• Title/Summary/Keyword: Reaction Oxygen

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Partial premixed combustion modeling of diffusion flame burner for SiO2 deposition as optical fiber cladding (광섬유 클래딩용 SiO2 증착을 위한 확산 화염 버너의 부분 예혼합 연소 모델링)

  • Park, Hyung-Bin;Han, Yoonsoo
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.29 no.6
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    • pp.365-371
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    • 2019
  • In this study, the flame temperature distribution of the diffusion flame burner for SiO2 deposition was analyzed by the computational fluid analysis. This corresponds to the previous step for simulating the SiO2 preform deposition process for manufacturing optical fibers using environmentally friendly raw materials. In order to model premixed combustion, heat flow, convection, and chemical reactions were considered, and Reynolds-averaged Navier-Stokes equations and k-ω models were used. As a result, the temperature distribution of the flame showed a tendency to increase the distance from the nozzle surface to the maximum temperature when the flow rate of the auxiliary oxygen increased. In addition, it was confirmed that the temperature distribution due to incomplete combustion was large in the combustion reaction with a large equivalence ratio of the mixed gas.

Fabrication and Characteristics of Sensing Materials for BaTiO3 Gas Sensors (BaTiO3가스센서 감지물의 제조와 특성 연구)

  • 서동진;장경욱;임실묵;김좌연;최병현;박경순
    • Journal of the Korean Ceramic Society
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    • v.40 no.12
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    • pp.1177-1182
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    • 2003
  • The porous sensing materials for BaTiO$_3$ gas sensors were fabricated by adding the graphite powders. The crystalline structure and microstructure of the porous BaTiO$_3$-based ceramics were studied. All the sintered bodies showed a tetragonal perovskite structure. The porosity increased with increasing graphite contents. This is mainly due to an enhanced evolution of CO and $CO_2$ gases resulting from the exothermic reactions of graphite and oxygen during the sintering. It was found that the discrepancy in the resistivities measured in air and CO atmospheres at high temperatures (>∼20$0^{\circ}C$) became remarkable with increasing temperature. The sensitivity of CO gas increased with porosity, since the reactions between CO gas and $O_2$$^{[-10]}$ and between CO gas and $O^{[-10]}$ are active due to the formation of many reaction sites. The porous BaTiO$_3$-based ceramics could be promising as a sensing material for CO gas sensors.

Effects of Y2O3 Addition on Densification and Thermal Conductivity of AlN Ceramics During Spark Plasma Sintering (Y2O3 첨가가 AlN 세라믹스의 방전 플라즈마 소결 거동 및 열전도도에 미치는 영향)

  • Chae, Jae-Hong;Park, Joo-Seok;Ahn, Jong-Pil;Kim, Kyoung-Hun;Lee, Byung-Ha
    • Journal of the Korean Ceramic Society
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    • v.45 no.12
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    • pp.827-831
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    • 2008
  • Spark plasma sintering (SPS) of AlN ceramics were carried out with ${Y_2}{O_3}$ as sintering additive at a sintering temperature $1,550{\sim}1,700^{\circ}C$. The effect of ${Y_2}{O_3}$ addition on sintering behavior and thermal conductivity of AlN ceramics was studied. ${Y_2}{O_3}$ added AlN showed higher densification rate than pure AlN noticeably, but the formation of yttrium aluminates phases by the solid-state reaction of ${Y_2}{O_3}$ and ${Al_2}{O_3}$ existed on AlN surface could delay the densification during the sintering process. The thermal conductivity of AlN specimens was promoted by the addition of ${Y_2}{O_3}$ up to 3 wt% in spite of the formation of YAG secondary phase in AlN grain boundaries because ${Y_2}{O_3}$ addition could reduced the oxygen contents in AlN lattice which is primary factor of thermal conductivity. However, the thermal conductivity rather decreased over 3 wt% addition because an immoderate formation of YAG phases in grain boundary could decrease thermal conductivity by a phonon scattering surpassing the contribution of ${Y_2}{O_3}$ addition.

Electrochemical Catalytic Behavior of Cu2O Catalyst for Oxygen Reduction Reaction in Molten Carbonate Fuel Cells

  • Song, Shin Ae;Kim, Kiyoung;Lim, Sung Nam;Han, Jonghee;Yoon, Sung Pil;Kang, Min-Goo;Jang, Seong-Cheol
    • Journal of Electrochemical Science and Technology
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    • v.9 no.3
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    • pp.195-201
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    • 2018
  • To enhance the performance of cathodes at low temperatures, a Cu-coated cathode is prepared, and its electrochemical performance is examined by testing its use in a single cell. At $620^{\circ}C$ and a current density of $150mAcm^{-2}$, a single cell containing the Cu-coated cathode has a significantly higher voltage (0.87 V) during the initial operation than does that with an uncoated cathode (0.79 V). According to EIS analysis, the high voltage of the cell with the Cu-coated cathode is due to the dramatic decrease in the high-frequency resistance related to electrochemical reactions. From XPS analysis, it is confirmed that the Cu is initially in the form of $Cu_2O$ and is converted into CuO after 150 h of operation, without any change in the state of the Ni or Li. Therefore, the high initial cell voltage is confirmed to be due to $Cu_2O$. Because $Cu_2O$ is catalytically active toward $O_2$ adsorption and dissociation, $Cu_2O$ on a NiO cathode enhances cell performance and reduces cathode polarization. However, the cell with the Cu-coated cathode does not maintain its high voltage because $Cu_2O$ is oxidized to CuO, which demonstrates similar catalytic activity toward $O_2$ as NiO.

A Study on the Effect of the Composting of the Food Garbage by the Variations of Agitation cycle (교반속도 변화가 음식쓰레기의 퇴비화에 미치는 영향에 관한 연구)

  • Hu, Kwan;Shin, Dae-Yewn;Jeong, Byeong-Keon;Park, Chi-Hong
    • Journal of Environmental Health Sciences
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    • v.24 no.2
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    • pp.118-125
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    • 1998
  • This study investigates the react characteristics to suggest the condition of the utilization and disintegration of food garbage as composting by varying the supply amount of air of the fermentation reactors. With the initial temperature and agitation velocity maintained 50$\circ$C and 1 rpm, the supply amount of air gives variety to 0.5, 1, 2, 4 l/kg$\cdot$ min. In the case of the amount of air operated at the 0.5 l/kg$\cdot$ min, reaction temperature shows a rising to the maximum 66$\circ$C after the 48hr, and the oxygen used rate of the micro-organisms shows the largest level at 18.4% after the 8hr. In the case of $NH_3, H_2, H_2S$ and SO$_2$ among the react gas, the sanitary utilization shows the possibility of the microorganisms gas disintegration, with most high gas generate rate. In the case of the amount of air operated at the 1, 2 and 4 l/kg$\cdot$ min, initial react was advanced rapidly and the product of the 72 hr after shows big weight reduction. As the experimentation result, when the amount of air operated at the 1 l/kg$\cdot$ min over, the reduction by disintegration would be more effectively, for the reactor maintains the color tone and shape of the straw (bulking agent).

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Experimental Study of Hydrogen and Syngas Production over Ni/Ce-ZrO2/Al2O3 Catalysts with Additives (Ni/Ce-ZrO2/Al2O3 촉매의 첨가제에 따른 수소 및 합성가스 생성에 대한 실험적 연구)

  • Cho, Wonjun;Yu, Hyejin;Mo, Yonggi;Ahn, Whaseung
    • Transactions of the Korean hydrogen and new energy society
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    • v.25 no.2
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    • pp.105-113
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    • 2014
  • Performance tests on $Ni/Ce-ZrO_2/Al_2O_3$ catalysts with additives (MgO, $La_2O_3$) were investigated in the combined reforming processes (SCR, ATR, TRM) in order to produce hydrogen and carbon monoxide (it is called "syngas".). The catalyst characterization was conducted using the BET surface analyzer, X-ray diffraction (XRD), SEM, TPR and TGA. The combined reforming process was developed to adjust the syngas ratio depending on the synthetic fuel (methanol, DME and GTL) manufacturing processes. Ni-based catalysts supported on alumina has been generally recommended as a combined reforming reaction catalyst. It was found that both free NiO and complexed NiO species were responsible for the catalytic activity in the combined reforming of methane conversion, and the $Ce-ZrO_2$ binary support employed had improved the oxygen storage capacity and thermal stability. The additives, MgO and $La_2O_3$, also seemed to play an important role to prevent the formation of the carbon deposition over the catalysts. The experimental results were compared with the equilibrium data using a commercial simulation tool (PRO/II).

The Effects of Salt Stress on Photosynthetic Electron Transport and Thylakoid Membrane Proteins in the Cyanobacterium Spirulina platensis

  • Sudhir, Putty-Reddy;Pogoryelov, Denys;Kovacs, Laszlo;Garab, Gyozo;Murthy, Sistla D.S.
    • BMB Reports
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    • v.38 no.4
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    • pp.481-485
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    • 2005
  • The response of Spirulina (Arthrospira) platensis to high salt stress was investigated by incubating the cells in light of moderate intensity in the presence of 0.8 M NaCl. NaCl caused a decrease in photosystem II (PSII) mediated oxygen evolution activity and increase in photosystem I (PSI) activity and the amount of P700. Similarly maximal efficiency of PSII (Fv/Fm) and variable fluorescence (Fv/Fo) were also declined in salt-stressed cells. Western blot analysis reveal that the inhibition in PSII activity is due to a 40% loss of a thylakoid membrane protein, known as D1, which is located in PSII reaction center. NaCl treatment of cells also resulted in the alterations of other thylakoid membrane proteins: most prominently, a dramatic diminishment of the 47-kDa chlorophyll protein (CP) and 94-kDa protein, and accumulation of a 17-kDa protein band were observed in SDS-PAGE. The changes in 47-kDa and 94-kDa proteins lead to the decreased energy transfer from light harvesting antenna to PSII, which was accompanied by alterations in the chlorophyll fluorescence emission spectra of whole cells and isolated thylakoids. Therefore we conclude that salt stress has various effects on photosynthetic electron transport activities due to the marked alterations in the composition of thylakoid membrane proteins.

Erosion-Corrosion Behavior of Power Plant Pipe Caused by Hot Feed Water (고온 급수에 의한 파워 플랜트 배관 침식-부식 거동)

  • Bang, Sung-Ho;Lee, Jin-Won;Kim, Tae-Won
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.37 no.6
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    • pp.739-745
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    • 2013
  • In this study, we tried to define the erosion-corrosion behavior together with the resulting effects on a pipe that is a part of a feed water circulation system according to the pipe size and hot feed water environment. An erosioncorrosion analysis was performed through the Hayduk and Minhas model based on the chemical reaction between iron and oxygen, an essential corrosive factor. The erosion-corrosion rate against the pipe diameter and feed water temperature was then evaluated by means of finite element analysis using ABAQUS. As shown in the results, the feed water temperature was the main factor influencing the erosion-corrosion rate; in particular, it was expected that the thickness of 316 stainless steel would decrease by $2.59{\mu}m$ every year in a hot water environment at $290^{\circ}C$.

Clinical characteristics of acute lower respiratory tract infections according to respiratory viruses in hospitalized children without underlying disease during the last 3 years (최근 3년간 기저질환이 없는 소아 입원 환자에서 호흡기 바이러스에 따른 급성 하기도 감염의 임상적 특징)

  • Seo, Min Hae;Kim, Hyung Young;Um, Tae Min;Kim, Hye-Young;Park, Hee-Ju
    • Journal of Yeungnam Medical Science
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    • v.34 no.2
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    • pp.182-190
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    • 2017
  • Background: Respiratory viruses play a significant role in the etiology of acute respiratory infections and exacerbation of chronic respiratory illnesses. This study was conducted to identify the epidemiological and clinical characteristics of children with acute viral lower respiratory infections. Methods: This study investigated 1,168 children diagnosed with acute viral lower respiratory tract infections (RTIs) between January 2012 and December 2014. Specimens of respiratory viruses were collected using a nasopharyngeal swab and analyzed by reverse transcriptase polymerase chain reaction. We retrospectively reviewed the medical records and analyzed the clinical features of children hospitalized for acute lower respiratory infections. Results: Respiratory syncytial virus (RSV), the main cause of infection in children aged <5 years, was the most commonly detected pathogen in children with bronchiolitis and pneumonia, and resulted in high proportions of children requiring oxygen treatment and intensive care unit admission. Rhinovirus was preceded by RSV as the second most common cause of bronchiolitis and pneumonia, and was detected most frequently in the children aged ${\geq}6$ years. In addition, asthma was predominantly caused by rhinovirus in children aged ${\geq}6$ years, whereas croup was mostly caused by parainfluenza virus in those aged <5 years. Rhinovirus infection (p<0.001) and history of asthma (p=0.049) were identified as significant risk factors for readmission within a month. Conclusion: We identified the epidemiological and clinical characteristics of respiratory viruses in children with acute lower respiratory infections during the last 3 years. Our findings may provide useful clinical insight to comprehend the acute viral lower RTIs in children.

Expression of the Antioxidant Enzyme and Apoptosis Genes in In vitro Maturation/In vitro Fertilization Porcine Embryos

  • Jang, H.Y.;Kong, H.S.;Lee, S.S.;Choi, K.D.;Jeon, G.J.;Yang, B.K.;Lee, C.K.;Lee, H.K
    • Asian-Australasian Journal of Animal Sciences
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    • v.17 no.1
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    • pp.33-38
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    • 2004
  • This study was aimed at testing the gene expression of antioxidant enzymes and apoptosis genes for in vitro culture in porcine embryos produced by in vitro maturation/in vitro fertilization (IVM/IVF). Pocine preimplantation embryos obtainted from IVM/IVF can be successfully culture in vitro, but they are delayed or stop to develop at specific developmental stage. Many factors such as reactive oxygen species and apoptosis in an IVM/IVF system followed by in vitro culture influence the rate of production of viable blastocysts. Porcine embryos derived from IVM/IVF were cultured in the atmosphere of 5% $CO_2$ and 20% $O_2$ at $38.5^{\circ}C$ in NCSU23 medium. The patterns of gene expression for antioxidant enzymes and apoptosis genes during in vitro culture in pocine IVM/IVF embryos were examined by the modified semi-quantitative single cell reverse transcriptase-polymerase chain reaction (RT-PCR). Porcine embryos produced by in vitro procedures were expressed mRNAs for CuZn-SOD, GAPDH and GPX, whereas transcripts for Mn-SOD and catalase were not detected at any developmental stages. Expression of caspase-3 mRNA was detected at 2 cell, 8 cell 16 cell and blastocyst, but p53 mRNA was not detected at any stages. The fas transcripts was only detected in blastocyst stage. These results suggest that various antioxidant enzymes and apoptosis genes play crucial roles in vitro culture of porcine IVM/IVF embryos.