• Title/Summary/Keyword: Reaction facilities

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A versatile small-scale structural laboratory for novel experimental earthquake engineering

  • Chen, Pei-Ching;Ting, Guan-Chung;Li, Chao-Hsien
    • Earthquakes and Structures
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    • v.18 no.3
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    • pp.337-348
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    • 2020
  • Experimental testing has been considered as one of the most straightforward approaches to realize the structural behavior for earthquake engineering studies. Recently, novel and advanced experimental techniques, which combine numerical simulation with experimental testing, have been developed and applied to structural testing practically. However, researchers have to take the risk of damaging specimens or facilities during the process of developing and validating new experimental methods. In view of this, a small-scale structural laboratory has been designed and constructed in order to verify the effectiveness of newly developed experimental technique before it is applied to large-scale testing for safety concerns in this paper. Two orthogonal steel reaction walls and one steel T-slotted reaction floor are designed and analyzed. Accordingly, a large variety of experimental setups can be completed by installing servo-hydraulic actuators and fixtures depending on different research purposes. Meanwhile, a state-of-the-art digital controller and multiple real-time computation machines are allocated. The integration of hardware and software interfaces provides the feasibility and flexibility of developing novel experimental methods that used to be difficult to complete in conventional structural laboratories. A simple experimental demonstration is presented which utilizes part of the hardware and software in the small-scale structural laboratory. Finally, experimental layouts of future potential development and application are addressed and discussed, providing the practitioners with valuable reference for experimental earthquake engineering.

Reverse Transcription Polymerase Chain Reaction-based System for Simultaneous Detection of Multiple Lily-infecting Viruses

  • Kwon, Ji Yeon;Ryu, Ki Hyun;Choi, Sun Hee
    • The Plant Pathology Journal
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    • v.29 no.3
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    • pp.338-343
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    • 2013
  • A detection system based on a multiplex reverse transcription (RT) polymerase chain reaction (PCR) was developed to simultaneously identify multiple viruses in the lily plant. The most common viruses infecting lily plants are the cucumber mosaic virus (CMV), lily mottle virus (LMoV), lily symptomless virus (LSV). Leaf samples were collected at lily-cultivation facilities located in the Kangwon province of Korea and used to evaluate the detection system. Simplex and multiplex RT-PCR were performed using virus-specific primers to detect single- or mixed viral infections in lily plants. Our results demonstrate the selective detection of 3 different viruses (CMV, LMoV and LSV) by using specific primers as well as the potential of simultaneously detecting 2 or 3 different viruses in lily plants with mixed infections. Three sets of primers for each target virus, and one set of internal control primers were used to evaluate the detection system for efficiency, reliability, and reproducibility.

A Study on the Corrosion Inhibition Effects of Sodium Heptanoate for Carbon Steel in Aqueous Solution

  • Won, D.S.;Kho, Y.T.
    • Corrosion Science and Technology
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    • v.3 no.6
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    • pp.227-232
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    • 2004
  • The carboxylates as a corrosion inhibitor has been studied by many researchers because of its environmental safety and low depletion rate. However, conventional test methods of inhibitor such as weight loss measurements, linear polarization resistance and corrosion potential monitoring etc., evaluate uniform corrosion of metals. These methods are unable to evaluate crevice-related corrosions, which are encountered in most of heat exchanging facilities. In order to choose the optimum corrosion inhibitor, the appropriate test methods are required to evaluate their performances in service environment. From this point of view, polarization technique was used to evaluate the characteristics of sodium heptanoate on corrosion behavior for carbon steel. Especially a thin film crevice sensor technique were applied to simulate the crevice corrosion in this study. From these experiments, we found that oxygen as an oxidizing agent was required to obtain stable passive film on the metal. Presence of oxygen, however, accelerated crevice corrosion. Potential shift by oxygen depletion and weakened inhibitive film inside the crevice were responsible for such accelerated feature. It is shown that film for corrosion inhibition is a mixture of sodium heptanoate and iron (II) heptanoate as reaction product of iron surface and sodium heptanoate. The iron (II) heptanoate which has been synthesized by reaction of heptanoic acid and ferrous chloride in methanol solution forms bidentate complex.

Loess and Lime Treatment for Modification of Waterworks Sludges (황토와 석회의 혼합처리에 의한 정수 슬러지의 개질화에 관한 연구)

  • Lim, Sung-Jin;Cho, Jae-Jun;Lee, Jae-Bok
    • Journal of Korean Society of Water and Wastewater
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    • v.14 no.4
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    • pp.318-327
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    • 2000
  • Sludge production from water treatment plants is increasing each year because water resources deterioration is proceeding and water supply facilities are growing due to water demand increase. Water treatment plant sludges can be modified to soil cover in sanitary landfilling site through the lime treatment and other alternatives. The compression strength of $1.0kg/cm^2$ is necessary for the dozer operation on soft son cover material at municipal landfilling site. Modified sludge was experimentally produced in this study with lime, bentonite, loess, and activated loess dosing. X-ray diffraction patterns of the limed water treatment plant sludge confirmed the presence of calcium carbonate and ettringite. Unconfined compression strength properties of modified sludges showed material property improvement applicable for soil cover alternatives. When adding 20-30% activated loess to water treatment plant sludges. the modified sludges could reach the compression strength for cover soil after 7 days solidification reaction, but decrease of compression strength was intentioned in 28 days reaction period. Solidification effect of the modified sludge with activated loess was observed through the scanning electron microscope.

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High-valence Mo doping for promoted water splitting of Ni layered double hydroxide microcrystals

  • Kyoungwon Cho;Seungwon Jeong;Je Hong Park;Si Beom Yu;Byeong Jun Kim;Jeong Ho Ryu
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.33 no.2
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    • pp.78-82
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    • 2023
  • The oxygen evolution reaction (OER) is the primary challenge in renewable energy storage technologies, specifically electrochemical water splitting for hydrogen generation. We report effects of Mo doping into Ni layered double hydroxide (Ni-LDH) microcrystal on electrocatalytic activities. In this study, Mo doped Ni-LDH were grown on three-dimensional porous nicekl foam (NF) by a facile solvothermal method. Homogeneous LDH structure on the NF was clearly observed. However, the surface microstructure of the nickel foam began to be irregular and collapsed when Mo precursor is doped. Electrocatalytic OER properties were analyzed by Linear sweep voltammetry (LSV) and Electrochemical impedance spectroscopy (EIS). The amount of Mo doping used in the electrocatalytic reaction was found to play a crucial role in improving catalytic activity. The optimum Mo amount introduced into the Ni LDH was discussed with respect to their OER performance.

A Study on the Development of Self-Checklists for Small and Medium-Sized Chemical Industries (중소규모 화학업종을 위한 자율점검표 개발 연구)

  • Woo Sub Shim;Kyeong-Seok Oh
    • Journal of the Korean Society of Industry Convergence
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    • v.26 no.5
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    • pp.757-763
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    • 2023
  • Major industrial accidents in which workers die due to fires or explosions while working at chemical substance handling workplaces continue to occur. Among the major industrial accidents that occurred between 2005 and 2021, the accident status by work situation and equipment was analyzed. Through analysis, it was confirmed that storage, reaction, and piping facilities were the main causes of the accident, and a self-checklist for each facility was developed. Verification was conducted through the supply and use groups to evaluate the suitability of the use, duties, and items of the self-checklist. The user group showed higher satisfaction than the supplier group for all three suitability of use, job, and item. In particular, since the inspection items of the self-checklist were organized around the cause of the accident derived through the analysis of actual accident cases, the satisfaction level was high in all groups. It is expected that the self-checklist developed through this study will be useful not only for large companies but also for small and medium-sized chemical industries that lack professional manpower.

A Study on Plasma Etching Reaction of Cobalt for Metallic Surface Decontamination (금속 표면 제염을 위한 코발트의 플라즈마 식각 반응 연구)

  • Jeon, Sang-Hwan;Kim, Yong-Soo
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.6 no.1
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    • pp.17-23
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    • 2008
  • In this study, plasma processing of metal surface is experimentally investigated to enhance the surface decontamination efficiency and to find out the reaction mechanism. Cobalt, the major contaminant in the nuclear facilities, and three fluorine-containing gases, $CF_4/O_2$, $SF_6/O_2$, and $NF_3$ are chosen for the investigation. Thin metallic disk specimens are prepared and their surface etching reactions with the three plasma gases are examined. Results show that the maximum etching rate of $17.2\;{\mu}m/min.$ is obtained with NF3 gas at $420^{\circ}C$, while with $CF_4/O_2$, $SF_6/O_2$ gas plasmas those of $2.56\;{\mu}m/min.$ and $1.14\;{\mu}m/min.$ are obtained, respectively. Along with etching experiments, constituent elements of the reaction products are identified to be cobalt, oxygen, and fluorine by AES (Auger Electron Spectroscopy) analysis. It turns out that the oxygen atoms are physically adsorbed ones to the surface from the ambient not participation ones during the analysis after reaction, which supports that the surface reaction of cobalt is mainly to be a fluorination reaction.

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Study on the Desulfurization Characteristic of Limestone Depending on the Operating Parameters of In-Furnace Desulfurization for Oxy-Fuel Combustion Using Drop Tube Furnace (순산소연소 조건에서 Drop tube furnace를 이용한 운전변수에 따른 석회석의 탈황특성 연구)

  • Choi, Wook;Jo, Hang-Dae;Choi, Won-Kil;Park, Yeong-Sung;Keel, Sang-In;Lee, Hyung-Keun
    • Korean Chemical Engineering Research
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    • v.49 no.6
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    • pp.857-864
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    • 2011
  • Oxy-fuel combustion with many advantages such as high combustion efficiency, low flue gas flow rate and low NOx emission has emerged as a promising CCS technology for coal combustion facilities. In this study, the effects of the direct sulfation reaction on $SO_2$ removal efficiency were evaluated in a drop tube furnace under typical oxy-fuel combustion conditions represented by high concentrations of $CO_2$ and $SO_2$ formed by gas recirculation to control furnace combustion temperature. The effects of the operating parameters including the reaction temperature, $CO_2$ concentration, $SO_2$ concentration, Ca/S ratio and humidity on $SO_2$ removal efficiency were investigated experimentally. $SO_2$ removal efficiency increased with reaction temperature up to 1,200 due to promoted calcination of limestone reagent particles. And $SO_2$ removal efficiency increased with $SO_2$ concentrations and the humidity of the bulk gas. The increase of $SO_2$ removal efficiency with $CO_2$ concentrations showed that $SO_2$ removal by limestone was mainly done by the direct sulfation reaction under oxy-fuel combustion conditions. From the impact assessment of operation parameters, it was shown that these parameters have an effects on the desulfurization reaction by the order of the Ca/S ratio > residence time > $O_2$ concentration > reaction temperature > $SO_2$ concentration > $CO_2$ concentration > water vapor. The semi-empirical model equation for to evaluate the effect of the operating parameters on the performance of in-furnace desulfurization for oxy-fuel combustion was established.

Implementation of Film Type Sensor for Synthetic Lube Oil and High Pressure Hydraulic Fluid Leak Detection (합성 윤활유 및 고압 작동유 누출감지 필름형 센서의 구현)

  • Park, No-Jin;Yu, Dong-Kuen;Yu, Hong-Kuen
    • Journal of Sensor Science and Technology
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    • v.23 no.4
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    • pp.266-271
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    • 2014
  • Chemical sensors are used in various industrial facilities such high-risk and prevent the leakage of substances, important in life and environmental protection and the safe use of industry, used for management. In particular, high-temperature environments such as power generation equipment of the rotating part due to leakage generated by the various oil, power plants Shut Down, fire, work environment (exposure to various chemical solution and gas leak) and various water, air and soil pollution causes. Thus, over the long term through various channels such as crops and groundwater contamination caused by the slow, serious adverse effect on the ecosystem. In this paper, synthetic lube oil and high pressure hydraulic fluid leakage and immediately detect a new Printed Electronic implementation of technology-based film-type sensors, and its performance test. Thus, industrial accidents and environmental pollution and for early detection of problems, large accidents can be prevented. Experimental results of the synthetic lube oil and high pressure hydraulic fluid solution after the contact time depending on the experiment and the oil solution of the sensor material of the conductive porous PE resistance value by a chemical reaction could be confirmed that rapid increase. Also implemented in the film-type oil sensor electrical resistance change over time of the reaction rate and the synthetic lube oil is about 2 minutes or less, the high pressure hydraulic fluid is less than about 1 minute was. Therefore, more high-pressure hydraulic fluid such as a low volatility synthetic lube oils are the resistance change and the reaction rate was confirmed to be the slowest.

Energy conversion of petroleum coke : CO2 gasification (석유 코크스의 에너지 전환 : CO2 가스화)

  • Kook, Jin-Woo;Gwak, In-Seop;Lee, See-Hoon
    • 한국연소학회:학술대회논문집
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    • 2014.11a
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    • pp.255-257
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    • 2014
  • The installation of light oil facilities or delayed cokers seems to be inevitable in the oil refinery industry due to the heavy crude oil reserves and the increased use of light fuels as petroleum products. Petroleum coke is a byproduct of oil refineries and it has higher fixed carbon content, higher calorific value, and lower ash content than coal. However, its sulfur content and heavy metal content are higher than coal. In spite of disadvantages, petroleum coke might be one of promising resources due to gasification processes. The gasification of petroleum coke can improve economic value of oil refinery industries by handling cheap, toxic wastes in an environment-friendly way. In this study, $CO_2$ gasification reaction kinetics of petroleum coke, various coals and mixing coal with petroleum coke have investigated and been compared by using TGA. The kinetics of $CO_2$ gasification has been performed with petroleum coke, 3 kinds of bituminous coal [BENGALLA, White Haven, TALDINSKY], and 3 kinds of sub-bituminous coal [KPU, LG, MSJ] at various temperature[$1100-1400^{\circ}C$].

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