• Bulletin of the Korean Chemical Society
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• v.24 no.2
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• pp.189-192
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• 2003

The reaction of 4-(2-methylaziridin-1-yl)-3-ureidobenzotrifluorides 4 with triphenylphosphine, carbon tetrachloride, and triethylamine (Appel's condition) led to the corresponding carbodiimides 5, which underwent intramolecular cycloaddition reaction with aziridine under the reaction condition to give the benzimidazolefused heterocycles, 2,3-dihydro-1H-imidazo[1,2-a]benzimidazoles 8 and 12,13-dihydro-5H-benzimidazo[2,3-b] [1,3]benzodiazepines 9.

• Journal of applied mathematics & informatics
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• v.29 no.3_4
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• pp.949-953
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• 2011

It is interesting to know the behavior of a network from its structure. One interesting topic is to find a relation between the existence of a positive equilibrium of the reaction network and its structure. One approach to study this topic is using the concept of deficiency. Another is using some conditions on nodes, which can apply to large-size networks compared to deficiency. In this work, we show the relation between deficiency and the conditions.

• 한국신재생에너지학회:학술대회논문집
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• 2009.06a
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• pp.888-888
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• 2009

A simulation study on SCR (Steam Carbon dioxide Reforming) process in gas-to-liquid (natural gas to Fischer-Tropsch synthetic fuel) process was carried out in order to find optimum reaction conditions for GTL (gas-to-liquid) process reaction. Optimum SCR operating conditions for synthesis gas to FT (Fischer-Tropsch) process were determined by changing reaction variables such as feed temperature and pressure. During the simulation, overall synthesis process was assumed to proceed under steady-state conditions. It was also assumed that physical properties of reaction medium were governed by RKS (Redlich-Kwong-Soave) equation. SCR process was considered as reaction models for synthesis gas in GTL proess. The effect of temperature and pressure on SCR process $H_2$/CO ratio and the effect of reaction pressure on SCR reaction were mainly examined. Simulation results were also compared to experimental results to confirm the reliability of simulation model. Simulation results were reasonably well matched with experimental results.

• Korean Journal of Materials Research
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• v.14 no.10
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• pp.725-730
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• 2004

Nickel ultrafine powder have been synthesized by chemical reduction of aqueous $NiSO_4$ with hydrazine at various reaction conditions. The effect of reaction conditions such as the amount of surfactant and reductor, and reaction temperature on the particle size and shape was investigated by the mean of XRD, SEM and SEM-PSA. Experiments showed that the ratio of $N_{2}H_4/Ni$ and the reaction temperature were affected on the particle size of the nickel powder. The average particle size of synthesized nickel powder increased with increasing reaction temperature regardless of the ratio of $N_{2}H_4/Ni$. Also the surfactant could influence the size and agglomeration of ultrafine powder with the reaction temperature.

• KSBB Journal
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• v.13 no.1
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• pp.20-25
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• 1998

Optimum conditions of the cellulose-hydrolysis reaction with mixed enzymes(cellulase extracted from Penicellium funiculosum mixed with $\beta$-glucosidase extracted from Almod) were investigated to increase the production of glucose from cellulose. Experimental result showed that optimum conditions fro pH, activity ratio of $\beta$-glucosidase to cellulase, concentration of mixed enzymes, concentration of cellulose as a substrate, and temperature range were 4.2, 0.4, 0.8, U/mL, 40 g/L, and 37$\pm$3$^\circ C$, respectively. In these conditions, quantities of glucose productions by using mixed enzymes were larger than those by using cellulase at optimum conditions.

• 한국신재생에너지학회:학술대회논문집
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• 2007.06a
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• pp.41-44
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• 2007

Steam reforming reaction of natural gas is an important process for fuelcell commercialization. In this paper, steam reforming reaction is studied by numerical method. Pseudo-homogeneous model is incorporated for chemical reactions and one medium approach is used to take into account thermally equilibrium phenomena between catalyst and bulk gas. The model is validated with our experimental results under the same operating conditions. Because performance of reformer has relation to heat flux from wall, heat flux profiles was investigated by using Nusselt number. Value of Nusselt number in steam reformer is larger than one in channel, which does not have chemical reaction because steam reforming reaction is an endothermic reaction. When the difference of Nusselt number at the front and the rear is larger, performance is improved.

• 한국정보디스플레이학회:학술대회논문집
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• 2002.08a
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• pp.724-727
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• 2002

2,7-dibromo-9, 9-dialkyl-substituted-fluorene derivatives were prepared by the alkylation of 2,7-dibromofluorene with various alkyl groups under two-phase phase transfer catalysis (PTC) conditions, as monomers for synthesizing poly(dialkylfluorene)s. Tetra-nbutylammonium hydrogen sulfate (TBAHS) was used as a phase transfer catalyst to enhance nucleophilic substitution. In addition, NaOH in water (25M) was used as a base to generate anions. Compared to conventional alkylation using butyllithium(BuLi), the reaction using the PTC technique attained high selectivity and substantial conversion of reactants, due to the enhanced reaction rate, while the reaction was carried out under moderate conditions. An approximately 90% yield was obtained from the reaction and the reaction time was remarkably reduced. 2,7-dibromo-9,9-dihexyl-fluorene, 2,7-dibromo-9,9-dioctyl-fluorene, and 2,7-dibromo-9,9-di(2-ethylhexyl)-fluorene were effectively synthesized by phase transfer catalytic reaction.

• Korean Journal of Metals and Materials
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• v.49 no.10
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• pp.790-796
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• 2011

To reduce the heat released during intermetallic reaction, Ni-50at%Al powder compact has been previously annealed at several conditions before the reaction. The effects of the pre-annealing conditions on the reaction synthesis process have been investigated. Experimental results show that the heat released during the reaction synthesis decreased proportionally with increase of the pre-annealing temperature and duration time. The reaction duration period was significantly increased when the intermetallics were formed in the powder compact during the pre-annealing. This was attributed to the fact that the reaction occurred by solid-state diffusion between the un-reacted elemental atoms and that the $NiAl_3$ phase formed predominantly during pre-annealing.

• Journal of the Korean Chemical Society
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• v.13 no.2
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• pp.187-193
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• 1969

As part of an extensive program on the microbiological oxidation of hydrocarbons, reaction conditions and nutrients consumption of candida lipolytica grown on alkane as carbon source were studied. For optimum growth of yeast, the conditions of pH 5, temperature $30^{\circ}C$, carbon number $C_{16}$& $C_{18}$aeration 25.6 1/l/hr, agitation 3000 r.p.m., hydrocarbon concentration 10% were obtained. Carbon and nitrogen balance related to these conditions were also investigated. In the course of this investigation, some significant effects of pH and carbon number of hydrocarbon variation were observed.

• Environmental Engineering Research
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• v.13 no.3
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• pp.112-118
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• 2008

Residual solid in excess sludge treated by hydrothermal reaction was investigated as raw material for its recycling. Treated excess sludge and residual solid were also focused on their content change during hydrothermal reaction. Two kinds of excess sludge, obtained from a local food factory and a municipal wastewater treatment process, were tested under various conditions. Following hydrothermal reaction, depending on the reaction conditions, biodegradable substrates in treated excess sludge appeared to increase. The separated residual solid was a composite composed of organic and inorganic materials. The proportion of carbon varied from 34.0 to 41.6% depending on reaction conditions. Although 1.89% of hazardous materials were detected, SiO2 (Quartz) was a predominant constituent of the residual solid. X-ray diffraction (XRD) experiments revealed that the residual solid was of a partially amorphous state, suggesting that the residual solids could be easily converted to stable and non harmful substances through a stabilization process. Thus, this technology could be successfully used to control excess sludge and its reuse.