• Title/Summary/Keyword: Reaction Time Analysis

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Development of an Immunosensor to Detect Rat IgG Using Impedance Analyser

  • No D. H.;Kang S.;Kim G. Y.;Chung S. H.;Park Y. H.;Om A. S.;Cho S. I.
    • Agricultural and Biosystems Engineering
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    • v.5 no.1
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    • pp.21-24
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    • 2004
  • Antibody based biosensors are very selective and ultra-sensitive. Antigen-antibody reactions have been used in immunoassays. In this research, a biosensor which uses antigen-antibody reaction was developed to measure and detect rat IgG. Because the antigen-antibody reaction is a physical bounding between antigen and antibody, there are several ways to measure an antigen-antibody reaction. Among the methods, impedance analysis has short measuring time and possibilities of analyzing various properties of the reaction using frequency analysis. Rat IgG could be detected with developed biosensor and impedance analyzer. The biosensor showed good repeatability and availability of detecting concentration changes of rat IgG.

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A Study on the Vulcanization Reaction of Modified NR Blends by In-Situ Electrical Property Measurement (전기적 특성의 in-situ 측정에 의한 개질된 NR 블랜드의 가황 반응에 관한 연구)

  • Ha, Ki-Ryong;Suh, Soong-Hyuck;Rho, Seung-Baik;Lee, Seung-Hyun;Ahn, Won-Sool
    • Elastomers and Composites
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    • v.38 no.3
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    • pp.235-242
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    • 2003
  • A vulcanization reaction characteristics of an isoprene rubber (IR)-modified natural rubber/carbon black (NR/CB) composite was studied using in-situ electrical property measuring technique. Since the electrical conductivity of the sample composite would be changed continuously during the vulcanization reaction by rearranging of the carbon black particles within the sample, volume resistivity (${\rho}$) might be obtained as a function or reaction time. A stabilization time ($t_i$), maximum reaction speed time ($t_p$), and volume resistivity at that time(${\rho}_p$) were defined from the data for the Arrhenius analysis. Volume resistivity ${\rho}$ showed a comparatively high value of ${\sim}10^8$ order before the reaction started, and dramatically decreased to be stabilized within $1{\sim}2$ minutes as soon as the reaction started. As the more time elapsed, thereafter, ${\rho}$ decreased monotonously to a certain constant value through a peak, ${\rho}_p$ at time $t_p$, which was considered as the maximum reaction rate. As a result, while $t_i$ values were comparatively constant as $1{\sim}2$ minutes, $t_p$ values showed to become shorter and shorter as the reaction temperature.

Analysis of Variability for the Components of VGRF Signal via Increasing the Number of Attempt during Running (달리기 시도 수 증가에 따른 VGRF 신호 성분의 Variability 분석)

  • Ryu, Ji-Seon
    • Korean Journal of Applied Biomechanics
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    • v.17 no.1
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    • pp.129-134
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    • 2007
  • The purpose of this study was to determine the variability of components of the vertical ground reaction force signal to seek the suitable number of attempt datum to be analyzed during running at 2m/s and 4m/s. For this study, six subjects (height mean:$174.5{\pm}4.4cm$, weight $671.5{\pm}116.4N.$, age:$25.0{\pm}yrs.$) were selected and asked to run at least 3 times each run condition randomly. FFT(fast Fourier transform) was used to analyze the frequency domain analysis of the vertical ground reaction forces signal and an accumulated PSD (power spectrum density) was calculated to reconstruct the certain signal. To examine the deviation of the vertical ground reaction between signals collected from an different number of attempt, variability of frequency, magnitude of passive peak, time up to the passive peak and maximum load rate were determined in a coefficient of variance. The variability analysis revealed that when analyze the vertical reaction force components at 2m/s speed running, which belongs to slow pace relatively, it would be good to calculate these components from signal of one attempt, but 4m/s speed running needs data collected from two attempts to decrease the deviation of signal between attempts. In summary, when analyzing the frequency and passive peak of the vertical reaction force signal during the fast run, it should be considered the number of attempt.

Changes of Cortical Activation Pattern Induced by Motor Learning with Serial Reaction Time Task (시열반응과제의 운동학습이 대뇌피질 활성화의 변화에 미치는 영향)

  • Kwon, Yong-Hyun;Chang, Jong-Sung;Kim, Chung-Sun
    • The Journal of Korean Physical Therapy
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    • v.21 no.1
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    • pp.65-71
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    • 2009
  • Purpose: Numerous investigators demonstrated that adaptative changes were induced by motor skill acquisition in the central nervous system. We investigated the changes of neuroelectric potential following motor learning with serial reaction time task in young healthy subjects, using electroencephalography (EEG). Methods: Twelve right-handed normal volunteers were recruited, who have no history of neurological dysfunction and were given to written the informed consent. All subjects were assigned to flex to extend the wrist joint or flex the thumb for pressing the matched button as quickly and accurately as possible, when one of five colored lights was displayed on computer screen (red, yellow, green, blue, white). EEG was measured, whenfive types simulations ware presented randomly with equal probabilities of 20% in total 200 times at the pre and post test. And they were scheduled for 30 minutes practice session during two consecutive days in the laboratory. Results: The results showed that the reaction time at the post test was significantly reduced, compared to one of the pre test in serial reaction time task. In EEG map analysis, the broaden bilateral activation tended to be changed to the focused contralateral activation in the frontoparietal area. Conclusion: These findings showed that acquisition of motor skill led to product more fast motor execution, and that motor learning could change cortical activation pattern, from the broaden bilateral activation to the focused contralateral activation. Thus we concluded that the adaptative change was induced by motor learning in healthy subjects.

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Analysis of Temperature Rise and Operation Time of Differential Spot Type Detector in Case of Mattress Fire in Multi-family House (다가구 주택의 매트리스 화재 시 차동식 스포트형 감지기의 온도상승 및 동작시간 분석)

  • Kim, Seo-Young;Kong, Ha-Sung
    • Journal of the Korea Safety Management & Science
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    • v.23 no.3
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    • pp.97-102
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    • 2021
  • This study developed a scenario to understand the reaction rate and operational time according to RTI value of rate of rise detector in each type in case of fire mattress. In the results of analyzing the reaction rate and operational time of detector in each scenario, in case when installing a single detector, the elevated temperature per minute was raised to 8℃/min ~ 9℃/min. In case when installing two detectors, it was raised to 9℃/min ~ 10℃/min. In case when installing three detectors, it was raised to 10℃/min. The horizontal distance between detector and mattress was 1.8m~2.5m. Whenever the number of detectors was increased, the horizontal distance was decreased. The operational time of detector was within maximum 540 seconds and minimum 420 seconds. As the research tasks in the future, there should be the researches on the effects of reaction rate of detector on the evacuation in case of fire through the result value of RSET by setting up the latency until the detector operates, and the researches on the safety by understanding if the operational time of detector is suitable for the evaluation standard of performance-centered design.

Application of a Gas Chromatography/Mass Spectrometric Method for the Determination of Butyltin Compounds in Sediment

  • Won, Yong-Il;Jung, Pyong-Gil;Chung, Min-Young;Kim, Byung-Joo;Yim, Yong-Heon;So, Hun-Young;Kim, Yong-Seong
    • Bulletin of the Korean Chemical Society
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    • v.25 no.10
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    • pp.1508-1512
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    • 2004
  • A gas chromatography/mass spectrometric (GC/MS) method has been developed for the determination of trace mono-n-butyltin (MBT), di-n-butyltin (DBT), and tri-n-butyltin (TBT) compounds in sediments. Samples were extracted by 10% acetic acid in methanol containing 0.03% tropolone and were then derivatized for GC/MS analysis. Ethylation by sodium tetraethylborate and phenylation by sodium tetraphenylborate were evaluated as a derivatization reaction of the organotins in sample extract. n-Hexane was added into reaction media in the beginning of the reaction for the continuous extraction of derivatized organotins. Ethylation requires less than 2 hours to get proper derivatization yields for MBT, DBT, and TBT altogether and produces relatively low amounts of side reaction products. Compared to ethylation, phenylation requires much longer time but provides relatively lower yield and produces considerable amounts of side reaction products. Therefore, the ethylation reaction was applied for the analysis of organotin compounds in sediment. An isotope dilution mass spectrometric (IDMS) method based on GC/MS has been applied to the accurate determination of DBT compounds in the sediments. The IDMS results from the analyses of sediment samples showed a reasonable repeatability and a good agreement with the values obtained by IDMS based on liquid chromatography/induced coupled plasma/mass spectrometry.

Numerical Prediction of NOx in the Nonpremixed Hydrogen-Air Flame using the Quasi-Laminar Reaction Modelling (준충류 근사를 이용한 수소-공기 비예혼합화염의 질소산화물 생성예측)

  • Kim, Seong-Lyong;Jeung, In-Seuck;Yoon, Young-Bin
    • Journal of the Korean Society of Combustion
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    • v.4 no.1
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    • pp.131-139
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    • 1999
  • A Numerical Analysis of NOx production in Hydrogen-Air flame is performed using the quasi-laminar reaction modelling. As results, in low global strain rate region, $U_F/D_F\;{\leq}\;50,000$, the quasi-laminar reaction modelling reproduces the experimentally observed EINOx half power scaling that the ratio of EINOx and flame residence time, $L_f^3(D_F^2U_F)$, is proportional to the square root of global strain rate. Thus, it suggests that turbulence-chemistry interaction has a minor impact on the trend of NOx production in low global strain rate region. However, the quasi-laminar reaction modelling predicts the higher temperature and NOx than experimentally observed. This overprediction may be due to the lack of radiation and quasi-laminar reaction modelling.

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Analysis of Oscillation Behaviour in Unsteady Shock-Induced Combustion with Detailed Reaction Mechanisms

  • Kumar, P.Pradeep;Kim, Kui-Soon;Oh, Sejong;Choi, Jeong-Yeol
    • 한국연소학회:학술대회논문집
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    • 2015.12a
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    • pp.251-255
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    • 2015
  • Unsteady Shock-Induced Combustion has been studied for the past few decades since it is considered as one of the potential ways to reach supersonic flights. Experimental observations of Unsteady SIC were observed as early as 1960's. But Lehr was the first to report in detail the mechanisms of Shock-Induced Combustion experimentally. Numerical Studies on SIC were helpful in explaining the insight into the oscillatory behaviour in the mid 90's to early 2000's. Detailed reaction mechanisms is required to prediction the SIC flowfield more in detail. However at that time, very few reaction mechanisms on hydrogen-oxidation were reported. In the last decade, various number of hydrogen reaction mechanisms were reported. In this study, an attempt has been made to analyze the effect of various reaction mechanisms in an unsteady mode of Shock-Induced Combustion.

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Properties and pozzolanic reaction degree of tuff in cement-based composite

  • Yu, Lehua;Zhou, Shuangxi;Deng, Wenwu
    • Advances in concrete construction
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    • v.3 no.1
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    • pp.71-90
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    • 2015
  • In order to investigate the feasibility and advantage of tuff used as pozzolan in cement-based composite, the representative specimens of tuff were collected, and their chemical compositions, proportion of vitreous phase, mineral species, and rock structure were measured by chemical composition analysis, petrographic analysis, and XRD. Pozzolanic activity strength index of tuff was tested by the ratio of the compression strength of the tuff/cement mortar to that of a control cement mortar. Pozzolanic reaction degree, and the contents of CH and bond water in the tuff/cement paste were determined by selective hydrochloric acid dissolution, and DSC-TG, respectively. The tuffs were demonstrated to be qualified supplementary binding material in cement-based composite according to relevant standards. The tuffs possessed abundant $SiO_2+Al_2O_3$ on chemical composition and plentiful content of amorphous phase on rock texture. The pozzolanic reaction degrees of the tuffs in the tuff/cement pastes were gradually increased with prolongation of curing time. The consistency of CH consumption and pozzolanic reaction degree was revealed. Variation of the pozzolanic reaction degree was enhanced with the bond water content and relationship between them appeared to satisfy an approximating linear law. The fitting linear regression equation can be applied to mutual conversion between pozzolanic reaction degree and bond water content.

Kinetic Study of Xylan Hydrolysis and Decomposition in Concentrated Sulfuric Acid Hydrolysis Process by $^1H$-NMR Spectroscopy ($^1H$-NMR에 의한 Xylan의 황산가수분해 과정에서 나타나는 반응 동력학 연구)

  • Cho, Dae-Haeng;Kim, Yong-Hwan;Kim, Byung-Ro;Park, Jong-Moon;Sung, Yong-Joo;Shin, Soo-Jeong
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.43 no.3
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    • pp.52-58
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    • 2011
  • Proton-NMR spectroscopic method was applied to kinetic study of concentrated sulfuric acid hydrolysis reaction, especially focused on 2nd step of acid hydrolysis with deferent reaction time and temperature as main variables. Commercial xylan extracted from beech wood was used as model compound. In concentrated acid hydrolysis, xylan was converted to xylose, which is unstable in 2nd hydrolysis condition, which decomposed to furfural or other reaction products. Without neutralization steps, proton-NMR spectroscopic analysis method was valid for analysis of not only monosaccharide (xylose) but also other reaction products (furfural and formic acid) in acid hydrolyzates from concentrated acid hydrolysis of xylan, which was the main advantages of this analytical method. Higher temperature and longer reaction time at 2nd step acid hydrolysis led to less xylose concentration in xylan acid hydrolyzate, especially at $120^{\circ}C$ and 120 min, which meant hydrolyzed xylose was converted to furfural or other reaction products. Loss of xylose was not match with furfural formation, which meant part of furfural was degraded to other undetected compounds. Formation of formic acid was unexpected from acidic dehydration of pentose, which might come from the glucuronic acid at the side chain of xylan.