• Title/Summary/Keyword: Reaction Front

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Evolution of reaction zones in reactive barriers consisting of calcite and glass beads

  • Jeong Gon, Kim;Gwang Man, Lee;Ik Hwan, Go
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.04a
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    • pp.19-22
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    • 2004
  • Two-dimensional modeling studies using TOUGHREACT were conducted to investigate the coupling between flow and transport developed as a consequence of differences in density, dissolution/ precipitation, and medium heterogeneity. The model includes equilibrium reactions for aqueous species, kinetic reactions between tile solid phases and aqueous constituents, and full coupling of porosity and permeability changes resulting from precipitation and dissolution reactions in porous media. Generally, the evolutions in the concentrations of the aqueous phase are intimately related to the reaction-front dynamics. Plugging of the medium contributed to significant transients in patterns of flow and mass transport.

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NUMERICAL STUDY ON THE MIXER TYPE OF UREA-SCR SYSTEM FOR FLOW MIXING IMPROVEMENT (Urea-SCR 시스템의 유동혼합 개선을 위한 혼합기 형상에 관한 수치적 연구)

  • Lee, J.W.;Choi, H.K.;Yoo, G.J.;Kim, W.S.
    • 한국전산유체공학회:학술대회논문집
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    • 2010.05a
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    • pp.368-375
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    • 2010
  • To alleviate NOx emission, a variety of approaches has been applied. In marine diesels, the application of SCR systems has been considered an effective exhaust aftertreatment method for NOx emission control. Most current SCR systems use a various catalyst for the reaction of ammonia with NOx to form nitrogen and water. In theory, it is possible to achieve 100% NOx if the NH3-to-NOx ratio is 1:1. However, the reaction has a limited non-uniformity of the exhaust gas flow and ammonia concentration distribution. Therefore it is necessary to investigate the optimum flow conditions. In order to achieve uniform flow at monolith front face, we are equipped with a various mixed device. In this paper, it is presented that the mixed devices play an important role improvement of flow patterns and particle distributions of NH3 by numerical simulation.

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NUMERICAL STUDY ON THE MIXER TYPES OF UREA-SCR SYSTEM FOR FLOW MIXING IMPROVEMENT (Urea-SCR 시스템에서 유동혼합 개선을 위한 혼합기 형상에 관한 수치적 연구)

  • Lee, J.W.;Choi, H.K.;Yoo, G.J.
    • Journal of computational fluids engineering
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    • v.15 no.4
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    • pp.9-16
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    • 2010
  • To alleviate NOx emission, a variety of approaches has been applied. In marine diesels, the application of SCR systems has been considered an effective exhaust aftertreatment method for NOx emission control. Most current SCR systems use a various catalyst for the reaction of ammonia with NOx to form nitrogen and water. In theory, it is possible to achieve 100% NOx if the $NH_3$-to-NOx ratio is 1:1. However, the reaction has a limited non-uniformity of the exhaust gas flow and ammonia concentration distribution. Therefore, it is necessary to investigate the optimum flow conditions. In order to achieve uniform flow at monolith front face, we are equipped with a various mixed devices. In this paper, it is presented that the mixed devices play an important role improvement of flow patterns and particle distributions of $NH_3$ by numerical simulation.

Solidification and Phase Equilibria Studies by Directional Solidification Technique in the Ni-Al System (Ni-Al계에서 일방향응고에 의한 응고 및 상평형 연구)

  • Lee, Jae-Hyeon;Jo, Chang-Yong;Lee, Jong-Hun;Choe, Seung-Ju
    • 연구논문집
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    • s.25
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    • pp.163-168
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    • 1995
  • The intermetallic compound $Ni_3Al$ causes a peritectic reaction at the composition and temperature very close to the eutectic reaction in Ni-Al system. Although the phase diagram accepted for this system by ASM Handbook has the eutectic forming between the $\gamma$ and $\gamma$ phases, directional solidification study has shown that the eutectic occurs between $\beta$ and $\gamma$. This work examines the liquidus region using quenched, directional solidification experiments that preserve the microstructrues formed at the solidification front. It is also shown that under certain composition and growth conditions a metastable eutectic between the $\beta$ and $\gamma$ phases forms in this system. Finding of the metastable eutectic provided an important information to understand the phase equilibria near the $Ni_3Al$ composition.

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Mathematical Modeling of Self-propagating High Temperature Synthesis of Molybdenum- Tungstenb Disilicide (이규화 몰리브덴-텅스텐의 자전 고온 합성 반응 모델링)

  • Yeon, Sun-Hwa;Jang, Dae-Gyu;Lee, Cheol-Gyeong
    • Korean Journal of Materials Research
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    • v.11 no.3
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    • pp.164-170
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    • 2001
  • The Self-propagating High-temperature Synthesis (SHS) for synthesizing ($Mo_{1-z}$ , $W_{z}$)$Si_2$was conducted experimentally with the mole fraction of Tungsten(W) from z=0.0 to z=0.5. The temperature profile was measured according to the reaction time through the thermocouple that was equipped into the center of these samples. When the reaction front is propagated around the thermocouple, the highest temperature appears and we regard this temperature as the adiabatic temperature. We found out by experimental results that the reaction velocity is in the range of 2.14~1.35mm/sec and the adiabatic temperature is in the range of 1883~1507K for the six samples. The reaction velocity and the adiabatic temperature were inclined to decrease with an increasing of the mole fraction of Tungsten (W). The SHS modeling is presented in order to predict the temperature profiles and these results are compared with the experimental results. It is predicted that in case of increasing the initial temperature of these six samples, the reaction temperature increased and that the sample of z=0.5 needs the preheating up to 800~900K in order to become reaction temperature 1900K.

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A Study on the Bucket Loading Characteristics for Wheel-loader Loading Automation (휠로더 굴착 자동화를 위한 버킷 부하특성 연구)

  • Seo, Dong-Kwan;Seo, Hyun-Jae;Kang, In-Pil;Kwon, Young-Min;Lee, Sang-Hoon;Hwang, Sung-Ho
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.33 no.11
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    • pp.1332-1340
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    • 2009
  • The front end wheel loader is widely used for the loading of materials in mining and construction fields. It has repetitive digging, loading and dumping procedures. The bucket is subjected to large resistance force from the soil during scooping. We considered the soil reaction force characteristics from scooping procedure, the protection by overload and automatic scooping mode algorithm. The main topic of this paper is the analysis of the soil reaction force characteristics. The analysis of soil mechanics is carried out and the developed soil model is verified by experimental results from the simplified experimental equipment. A simplified model of the soil shape and bucket trajectory is used to determine the scooping direction based on an estimation of the resistance force applied on the bucket during the scooping motion. In the future, this model will be used for the generation of an appropriate path for the wheel loader automation.

The Biomechanical Analysis of the Driver Swing of High School female Golfers (고교 여자 골프선수의 드라이버 스윙에 대한 운동역학적 분석)

  • Lee, Kyung-Il;Lee, Hee-Kyung;Bae, Jong-Won;Chung, Jin-Young
    • Korean Journal of Applied Biomechanics
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    • v.19 no.2
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    • pp.273-286
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    • 2009
  • The objective of this research is to evaluate both quantitative analysis and qualitative analysis by comparing vital variable factors of the golf swing successes and the failures. At the moment of swing, each body segment and the movement of the club as well as kinematical parameters were produced by utilizing the 3-D swing analysis for the high school female golfers. As kinematical parameters, it analyzes the 3-D analysis and ground reaction force about the location change, velocity and angle. The 3-D swing analysis and ground reaction force location change, velocity and angle are analyzed for Kinematical parameters. As a result, the stable swing is maintained by club head showing very few front-back movement (X) when the address and the top swing. Also, the center of mass velocity contributes to the momentum increase by showing very rapid velocity when successful comparing with when failed at the time of top swing of left-right(Y) and it is thought that by lessening the cocking angle when successful from the top swing to the impact, it influences the linear velocity increase and has a good effect on a non-distance increase. It shows that Ground reaction force (GRF) is examined by showing the stable approval rating in a front-back(X) direction and left-right(Y) and connected to a successful swing.

Effects of Base Metal on the Partial Oxidation of Methane Reaction (메탄의 부분산화반응에 미치는 Base metal의 영향)

  • 오영삼;장보혁;백영순;이재의;목영일
    • Journal of Energy Engineering
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    • v.8 no.2
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    • pp.256-264
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    • 1999
  • The performance of the Pt-B/cordierite catalysts (2 wt%) Pt, 70 wt% Alumina, 28 wt%) Ceria and Zirconia, B: base metal) loaded with 6∼12 wt% Mn, Cu, V, Co, Cr and Ba, respectively was studied for partial oxidation of methane reaction and compared with that of Ni loaded catalyst. As a results, it was found that Ba, Co, Cr as well as Ni loaded catalysts showed higher activity for methane partial oxidation of methane than the Mn, Cu and V loaded catalyst. But it was known that catalysts having good activity for methane showed the good activity for coke formation, too. A XRD analysis of the catalyst before and after the reaction using 5 wt% Ni/Al$_2$O$_3$) showed that there were three Ni phases. In these results, it was found that methane oxidation reaction occulted at the front of the catalyst bed consisted of NiAl$_2$O$_4$and NiO and reforming reaction occurred at the rear part of the catalyst bed consisted of reduced Ni.

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Analysis of Ground Reaction Force with Different Soccer Studs (축구화 스터드의 형태변화에 따른 지면반력 분석)

  • Lee, Joong-Sook
    • Korean Journal of Applied Biomechanics
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    • v.16 no.1
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    • pp.119-128
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    • 2006
  • This study was performed to see ground reaction force with different soccer studs with twelve players in Human Performance Laboratory(University of Calgary). Running speed was $4.0{\pm}0.2m/sec$ in straight running as well as vcut running. By using four different kinds of shoes; three different pairs of soccer shoes and one pair of jogging shoes, I reached a conclusion as following. In case of right and left ground reaction force, on the assumption that the positive magnitude of power is inversion and the negative is eversion, vcut running did not occur any inversion, which in the aspect of kinetic mechanics, thought to be decelerating movement. Because when eversion happens, it arises component force of power on heading direction about 8.6 times more than in the movement of straight running. In case of front and rear ground reaction, on the assumption that the positive magnitude of power is suspension power and the negative is propulsion, vcut movement is thought to be decelerating movement in the aspect of kinetic mechanics. Because on heading direction, this movement occurs component force of power about 1.8 times more suspension and 2.2 more propulsion than in the straight running movement. In case of vertical ground reaction, on the assumption that the first peak is the magnitude of power in impact and the second peak is the magnitude of power in active, we judged that the straight running movement performed more efficiently than the vcut movement in the aspect of kinetic mechanics. On the next study, I suppose that vcut running would make up an interesting subject in the aspect of improving kinetic performance ability.

Investigation of the Three-Dimensional Turbulent Flow Fields of the Gas Swirl Burner with a Cone Type Baffle Plate(II)

  • Kim, Jang-kweon
    • Journal of Mechanical Science and Technology
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    • v.15 no.7
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    • pp.906-920
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    • 2001
  • This paper presents three-dimensional mean velocities, turbulent intensities and Reynolds shear stresses measured in the Y-Z plane of the gas swirl burner with a cone type baffle plate by using an X-type hot-wire probe. This experiments is carried out at the flow rate of 450ℓ/min which is equivalent to the combustion air flow rate necessary to heat release 15,000 kcal/hr in a gas furnace. Mean velocities and turbulent intensities etc. show that their maximum values exist around the narrow slits situated radially on the edge of and in front of a burner. According to downstream regions, they have a peculiar shape like a starfish because the flows going out of the narrow slits and the swirl vanes of an inclined baffle plate diffuse and develop into inward and outward of a burner. The rotational flow due to the inclined flow velocity going out of swirl vanes of a cone type baffle plate seems to decrease the magnitudes of mean velocities V and W respectively by about 30% smaller than those of mean velocity U. The turbulent intensities have large values of 50%∼210% within the range of 0.5

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