• Title/Summary/Keyword: Reactants

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Metal-Organic Vapor Phase Epitaxy : A Review II. Process and charactristics (MOVPE 단결정층 성장법 II. MOVPE공정 및 특징)

  • 정원국
    • Journal of the Korean institute of surface engineering
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    • v.23 no.2
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    • pp.1-10
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    • 1990
  • Metal-Organic Vapor Phase Epitaxy (MOVPE) is an epitaxial process utilizaing ane or more of organometallice as reactnte to grow compound semicond semiconductror layers. MOVPE is basically a cold wall process in which reactants are delivered without reacting with each other to the heated substrate where reactants are thermally decomposed to from compound semiconductors through chemical reaction. Since reactants are delivered as gas phase and the formation of the single crystal compunds depends on the thermal decomposition of the reactants, details of MOVPE relies on the hydrodynamics and pyroltsis and chemical reation of reactants inside on reaction chamber. It has been demonstrated that MOVPE is capable of growing virtually all of the III-V, II-VI and IV-VI compound semiconductrs, fabricating ultrathin epilayers, for ming abrupt hetrointerfaces with monolayer transition width, and is suitable for multi-wafer operation yilding a high throghtput. Overiew of reactror componts and layer, characteristics, and status of MOVPE are discussed.

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Improvement of Physical Property of Autoclaved Light-Weight Concrete Using Admixtures and Chemical Reactants (혼화재 및 화학반응제를 혼입한 경량기포콘크리트의 물성 개선)

  • Song, Hun
    • Journal of The Korean Digital Architecture Interior Association
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    • v.12 no.4
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    • pp.87-95
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    • 2012
  • Autoclaved lightweight concrete (ALC), also known as autoclaved aerated concrete (AAC), is a lightweight, precast building material that simultaneously provides structure, insulation. ALC is a unique building material. Because of its cellular nature, it is lightweight, self-insulating, as well as sound and fireproof. ALC products include blocks, wall panels, floor and roof panels, and lintels. Recently, the use of ALC has became increasingly popular. However, ALC have high water absorption, low compressive strength and popout the origin of the low surface strength in its properties. Thus, this study is to improve the fundamental strength by controls of increasing of admixtures and chemical reactants. Admixtures make use of meta kaolin and silica fume, chemical reactants make use of sodium silicate and sodium hydroxide. From the test result, the ALC using admixtures and chemical reactants have a good fundamental properties compared with plain ALC. These good fundamental properties is caused by the admixtures and chemical reactants of ALC by the reason of the micro filling effect and chemical binding of C-S-H gel, tobermolite and quartz.

Effects of Onion Juice on Ethanol-Induced Hepatic Lipid Persoxidation in Rats (양파즙이 에탄올에 의한 백서의 지질산화물 생성에 미치는 영향)

  • 박평심;이병래;이명렬
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.23 no.5
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    • pp.750-756
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    • 1994
  • The effect of onion juice on ethanol -induced lipid peroxidation were studied were studied in rats. The contents of thiobarbituric acid (TBA) -reactants increased significantly in liver thanol(4ml/kg/day) administered -rats. The activities of serum alanine aminotransferase and alkaline phosphatase increased by ethanol administration compared with control group, but alterations of antioxidant enzymes activities in liver of ethanol administered rats were not significant vs control group. The glutathione contents in liver decreased by ethanol , whereas the glutathione level increased in ethanol and onion juice group compared with ethanol group. The contents of hepatic TBA-reactants and serum aminotrasnferase activity in ethanol group were reduced by onion juice administration. In these results, increased hepatic TBA-reactants of liver in ethanol group might be due to decreased glutathione contents in liver. Reduced glutathione (GSH) plays an important roles in the liver in several detoxification and the reduction of lipid peroxides. So the protective effects of onion juice on ethanol-induced increment of TBA-reactants may be due to the increament of lgutathions content. The glutathione depletion by ethanol was an important factor of ethanol-induced cell damage, and the prevention of onion juice to the glutathione depletion reduced by ethanol may be an important factor on the protection from ethanol-induced lipid perpxidation in rats.

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The Crystalline Quality of Si Films Prepared by Thermal- and Photo-CVD at Low Temperatures

  • Chung, Chan-Hwa;Rhee, Shi-Woo;Moon, Sang-Heup
    • Journal of the Korean Vacuum Society
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    • v.4 no.S1
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    • pp.34-39
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    • 1995
  • Various silicon films were prepared by thermal- and UV photo-CVD processes. The reactants were SiH4, Si2H6, SiH2F2, SIF4, and H2. Silicon films grown at temperatures below $500 ^{\circ}C$ were either amorphous or crystalline depending on the process conditions, and the growth rates ranged between 5 and $80\AA$min. Crystallinity of the film was improved even at $250^{\circ}C$ when the film was grown by photo-CVD using fluoro-silanes as the reactants. Analysis of the film by RBS, SIMS, XRD, and ex-situ IR indicated that substrate surface was contaminated by oxygen and other impurities when the reactants contained neither hydrogen nor fluoro-silnanes, but when fluoro-silanes were used as reactants the silicon film was highly crystalline.

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Catalytic Oxidation of VOCs using Photocatalysis (광촉매반응을 이용한 VOCs의 촉매산화)

  • 이승범;이재동
    • Journal of environmental and Sanitary engineering
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    • v.18 no.2
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    • pp.52-59
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    • 2003
  • This study was progressed in photocatalysis of VOCs using $UV/TiO_2$ which was a benign process environmentally. The experiments were peformed to know photodegradation characteristics as crystalline structure of $TiO_2$ which had anatase, rutile and P-25 (anatase : rutile = 70 : 30). The main purpose of this study was to identify photocatalytic characteristics as inlet concentration of reactants, $H_2O$, and residence time. The inlet concentration of VOCs was changed 50, 100 and 200 ppmv, and amount of $H_2O$ was changed 0, 500 and $1000{\;}mg/m^3$, respectively. The deep conversion was increased as the inlet concentration decreased, and the amount of $H_2O$ increased. The deep conversion of benzene had the highest value at $1000{\;}mg/m^3${\;}H_2O$ and 50 ppmv of inlet concentration. The reactivity of reactants was decreased in order benzene > toluene > m-xylene. Also, the photocatalytic deep conversion was increased as residence time increased, because the contact time between reactants and catalyst was increased. In this study, intermediates had not found by GC/MSD analysis. Therefore, the reactants were completely converted to $H_2O{\;}and{\;}CO_2$.

Synthesis of $H_2$-Permselective Silica Films by Chemical Vapor Deposition (화학증착(CVD)에 의한 선택적 수소 투과성 실리카막의 제조)

  • 남석우;하호용;홍성안
    • Membrane Journal
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    • v.2 no.1
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    • pp.21-32
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    • 1992
  • Hydrogen-permselective silica membranes were synthesized within tim walls of porous Vycor tubes by chemical vapor depostion of $SiO_2$. Film deposition was carried out using $SiCl_4$ hydrolysis either in the oppm shag reactants or in the one-sided geometry. At temperatures above $600^{\circ}C$ the permeation rate of hydrogen thorough the silica films varied between 0.01 and $025cm^3(STP)/cm^2-min-atm$ depending on the reaction geometry and the $H_2 : N_2$ permeation ratio was about 1000. Permeation rates of both $H_2$ and $N_2$ increased with increasing temperature. The silica membranes produced by one-sided deposition have higher hydrogen permmeation rates than those produced by the opposing reactants geometry although the membranes formed in an opposing reactants geometry were relatively stable during the heat treatment or after exposure to ambient air. These membranes can be applied to high temperature gas separations or membrane reactors once the film deposition process is optimized to get high permeability as well as good stability.

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Continuous Processing of Monodispersed Zirconia Powders (초음파 혼합 연속공정에 의한 단분산 지르코니아 분체의 합성)

  • Rhee, Jhun;Jo, Dong-Soo
    • Journal of the Korean Ceramic Society
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    • v.29 no.12
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    • pp.919-925
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    • 1992
  • Continuous synthesis process for monodispersed zirconia powders with ultrasonic wave mixing was developed. Reactant solutions were flowed through a T-tube with small diameter and then mixed in a microscale with ultrasonification. Reaction and aging were followed during the mixed solution of reactants is in plug flowing through a narrow long teflon tubing. Zr(n-OC4H9)4 in ethanol and H2O in ethanol were used as reactants. From this process monodispersed, spherical, non-agglomerated, singlet hydrated zirconia powders with 0.6 $\mu\textrm{m}$ average size were obtained. Geometrical standard deviation of the particle size distribution was less than 1.2 with ultrasonic mixing, and the geometrical standard deviation was not affected by the flow rate of the reactants.

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Design of Inlet Manifold for PEM Fuel Cells and Numerical Analysis (고분자 전해질 연료전지를 위한 연료주입구 설계 및 수치해석)

  • Uhm, Seung-Bae;Na, Tae-Kyung;Kim, Hong-Suk;Baek, Jung-Sik;Sung, Dong-Mug;Kim, Tae-Min
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.172-175
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    • 2007
  • The Performance of a PEMFC stack is strongly dependent on the uniform reactants distribution on MEA. The uniform distribution can be achieved by flow-field pattern and manifold design optimized to satisfy operating conditions. This paper investigates uniform reactants distribution in channels by changing manifold shape and inlet mass flow rate. Typical U and Z shape and modified U and Z shape manifolds with buffer zone were designed. To check the uniform reactants distribution, standard deviation of mass flow rate was compared. The numerical results show that the inlet mass flow rate, inlet shape, and manifolds shape are critical factor for uniform distribution.

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The Effect of Reaction Conditions on the Conversion of Synthesis of 1-Amino-4-(3'-Acetaminoanilino) Anthraquinone-2-Sulfonic Acid (1-Amino-4-(3'-Acetaminoanilino) Anthraquinone-2-Sulfonic Acid 합성의 전화율에 미치는 반응조건의 영향)

  • 천재기;구수진
    • Journal of the Korean Graphic Arts Communication Society
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    • v.16 no.3
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    • pp.133-146
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    • 1998
  • The conversion of 1-Amino-4-(3'-Acetaminoanilino) Anthraquinone-2-Sulfonic Acid prepared by the Ullmann condensation have been investigated as a function of the reaction conditions such as catalysts, initial concentration of reactants, reaction temperature, pH, condensation agents and neutralizing agents. The experimental results showed that the Cu(I)-type catalysts had higher activity than the Cu(II)-type catalysts in this study. The conversion increased with increasing initial concentration of reactants but decreased at above critical concentration owing to agglomeration of reactants. It was also observed that the maximum conversion obtained at 7$0^{\circ}C$ and pH=7~8.

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The Effect of Anion Catalysts in Transesterification Reaction (에스테르 교환반응(交渙反應)에서 음(陰)이온 촉매(觸媒)의 영향(影響))

  • Park, Keun-Ho
    • Journal of the Korean Applied Science and Technology
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    • v.9 no.2
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    • pp.141-148
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    • 1992
  • Transesterification reactions (methyl methacrylate with diethanolamine, ethylene glycol with dimethylphthalate) were kinetically investigated in the presence of zinc compound catalysts at $120{\sim}170^{\circ}C$ The amount of reactants was measured by gas chromatography. and the reaction rates also measured from the amount of reaction products and reactants upon each catalyst. The transesterification reactions were carried out under the first order conditions respect to the concentration of reactants, respectively, The overall reaction order was 2nd. The apparent rate constant (k') was found to obey first kinetics with respect to the concentration of catalyst. It shows that according to an increase in basicity of anionic species the rate constant increase, and that a linear relationship exists between ln k and pKa in transesterification reaction of methyl methacrylate with diethanolamine.