• Title/Summary/Keyword: Reaction Progress Variable

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Developmental Changes in Photosynthetic Pigments and Chlorophyll Fluorescence in Etiolated Rice Seedlings During Greening

  • Chun, Hyun-Sik;Moon, Byoung-Yong;Suh, Kye-Hong;Lee, Chin-Bum
    • Journal of Plant Biology
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    • v.39 no.4
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    • pp.309-314
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    • 1996
  • Developmental of photosynthetic pigments and changes in chlorophyll fluorescence of dark-grown rice seedlings were studied during greening. Light-illumination stimulated accumulations of total chlorophylls and carotenoids in leaves of etiolated seedlings, accompanied by a decrease in the ratio of chlorophyll a to chlorophyll b. When the composition of carotenoids was analyzed, violaxanthin level was shown to increase up to 24 h after the beginning of light illumination, followed by a subsequent decline. In contrast to this, zeaxanthin level increased consistently with progress of deetiolatin. The role of zeaxanthin is discussed in relation to chlorophyll fluorescence quenching. A study on chlorophyll fluorescence kinetics of the rice seedlings being deetiolated showed a time-dependent increase in Fv/Fm (yield of variable fluorescence/maximum yield of fluoresecnece) ratios, indicating that greening is responsible for the activation of photochemical reaction centers of the photosystem. When chlorophyll fluorescence quenching was examined, qNP (nonphotochemical quenching) and qE (energy-dependent quenching) exhibited a time-dependent decline with progress of greening. The presented results indicate that greening-induced development of the photosynthetic machinery is associated the conversion of the carotenoid violaxanthin to zeaxanthin, suggesting that zeaxanthin synthesized in the illuminated leaves may provide the protection from the damage when etiolated plants are exposed to light.

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The Dynamic Effects of China's Agricultural Technology Progress and Agricultural Environment Grants on Agricultural Development - Focusing on 3 Dongbei Province in China - (중국의 농업기술진보와 농업환경보조금이 농업발전에 미치는 동태적 파급효과 - 동북 3성을 중심으로 -)

  • Jin, Lin;Mun, Hong Sung
    • Journal of Korean Society of Rural Planning
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    • v.26 no.3
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    • pp.57-65
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    • 2020
  • Agricultural research and development (R&D) investment has contributed not only to agriculture but also to the overall economic growth of the country. The recent arrival of the fourth industrial revolution has raised the need for agricultural R&D as a preparation. Agriculture R&D is directly related to the fourth industrial revolution in the agricultural and livestock sectors that utilize big data, robots, artificial intelligence and cloud. Meanwhile, subsidies or grants are considered the most widely used means of policy. Therefore, in light of the current situation in which Chinese agriculture values R&D investment, this study attempted to analyze the dynamic relationship between variables by establishing a model of agricultural environment subsidy representing the role of government, agricultural technology progress representing existing agricultural R&D investment, agricultural income representing agricultural development and total agricultural output. The analysis results showed that each variable's reaction to the rise in China's agricultural R&D investment has a positive effect on agricultural development, in line with the theory that the investment in science and technology in the agricultural sector has a positive effect. In addition, the response of each variable to China's rising agricultural environment subsidy is shown to have a positive relationship, which can also be said to be in line with the theory that the government's market-friendly intervention is beneficial to economic development.

Numerical Modeling for the $H_2/CO$ Bluff-Body Stabilized Flames

  • Kim, Seong-Ku;Kim, Yong-Mo;Ahn, Kook-Young;Oh, Koon-Sup
    • Journal of Mechanical Science and Technology
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    • v.14 no.8
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    • pp.879-890
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    • 2000
  • This study investigates the nonpremixed $H_2/CO$-air turbulent flames numerically. The turbulent combustion process is represented by a reaction progress variable model coupled with the presumed joint probability function. In the present study, the turbulent combustion model is applied to analyze the nonadiabatic flames by introducing additional variable in the transport equation of enthalpy and the radiative heat loss is calculated using a local, geometry independent model. Calculations are compared with experimental data in terms of temperature, and mass fraction of major species, radical, and NO. Numerical results indicate that the lower and higher fuel-jet velocity flames have the distinctly different flame structures and NO formation characteristics in the proximity of the outer core vortex zone. The present model correctly predicts the essential features of flame structure and the characteristics of NO formation in the bluff-body stabilized flames. The effects of nonequilibrium chemistry and radiative heat loss on the thermal NO formation are discussed in detail.

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Internal Flow Dynamics and Performance of Valveless Airbreathing Pulse Detonation Engine (무-밸브 공기흡입 펄스데토네이션 엔진의 내부 유동과 성능)

  • Ma Fuhua;Choi J.Y.;Yang Vigor
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2006.05a
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    • pp.367-370
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    • 2006
  • This paper deals with the modeling and simulation of the internal flowfield in a valveless airbreathing pulse detonation engine (PDE) currently under experimental development at the U.S. Naval Postgraduate School. The system involves no valves in the airflow path, and the isolation between the inlet and combustor is achieved through the gasdynamics in an isolator. The analysis accommodates the full conservation equations in axisymmetric coordinates, and takes into account variable properties for ethylene/oxygen/air system. Chemical reaction schemes with a single progress variable are implemented to minimize the computational burden. Detailed flow evolution during a full cycle is explored and propulsive performance is calculated. Effect of initiator mass injection rate is examined and results indicate that the mass injection rate should be carefully selected to avoid the formation of recirculation zones in the initial cold flowfield. Flow evolution results demonstrate a successful detonation transmission from the initiator to the combustor. However, strong pressure disturbance may propagate upstream to the inlet nozzle, suggesting the current configuration could be further refined to provide more efficient isolation between the inlet and combustor.

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A Study on Analysis of the Hydrogen-Oxygen Gas Generator Using Pulse Power Supply (펄스전원에 의한 수산화가스 발생기에 관한 연구)

  • 이정민;강병희;목형수;최규하
    • The Transactions of the Korean Institute of Power Electronics
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    • v.6 no.5
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    • pp.377-385
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    • 2001
  • The mixed gas of Hydrogen and Oxygen is gained from water electrolysis reaction. It has constant volume ratio 2 : 1 Hydrogen and Oxygen, and it is used as a source of thermal energy by combustion reaction. This gas has better characteristics in the field of economy, efficiency of energy, and environmental intimacy than acetylene gas and LPG used for gas welding machine. So several studies of this gas are actively in progress nowadays. The object of this study is the optimization of power condition in the side of electricity for the Hydrogen-Oxygen gas generator, Firstly chemical analysis of electrolysis is conducted, and the relation of electrical energy and chemical energy is quantitatively investigated through Faraday's laws of electrolysis. After that, pulse power supply is designed for basic experiment which could be applied to the analysis of Hydrogen-Oxygen gas generator. In the basis of above steps, comparison and analysis of Hydrogen-Oxygen gas generator was conducted as variable frequency using pulse Power supply.

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Leading Edge Statistics of a Turbulent Premixed Flame (난류 예혼합 화염 선단부의 통계적 특성에 관한 수치적 연구)

  • Kwon, Jaesung;Huh, Kang Y.
    • Journal of the Korean Society of Combustion
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    • v.18 no.1
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    • pp.13-20
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    • 2013
  • Leading edge statistics are obtained by direct numerical simulation(DNS) of freely propagating incompressible and stagnating compressible turbulent premixed flames. Conditional averages of velocities in terms of reaction progress variable, c, and local flame surface density, ${\sum}^{\prime}_f$, are defined and compared through the flame brush. It holds asymptotically that $<u>_f=<S_d>_f$ and $<u>_u-<u>_b=D_t/L_w$ with the characteristic length scale of $\bar{c}$ variation, $L_w$. It also holds that $<u>_b=<u>_f$ for a freely propagating flame under no mean strain rate. The turbulent burning velocity, $S_T$, is determined by the conditional statistics at the leading edge under large activation energy.

First Moment Closure Simulation of Floating Turbulent Premixed Flames in Stagnation Flows (정체 유동장에 떠있는 난류 예혼합 화염의 일차 모멘트 닫힘 모사)

  • Lee, Eun-Ju;Huh, Kang-Y.
    • 한국연소학회:학술대회논문집
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    • 2000.05a
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    • pp.122-132
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    • 2000
  • Computational fluid dynamic simulation is performed for the floating turbulent premixed flames stabilized in stagnation flows of Cho et al. [1] and Cheng and Shepherd [2]. They are both in the wrinkled flamelet regime far from the extinction limit with $u'/S^{0}_{L}$ less than unity. The turbulent flux is given in the first moment closure as a sum of the classical gradient flux due to turbulent motions and the countergradient flux due to thermal expansion. The parameter $N_{B}'s$ are greater than unity with the countergradient flux dominant over the gradient flux. The countergradient flux is assumed to be zero in $\bar{c}<0.05$. The flame surface density is modeled as a symmetric parabolic function with respect to $\bar{c}$. The product of the maximum flame surface density and the mean stretch factor is considered as a tuning constant to match the flame location. Good agreement is achieved with the measured $\tilde{w}$ and $\bar{c}$ profiles along the axis in both flames.

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Feasibility of a methane reduced chemical kinetics mechanism in laminar flame velocity of hydrogen enriched methane flames simulations

  • Ennetta, Ridha;Yahya, Ali;Said, Rachid
    • Advances in Energy Research
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    • v.4 no.3
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    • pp.213-221
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    • 2016
  • The main purpose of this work is to test the validation of use of a four step reaction mechanism to simulate the laminar speed of hydrogen enriched methane flame. The laminar velocities of hydrogen-methane-air mixtures are very important in designing and predicting the progress of combustion and performance of combustion systems where hydrogen is used as fuel. In this work, laminar flame velocities of different composition of hydrogen-methane-air mixtures (from 0% to 40% hydrogen) have been calculated for variable equivalence ratios (from 0.5 to 1.5) using the flame propagation module (FSC) of the chemical kinetics software Chemkin 4.02. Our results were tested against an extended database of laminar flame speed measurements from the literature and good agreements were obtained especially for fuel lean and stoichiometric mixtures for the whole range of hydrogen blends. However, in the case of fuel rich mixtures, a slight overprediction (about 10%) is observed. Note that this overprediction decreases significantly with increasing hydrogen content. This research demonstrates that reduced chemical kinetics mechanisms can well reproduce the laminar burning velocity of methane-hydrogen-air mixtures at lean and stoichiometric mixture flame for hydrogen content in the fuel up to 40%. The use of such reduced mechanisms in complex combustion device can reduce the available computational resources and cost because the number of species is reduced.

The Fabrication of Porous Nickel Oxide Thin Film using Anodization Process for an Electrochromic Device

  • Lee, Won-Chang;Choe, Eun-Chang;Hong, Byeong-Yu
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.407.1-407.1
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    • 2016
  • Electrochromism is defined as a phenomenon which involves persistently repeated change of optical properties between bleached state and colored state by simultaneous injection of electrons and ions, sufficient to induce an electrochemical redox process. Due to this feature, considerable progress has been made in the synthesis of electrochromic (EC) materials, improvements of EC properties in EC devices such as light shutter, smart window and variable reflectance mirrors etc. Among the variable EC materials, solid-state inorganics in particular, metal oxide semiconducting materials such as nickel oxide (NiO) have been investigated extensively. The NiO that is an anodic EC material is of special interest because of high color contrast ratio, large dynamic range and low material cost. The high performance EC devices should present the use of standard industrial production techniques to produce films with high coloration efficiency, rapid switching speed and robust reversibility. Generally, the color contrast and the optical switching speed increase drastically if high surface area is used. The structure of porous thin film provides a specific surface area and can facilitate a very short response time of the reaction between the surface and ions. The large variety of methods has been used to prepare the porous NiO thin films such as sol-gel process, chemical bath deposition and sputtering. Few studies have been reported on NiO thin films made by using sol-gel method. However, compared with dry process, wet processes that have the questions of the durability and the vestige of bleached state color limit the thin films practical use, especially when prepared by sol-gel method. In this study, we synthesis the porous NiO thin films on the fluorine doped tin oxide (FTO) glass by using sputtering and anodizing method. Also we compared electrical and optical properties of NiO thin films prepared by sol gel. The porous structure is promised to be helpful to the properties enhancement of the EC devices.

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