• Title/Summary/Keyword: Reaction Oxygen

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Development of Air Supply System for Fuel Cell Electric Bus (연료전지 버스용 공기공급시스템 개발)

  • Kim, Woo-June;Park, Chang-Ho;Cho, Kyung-Seok;Oh, Chang-Hoon
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.561-564
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    • 2007
  • FCEV uses electric energy which generated from the reaction between Hydrogen and Oxygen in fuel cell stack as driving force. As fossil fuels are exhausted, fuel cell is regarded as a potent substitute for next generation energy source, and thus, most of car-makers make every efforts to develop fuel cell electric vehicle (FCEV). In addition, fuel cell is also beneficial in aspect of environment, because only clean water is produced during chemical reaction process instead of harmful exhausted gas. Generally, Hydrogen is supplied from high-pressured fuel tank, and air blower (or compressor) supply Oxygen by pressurizing ambient air. Air blower which is driven by high speed motor consumes about $7{\sim}8$ % of energy generated from fuel cell stack. Therefore, the efficiency of an air blower is directly linked with the performance of FCEV. This study will present the development process of an air blower and its consisting parts respectively.

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Development of Air Supply System for FCEV Bus (연료전지 버스용 공기공급시스템 개발)

  • Park, Chang-Ho;Cho, Kyung-Seok;Kim, Woo-June;Oh, Chang-Hoon
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.11a
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    • pp.417-420
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    • 2006
  • FCEV uses electric energy generated from the reaction between Hydrogen and Oxygen in fuel cell stack as driving force. As fossil fuels are exhausted, fuel cell is regarded as a potent substitute for next generation energy source, and thus, most of car-makers make every efforts to develop fuel cell electric vehicle (FCEV). In addition, fuel cell is also beneficial in aspect of environment, because only clean water is produced during chemical reaction process instead of harmful exhausted gas. Generally, Hydrogen is supplied from high-pressured fuel tank, and air blower (or compressor) supplies Oxygen by pressurizing ambient air. Air blower which is driven by high speed motor consumes about $7{\sim}8%$ of energy generated from fuel cell stack. Therefore, the efficiency of an air blower is directly linked with the overall performance of FCEV. This study will present developing process of an air blower and its consisting parts respectively.

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Fabrication of Cu-Sheathed Bi-Sr-Cu-O High Temperature Superconductor Thick Films (동피복재법을 이용한 Bi-Sr-Ca-Cu-O 고온초전도 후막 제조)

  • 한상철;성태현;한영희;이준성;정상진
    • Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
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    • 1999.02a
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    • pp.22-25
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    • 1999
  • A well oriented Bi-2212 superconductor thick films were fabricated by screen printing with a Cu-free Bi-Sr-Ca-Cu-O powder on a copper plate and heat-treating at 820- $880^{\circ}C$for several minute in low oxygen pressure or are. At minute in low oxygen pressure of air. At , the printing layer partially melted by reaction between the Cu-free precursor by reaction between the Cu-free$870^{\circ}C$ precursor and CuO of the oxidizing copper plate. It is believed that the solid phase is Bi : Sr : Ca : Cu = 2 : 2 : 0 : 1. It is likely that the Bi-2212 superconducting phase is formed at Bi-2212 superconducting phase is formed at Bi-free phase/liquid interface by nucleation and grows.

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Effects of Aging on Electrocatalytic Activities of Pt and Pd Nanoparticles

  • Dutta, Gorachand;Yang, Haesik
    • Journal of Electrochemical Science and Technology
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    • v.7 no.1
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    • pp.27-32
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    • 2016
  • Although the time dependences of the electrocatalytic activities of Pt and Pd nanoparticles during electrochemical operations have been widely studied, the time dependences under nonpolarized conditions have never been investigated in depth. This study reports the changes in the electrocatalytic activities of Pt and Pd nanoparticles with aging in air and in solution. Pt (or Pd) nanoparticle-modified electrodes are obtained by adsorbing citrate-stabilized Pt (or Pd) nanoparticles on amine-modified indium-tin oxide (ITO) electrodes, or by electrodeposition of Pt (or Pd) nanoparticles on ITO electrodes. The electrocatalytic activities of freshly prepared Pt and Pd nanoparticles in the oxygen reduction reaction slowly decrease with aging. The electrocatalytic activities decrease more slowly in solution than in air. An increase in surface contamination may cause electrocatalytic deactivation during aging. The electrocatalytic activities of long-aged Pt (or Pd) nanoparticles are significantly enhanced and recovered by NaBH4 treatment.

Recent Progress in Nanoparticle Synthesis via Liquid Medium Sputtering and its Applications

  • Cha, In Young;Yoo, Sung Jong;Jang, Jong Hyun
    • Journal of Electrochemical Science and Technology
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    • v.7 no.1
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    • pp.13-26
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    • 2016
  • Nanoparticles (NPs), which have been investigated intensively as electrocatalysts, are usually synthesized by chemical methods that allow precise size and shape control. However, it is difficult to control the components and compositions of alloy NPs. On the other hand, the conventional physical method, sputtering with solid substrates, allows for facile composition control but size control is difficult. Recently, “liquid medium sputtering” has been suggested as an alternative method that is capable of combining the advantages of the chemical and conventional physical methods. In this review, we will discuss NP synthesis via the liquid medium sputtering technique using ionic liquid and low-volatile polymer media. In addition, potential applications of the technique, including the generation of oxygen reduction reaction electrocatalysts, will be discussed.

The Fabrication of Low Cost High Temperature Superconducting Tape (저비용 고온초전도 선재 제조 연구)

  • 한상철;성태현;한영희;이준성;이영우;정년호;김상준
    • Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
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    • 2000.02a
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    • pp.85-88
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    • 2000
  • Cu-free Bi-Sr-Ca-O powder mixtures were screen-printed on Cu tapes and heat-treated at 850-$870^{\circ}C$ for several minutes in air, oxygen, nitrogen and low oxygen pressure. Cu-free precursors were composed of Bi_{x}$SrCaO_{y}$ (x=1.2-2). In order to obtain the optimum heat-treatment condition, we studied on an effect of the precursor composition, the printing thickness and the heat-treatment atmosphere on the superconducting properties of Bi2212 films and the reaction mechanism of their rapid formation. Microstructures and phases of thick films were analyzed by optical microscope and XRD. The electric properties of superconducting films were examined by the four probe method. At heat-treatment temperature, the thick films were in a partially molten state by liquid reaction between CuO in the oxidized copper tape and the precursors which were printed on Cu tapes.

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Investigation on Flame Characteristics′ Variation by Flue Gas Recirculation and Fuel Injection Recirculation (산화제류 및 연료류 희석에 의한 화염특성변화에 대한 연구)

  • Han, Ji-Woong;Kum, Sung-Min;Lee, Chang-Eon
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.28 no.12
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    • pp.1625-1631
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    • 2004
  • Investigation on Flue Gas Recirculation(FGR) flame and Fuel Injection Recirculation(FIR) flame was performed with numerical method. Quantitative Reaction Path Diagram(QRPD) is utilized to compare the different chemistry effects between FGR flame and FIR flame. In order to compare flamelets in various oxygen-enrichment conditions reasonably, the adiabatic flame temperature and Damkohler number were held fixed by modulating the amount of diluents to fuel and oxidizer stream and by varying global strain rate of flame respectively. Basic flame structures were compared and characteristics of CH$_4$ decomposition and NO formation were analyzed based on QRPD analysis between FGR flame and FIR flame.

Electrochemical preparation of Blue TiO2 nanotube array and its application for oxygen evolution reaction (전기화학적 방법을 이용한 산소 발생용 Blue TiO2 전극제조 및 반응특성조사)

  • Han, Jun-Hyeok;Tak, Yong-Seok;Yun, Je-Yong
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2014.11a
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    • pp.46-46
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    • 2014
  • 알칼리 수전해는 신재생에너지를 이용하여 오염물질 없이 효율적으로 수소를 생산할 수 있는 방법 중의 하나이다. 알칼리 수전해 시스템의 산화전극으로 불용성전극이 많이 사용되고 있으나 높은 과전압과 제조 공정이 복잡한 문제점을 가지고 있다. 본 연구에서는 전기변색을 이용해 짙은 파란색의 $TiO_2$ 나노튜브를 알칼리 수전해 시스템의 산화전극으로 이용하고자 하였다. 양극산화법을 이용해 $TiO_2$ 나노튜브를 만드는 과정에서 양극산화 시간과 인가전압에 따라 Blue $TiO_2$의 산소발생반응(Oxygen evolution reaction, OER) 활성 변화를 측정하였고 나노튜브 길이가 길고 직경이 클수록 OER활성과 내구성이 향상되는 것을 확인하였다.

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Electrochemical Evaluation and Synthesis of Pt/C and PtCo/C Catalysts for the Cathode of PEMFC (PEMFC용 캐소드를 위한 Pt/C, PtCo/C 촉매제조 및 전기화학평가)

  • Kim, Jin-Hwan;Ryu, Ho-Jin
    • Journal of the Semiconductor & Display Technology
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    • v.7 no.4
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    • pp.45-49
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    • 2008
  • For the commercialization of polymer electrolyte membrane fuel cell (PEMFC), some serious problems such as the decrease of platinum use as catalysts and a larger overpotential of oxygen reduction reaction (ORR) at cathode must be solved. In this study, 20%Pt/C and 20%PtCo/C catalysts for the cathode of PEMFC were synthesized from the chemical reduction method and evaluated using an electrochemical measurement. The ORR activity of synthesized 20%Pt/C and 20%PtCo/C had higher than that of the 20%Pt/C on the market. The synthesized 20%PtCo/C with the cobalt concentration (Pt:Co atomic ratio) from 5 to 20% showed the highest ORR activity.

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A Study on Brown Gas Generator with Instantaneous Source Power Control (순시전원제어에 의한 수산화가스 발생장치에 관한 연구)

  • Jeon, Yoon-Seok;Lee, Sang-Yong;Mok, Hyung-Soo;Choe, Gyu-Ha
    • Proceedings of the KIEE Conference
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    • 2003.07b
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    • pp.1093-1095
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    • 2003
  • The mixed gas of Hydrogen and Oxygen has obtained from water electrolysis reaction. It has constant volume ratio 2 : 1 Hydrogen and Oxygen, and it is used as a source of thermal energy by combustion reaction. In this paper, Brown Gas Generator with Instantaneous source power control method is designed and relationship between brown gas quantities, efficiency and power condition is studied.

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