• Title/Summary/Keyword: Reaction experiment

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Hydrogen Production by the Reaction of Al and Alkaline Solution for PEMFC Application (알루미늄 알칼리용해에 의한 PEMFC용 수소 생성)

  • Sim, Woo-Jong;Na, Il-Chal;Song, Myung-Hyun;Chung, Hoi-Bum;Kim, Jeong-Ho;Kim, Tae-Hee;Park, Kwon-Pil
    • Journal of Hydrogen and New Energy
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    • v.20 no.1
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    • pp.1-8
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    • 2009
  • Hydrogen production by the reaction of aluminum alloys and NaOH solution was studied for an automotive proton exchange membrane fuel cell(PEMFC) application. In our experiment conditions($30{\sim}75^{\circ}C$, NaOH $0.5{\sim}5M$), passivation of aluminum was not occurred. Higher rate of hydrogen production was observed at the reaction with Al alloys that contain impurities. With an increase in reaction temperature, hydrogen production rate by an increase in NaOH concentration increased much. When hydrogen was fed into the anode without filtering, PEMFC cell performance decreased 35% by ionic contamination such as $Na^+$ on the membrane and electrode. Thus, filtering of produced hydrogen is necessary for PEMFC operation.

A TISSUE RESPONSE TO THE TITANIUM ALLOY (Ti-13Zr-6Nb) IN VIVO

  • Kim Chang-Su;Lee Seok-Hyung;Shin Sang-Wan;Suh Kyu-Won;Ryu Jae-Jun
    • The Journal of Korean Academy of Prosthodontics
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    • v.42 no.6
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    • pp.619-627
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    • 2004
  • Statement of problem. Mechanisms of tissue-implant interaction and the effect of the implant surface on the behavior of cells has not yet been clarified. Purpose. This study was performed to investigate the tissue reaction to the titanium alloy submerged into rat peritoneum in vivo. Materials and methods. Titanium alloys (titanium-13Zirconium-6Niobium) were inserted inside the peritoneal cavity of Sprague Dawley rats. After 3 months, the tissue formed around the inserted titanium alloys were examined with a light-microscope. Tissue reaction around the material was analyzed by confocal microscopy to evaluate their biocompatibility in a living body. Results. In in vivo study, foreign body type multinucleated giant cells were found in the fibrous tissue formed as a reaction to the foreign material (4 in 20 cases), but the inflammatory reaction was very weak. After experiment, the contaminants of biomaterials was removed from living tissue. In confocal microscopy, we observed that the staining of vinculin and actin showed mixed appearance. In a few cases, we found that the staining of vinculin and beta-catenin showed the prominent appearance. Conclusion. We found that titanium-13Zirconium-6Niobium alloy was an excellent biomaterial.

Production of Titanium Powder by Electronically Mediated Reaction (EMR) (도전체 매개반응(EMR)법에 의한 Ti 분말 제조)

  • Park Il;Chu Yong Ho;Lee Chul Ro;Lee Oh Yeon
    • Korean Journal of Materials Research
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    • v.14 no.12
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    • pp.857-862
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    • 2004
  • Production of titanium powder directly from tantalum oxides ($TiO_2$) pellet through an electronically mediated reaction (EMR) by calciothermic reduction has been investigated. Feed material ($TiO_2\;pellet$) and reductant (Ca-Ni alloy) were charged into electronically isolated locations in a molten calcium chloride ($CaCl_2$) bath at $950^{\circ}C$. The current flow through an external circuit between the feed (cathode) and reductant (anode) locations was monitored during the reduction of $TiO_2$. The current approximately 3.2A was measured during the reaction in the external circuit connecting cathode and anode location. After the reduction experiment, pure titanium powder with low nickel content was obtained even though Ca-Ni alloy was used as a reductant. These results demonstrate that titanium powder can be produced without direct physical contact between the feed and reductant. In certain experimental conditions, pure titanium powder with approximately $99.5\;mass\%$ purity was successfully obtained.

Ground Reaction Force and Foot Pressure Analysis During Golf Iron Swing by Gender (골프 아이언 스윙 시 성별에 따른 지면반력 및 족저압력 분석)

  • Park, Jae-Young
    • Korean Journal of Applied Biomechanics
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    • v.20 no.2
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    • pp.167-174
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    • 2010
  • This study aims to quantitatively compare and analyze kinetic variables in the motion of male and female professional golfers to suggest basic scientific materials for golf iron swing. Five male and five female professional golfers participated in this experiment. Ground reaction force and foot pressure were measured during performing 10 swings for each participants using an iron club. The result of the ground reaction force indicates that the force occurs at the left foot toward right(-) direction in the mid-downswing(E3) and impact(E4) events in X-axis, while it occurs at the right foot toward anterior(-) direction in Y-axis for both male and female, showing a big difference between them. Also, in Z-axis, large force occurs at the left foot in most events. The analyzed result on foot pressure indicates that men have the highest pressure and area at the left foot, and women have the highest ones at the right foot in the mid-downswing(E3) and impact(E4) events in the max foot pressure, ground contact area and average pressure. It is considered that there is difference of central movement methods between men and women. Thus, different education and training on golf swing should be necessary by gender due to their different patterns of golf iron swing.

Meteorological Response against Yield and Yield Component of Rice in Chungnam and Daejeon Area (충남지역에서 기상요소가 벼의 수량과 수량구성요소에 미치는 영향)

  • An, Jong-Beom;Cho, Jin-Woong
    • Korean Journal of Agricultural Science
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    • v.37 no.2
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    • pp.177-189
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    • 2010
  • These studies were conducted to analysis for weather reaction on the growth and yield component according to meterological elements used Vector Autoregressive Regression(VAR) Model at Daejeon, Hongseong, Geumsan, Nonsan, and Yesan to core of center to Chungnam area in Rice. Reaction of cultivars according to change of meterological elements for growth and yield component effected on heading time in Gancheokbyeo and Mananbyeo, grain number of a spike in Gancheokbyeo, ratio of ripeness in Gancheokbyeo and Geumobyeo 1, amount of milled rice in Geurubyeo and Ansanbyeo, and 1,000 grains weight in Gancheokbyeo, Dasanbyeo, and Hwajinbyeo. An effect on the growth and yield components of meterological elements were influenced by heading date, 1,000 grain weight and ratio of repening as sunshine hours. The cultivars in sensitive reaction for change of weather condition were classified to 14 varieties including Gerubyeo et al., insensitive cultivars were classified to 66 varieties including Gyehwabyeo et. al.

Preparation of Magnetite Nanoparticles by Two Step Reaction (2단계 반응에 의한 마그네타이트 나노입자의 제조)

  • Shin, Dae-Kyu;Riu, Doh-Hyung
    • Journal of Powder Materials
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    • v.15 no.2
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    • pp.148-155
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    • 2008
  • Nano magnetite particles have been prepared by two step reaction consisting of urea hydrolysis and ammonia addition at certain ranges of pH. Three different concentrations of aqueous solution of ferric ($Fe^{3+}$) and ferrous ($Fe^{2+}$) chloride (0.3 M-0.6 M, and 0.9 M) were mixed with 4 M urea solution and heated to induce the urea hydrolysis. Upon reaching at a certain pre-determined pH (around 4.7), 1 M ammonia solution were poured into the heated reaction vessels. In order to understand the relationship between the concentration of the starting solution and the final size of magnetite, in-situ pH measurements and quenching experiments were simultaneous conducted. The changes in the concentration of starting solution resulted in the difference of the threshold time for pH uprise, from I hour to 3 hours, during which the akaganeite (${\beta}$-FeOOH) particles nucleated and grew. Through the quenching experiment, it was confirmed that controlling the size of ${\beta}$-FeOOH and the attaining a proper driving force for the reaction of ${\beta}$-FeOOH and $Fe^{2+}$ ion to give $Fe_3O_4$ are important process variables for the synthesis of uniform magnetite nanoparticles.

SPO based Reaction Force Estimation and Force Reflection Bilateral Control of Cylinder for Tele-Dismantling (원격해체 작업을 위한 유압 시스템의 SPO 기반 반력 추정 및 힘 반향 양방향 원격제어)

  • Cha, Keum-Gang;Yoon, Sung Min;Lee, Min Cheol
    • The Journal of Korea Robotics Society
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    • v.12 no.1
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    • pp.1-10
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    • 2017
  • For dismantling heavy structure under special environment in radioactivity, there are many problems which should be tele-operated and feedback a cutting force for cutting a thick structure such as concrete. When operator dismantles a thick heavy concrete structure, it is in sufficient to judge whether robot is contacting or not with environment by using only vision information. To overcome this problem, force feedback and impedance model based bilateral control are introduced. The sliding mode control with sliding perturbation observer (SMCSPO) based bilateral control is applied and surveyed to a single rod hydraulic cylinder in this paper. The sliding mode control is used for robustness against a disturbance. The sliding perturbation observer is used for estimation of a reaction force such as cutting force. The bilateral control is executed using the information of reaction force estimated by SMCSPO. The contribution of this paper is that the estimation method and bilateral control of the single rod hydraulic cylinder are introduced and discussed by experiment.

Hydrogen production by catalytic decomposition of propane over carbon black catalyst in a fluidized bed (유동층 반응기에서 카본블랙 촉매를 이용한 프로판의 촉매 분해에 의한 수소생산 연구)

  • Jung, Jae-Uk;Nam, Woo-Seok;Yoon, Ki-June;Lee, Dong-Hyun;Han, Gui-Young
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.06a
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    • pp.85-88
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    • 2006
  • A fluidized bed reactor made of quartz with 0.055m I.D. and 1.0m in height was employed for the thermocatalytic decomposition of propane to produce $CO_2$-free hydrogen. The fluidized bed was proposed for the continuous withdraw of product carbons from the reactor. The propane decomposition rate used carbon black N33O as a catalyst. The propane decomposition reaction was carried out at the temperature range of $600{\sim}800^{\circ}C$, paropane gas velocity of $1.0 U_{mf}\;3.0U_{mf}$ and the operating pressure of 1.0 atm. Effect of operating parameters such as reaction temperature, gas velocity on the reaction rates was investigated. The carbon which was by-product of methane decomposition reaction was deposited on the catalyst surface that was observed by SEM. Resulting production in our experiment were not only hydrogen but also several by products such as methane, ethylene, ethane, and propylene.

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Effects of Additional Bubbling on RH Vacuum Degassing Process with Water Model Experiment (수모델을 사용한 RH 진공 탈가스장치에서의 추가 버블링 효과)

  • Jang, Young-Hwan;Kim, Young-Tae;Yi, Kyung-Woo
    • Korean Journal of Metals and Materials
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    • v.48 no.5
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    • pp.424-429
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    • 2010
  • In the RH process, it is possible to obtain quicker processing times by enhancing the decarburization rates at a low carbon range of steel melt through Ar gas injection into the vacuum vessel. The RH decarburization reaction was simulated through a dissolved oxygen removal reaction by injecting nitrogen into a 1/8 scale RH water model system. The gas nozzles for the N$_{2}$ injection into the vacuum vessel were located at the lowest level of the vessel's outer wall. The nitrogen bubbling in the vacuum vessel resulted in an increase in the reaction rate constant, which rose in accordance with an increase in the bubbling flow rate and number of nozzles used. However, there was almost no variation in the reaction rate constant, which depended on the horizontal positions of the bubbling nozzles.

Anti-cancer Effects of Cultivated Wild Ginseng Herbal Acupuncture in C57BL/6 Mice Injected with B16/F10 Cells and Reproductive Toxicity by Doxorubicin (B16/F10세포를 이식한 C57BL/6 생쥐에서 산삼약침의 항암효과 및 Doxorubicin에 의한 생식독성 완화효과)

  • Yoon, Hye-Chul;Kim, Ho-Hyun;Kwon, Ki-Rok
    • Journal of Acupuncture Research
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    • v.23 no.1
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    • pp.105-120
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    • 2006
  • To investigate anti-cancer effects of wild ginseng herbal acupuncture and mitigation of anti-cancer drug when taken concurrently, cancer cells from B16/F10 melanoma were injected intraperitoneally in C57BL/6. After inducing cancer, anti-cancer effects and mitigation of reproductive toxicity of Doxorubicin were evaluated. 1. For changes in weight, Doxorubicin treated group showed significant decrease, and administration of wild ginseng herbal acupuncture didn't cause any weight change. 2. Volume of tumor was significantly reduced in Doxorubicin teated group. Wild ginseng herbal acupuncture groups showed slight decrease but insignificant compared to the control group. 3. For hematological evaluation, Doxorubicin only group's reticulocytes were significantly decreased compared to the control group, and Platelet Count was significantly increased. Wild ginseng herbal acupuncture group showed significant increase of Neutrophils and significant decrease of Lymphocytes compared to the control group. 4. For histological evaluation of the tumor, necrosis occurred in a wide range in the Doxorubicin treated group. Wild ginseng herbal acupuncture didn't cause much histological changes. 5. For histological evaluation of the testis, seminiferous tubules of the control group suffered severe damage on epithelial cells. When wild ginseng herbal acupuncture was administered concurrently, damage on the seminiferous tubules was significantly inhibited compared to the Doxorubicin only group. 6. Diameter of seminiferous tubules and spermatogonia count were insignificant between the experiment groups. 7. For BrdU positive reaction of testicle tissue, Doxorubicin only group failed to show any reaction of spermatogonia, but spermatocytes and spermatids showed slight positive reaction. When wild ginseng herbal acupuncture was treated concurrently, much greater positive reaction was made but similar to that of the control and normal groups. 8. For observation of changes in BrdU spermatogonia count of the testicle tissue, Doxorubicin only group didn't show any positive reaction, and relative increase was shown in the group with concurrent administration of wild ginseng herbal acupuncture. 9. For observation of TUNEL positive reaction cells of the testicle tissue, no significant changes were witnessed in all the experiment groups.

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