression of the value derived from a first input rather than creating expressions of emotion that actively respond to their surroundings. As such, there are as of yet no displays of deep emotions among game characters. In light of this, the present article proposes the 'CROSS(Character Reaction on Specific Situation) Model AE Engine' for game characters in order to develop characters that will actively express action and emotion within the environment of the changing face of games. This is accomplished by classifying the emotional components applicable to game characters based on the OCC model, which is one of the most well known cognitive psychological models. Then, the situation of game playing analysis of the commercialized RPG game is systematized by ontology.

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Icon Evaluation Using Spreading Activation Model (활성화 확산 모형을 이용한 아이콘 평가)

  • Lee, Sun-Jung;Myung, Ro-Hae
    • Journal of the Ergonomics Society of Korea
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    • v.26 no.4
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    • pp.135-142
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    • 2007
  • Icon conveys symbolic information which they have become ubiquitous as main element of GUI. However, users often cannot intuitively understand its functional meanings. Icon has to be designed for users to easily understand functional meanings. In order to evaluate icon, the spreading activation model can be used to effectively understand the process of information retrieval. In asymmetric spreading activation model is that in the two nodes the degree of spreading activation is different according to direction. Thus, asymmetric spreading activation theory was performed evaluating the strength of association when users see visual image to associate their verbal meaning (visual image - verbal meaning pair) and users see verbal meaning to associate their visual image (verbal meaning - visual image pair). According to the direction, this study hypothesizes that the well-designed icons have symmetric relationship rather than asymmetric relationship between the two pairs. The strength of association is measured through the reaction time and the accuracy rate. In performing SAT (spreading activation test), the ten icons were selected as word processing software icons. After first SAT, newly designed icons were developed based on Korean mental model, and second SAT was conducted using them. The results showed that the accuracy rate of newly designed icon has been improved. Also there is significant difference of reaction time between current icons and newly designed icons. Well-designed icon is confirmed that the strength of association relationship arises symmetrically rather than asymmetrically between the two pairs. User centered icons could be designed by improving the strength of association between the two pairs. Asymmetric SAT evaluates the strength of the association between the visual image and the verbal meanings to contribute to the development of icon which it related to human's association structure.

Investigation of NO Formation Characteristics in Multi Staged Air Combustor (공기 다단 연소기 화염의 NO 발생특성에 관한 연구)

  • Kim, Han-Seok;An, Guk-Yeong;Baek, Seung-Uk;Yu, Myeong-Jong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.25 no.11
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    • pp.1594-1605
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    • 2001
  • In this study, a numerical simulation was developed which was capable of predicting the characteristics of NO formation in pilot scale combustor adopting the air-staged burner flame. The numerical calculation was constructed by means of establishing the mathematical models fur turbulence, turbulent combustion, radiation and turbulent nitric oxide chemistry. Turbulence was solved with standard k-$\xi$ model and the turbulent combustion model was incorporated using a two step reaction scheme together with an eddy dissipation model. The radiative transfer equation was calculated by means of the discrete ordinates method with the weighted sum of gray gases model for CO$_2$and H$_2$O. In the NO chemistry model, the chemical reaction rates for thermal and prompt NO were statistically averaged using the $\beta$ probability density function. The results were validated by comparison with measurements. For the experiment, a 0.2 MW pilot multi-air staged burner has been designed and fabricated. Only when the radiation was taken into account, the predicted gas temperature was in good agreement with the experimental one, which meant that the inclusion of radiation was indispensable for modeling multi-air staged gas flame. This was also true of the prediction of the NO formation, since it heavily depended on temperature. Subsequently, it was found that the multi-air staged combustion technique might be used as a practical tool in reducing the NO formation by controlling the peak flame temperature.

Development of a Multi-zone Combustion Model for the Analysis of CAI Engines (CAI 엔진 해석을 위한 multi-zone 연소 모델의 개발)

  • Lee, Kyeong-Hyeon;Lim, Jae-Man;Kim, Young-Rae;Min, Kyoung-Doug
    • Transactions of the Korean Society of Automotive Engineers
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    • v.16 no.6
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    • pp.74-80
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    • 2008
  • A combustion of CAI engine is purely dominated by fuel chemical reactions. In order to simulate the combustion of CAI engine, it should be considered the effect of fuel components and chemical kinetics. So it needs enormous computational power. To overcome this problem reduced problem of needing massive computational power, chemical kinetic mechanism and multi-zone method is proposed here in this paper. A reduced chemical kinetic mechanism for a gasoline surrogate was used in this study for a CAI combustion. This gasoline surrogate was modeled as a blend of iso-octane, n-heptane, and toluene. For the analysis of CAI combustion, a multi-zone method as combustion model for a CAI engine was developed and incorporated into the computational fluid dynamics code, STAR-CD, for computing efficiency. This coupled multi-zone model can calculate 3 dimensional computational fluid dynamics and multi-zoned chemical reaction simultaneously in one time step. In other words, every computational cell interacts with the adjacent cells during the chemical reaction process. It can enhance the reality of multi-zone model. A greatly time-saving and yet still relatively accurate CAI combustion simulation model based on the above mentioned two efficient methodologies, is thus proposed.

Study on Anti-allergic Effects of Electroacupuncture in Allergic Mouse Model

  • Yoon Ji-Won;Jeong Kyoung-Ah;Cho Zang-Hee;Sung Kang-Keyng
    • Journal of Physiology & Pathology in Korean Medicine
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    • v.20 no.1
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    • pp.196-201
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    • 2006
  • Electroacupuncture(EA) is commonly used in various diseases. In the present study, the effect of EA in the allergic mouse model was examined. Allergy is generated via immunological mechanism and non-immunological mechanism. Mast cells activated dy those mechanisms get to release various substances such as histamine, leukotrienes, prostaglandin, TNF-$\alpha$, IL-4, IL-6, etc. which induce allergic reactions and the following inflammatory responses. To evaluate the anti-allergic effects of EA, mortality, ear swelling response, vascular permeability and cytokine secretion were investigated in EA group and non-EA group of which mice were compound 48/80-induced allergy model or PCA model. Compound 48/80 induces allergic reaction via non-immunological mechanism and PCA model is generated through the same mechanism with immediate-type(Type1) allergic reaction, one of immunological allergic reactions. EA inhibited compound 48/80-induced ear swelling response but did not inhibit the systemic anaphylaxis. EA also inhibited passive cutaneous anaphylaxis(PCA) activated dy anti-dinitrophenol IgE. In addition, EA inhibited IL-6 and TNF-$\alpha$ secretion from 48 h PCA in mice. These results indicate that EA may be used for the treatment of mast cell-mediated allergic diseases, especially immediate-type(Type 1) allergy and non-immunologically mediated allergy.

Characteristics of Cu and Cs Ions adsorbed on an immobilized Adsorbent including Zeolite Synthesized from Jeju Scoria (제주 스코리아로부터 합성한 제올라이트계 고정화 흡착제에 의한 Cu와 Cs 이온의 흡착 특성)

  • Lee, Chang-Han;Kam, Sang-Kyu;Lee, Min-Gyu
    • Journal of Environmental Science International
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    • v.28 no.1
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    • pp.55-64
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    • 2019
  • The adsorption properties of $Cs^+$ and $Cu^{2+}$ ions were evaluated by using a polysulfone scoria zeolite (PSf-SZ) composite with synthetic zeolite synthesized from Jeju volcanic rocks (scoria). In order to investigate the adsorption properties, various parameters, such as pH, contact time, reaction rate, concentration, and temperature in aqueous solutions, were evaluated by tests carried out in batch experiments. The adsorption capacities of $Cs^+$ and $Cu^{2+}$ ions increased between pH 2 but achieved equilibrium at pH 4 and above. The adsorption rate increased rapidly up to the initial 24 h, after which it plateaued ; the adsorption rate then sustained at equilibrium from 48 h. The adsorption kinetics of $Cs^+$ and $Cu^{2+}$ ions were described better by the pseudo-second-order kinetic model than the pseudo-first-order kinetic model. The Langmuir model fitted the adsorption isotherm data better than the Freundlich model. The maximum adsorption capacities of $Cs^+$ and $Cu^{2+}$ ions obtained from the Langmuir model were 53.8 mg/g and 84.7 mg/g, respectively. The calculated thermodynamic parameters showed that the adsorption of $Cs^+$ and $Cu^{2+}$ ions on PSf-SZ was feasible, spontaneous and endothermic reaction.

Model Test on Motion Responses and Anchor Reaction Forces of an Articulated Tower-Type Buoy Structure in Waves (아티큘레이티드 타워 형태의 부이 구조물에 관한 파랑 중 운동응답 및 앵커 지지력에 관한 모형시험 연구)

  • Kwon, Yong-Ju;Nam, Bo Woo;Kim, Nam Woo;Won, Young-Uk;Park, In-Bo;Kim, Sea-Moon
    • Journal of Ocean Engineering and Technology
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    • v.33 no.3
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    • pp.214-221
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    • 2019
  • A series of model tests was performed to evaluate the survivability of an articulated tower-type buoy structure under harsh environmental conditions. The buoy structure consisted of three long pipes, a buoyancy module, and top equipment. The scale model was made of acrylic pipe and plastic with a scale ratio of 1/22. The experiments were carried out at the ocean engineering basin of KRISO. The performance of the buoy structure was investigated under waves only and under combined environmental conditions from sea state (SS) 5 to 7. A nonlinear time-domain numerical simulation was conducted using the mooring analysis program OrcaFlex. The survivability of the buoy was analyzed based on three factors: the pitch motion, submergence of the top structure, and anchor reaction force. The model test results were directly compared to the results of numerical simulations. The effects of the sea state and combined environment on the performance of the buoy structure were investigated.

Analysis of NO Formation in Nonpremixed Hydrogen-Air Flames Considering Turbulence-Chemistry Interaction (난류연소 모델링을 이용한 수소-공기 비예혼합 화염의 NOx 생성 분석)

  • Park, Y.H.;Moon, H.J.;Kim, S.Y.;Yoon, Y.;Jeong, I.S.
    • 한국연소학회:학술대회논문집
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    • 1999.10a
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    • pp.71-79
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    • 1999
  • Numerical analysis on the characteristics of nitrogen oxides (NOx) formation in turbulent nonpremixed hydrogen-air flames was carried out. Lagrange IEM model and Assumed PDF model were applied to consider turbulence-chemistry interaction known to affect the production of NOx. Partial equilibrium assumption was used to predict nonequilibrium effect to which one-half power dependence between EINOx normalized by flame residence time and global strain rate is attributed. As a result. such one-half power dependence could be reproduced only by reaction model including $HO_{2}$and $H_{2}O_{2}$, which means its dependence on Damkohler number; nonequilibrium effect. This dependence was shown better in the region of higher global strain. Besides, the improvement of turbulence model is required to predict mean flow properties quantitatively in the radial direction.

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