• Applied Chemistry for Engineering
• /
• v.28 no.6
• /
• pp.705-713
• /
• 2017

A novel material, $Bi_2WO_6-GO-TiO_2$ composite, was successfully synthesized using a facile hydrothermal method. During the hydrothermal reaction, the loading of $Bi_2WO_6$ and $TiO_2$ nanoparticles onto graphene sheets was achieved. The obtained $Bi_2WO_{6-GO-TiO2}$ composite photo-catalysts were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray (EDX) analysis, transmission electron microscopy (TEM), Raman spectroscopy, ultraviolet-visible diffuse reflectance spectroscopy (UV-vis-DRS), and X-ray photoelectron spectroscopy (XPS). The $Bi_2WO_6$ nanoparticle showed an irregular dark-square block nanoplate shape, while $TiO_2$ nanoparticles covered the surface of the graphene sheets with a quantum dot size. The degradation of rhodamine B (RhB), methylene blue trihydrate (MB), and reactive black B (RBB) dyes in an aqueous solution with different initial amount of catalysts was observed by UV spectrophotometry after measuring the decrease in the concentration. As a result, the $Bi_2WO_6-GO-TiO_2$ composite showed good decolorization activity with MB solution under visible light. The $Bi_2WO_6-GO-TiO_2$ composite is expected to become a new potential material for decolorization activity. Photocatalytic reactions with different photocatalysts were explained by the Langmuir-Hinshelwood model and a band theory.

• Journal of Radiation Protection and Research
• /
• v.12 no.1
• /
• pp.1-11
• /
• 1987

Central axis percentage depth-doses, P(%), were measured at the points from the 2.5cm depth of reference point to 20 cm depth with 2.5 cm interval. Distance from the X-ray target to the water phantom($30{\times}30{\times}30cm^3$) surface was 1 m, and at this point three different beam sizes of $5cm{\phi},\;10cm{\phi},\;and\;15cm{\phi}$ were used. While the X-ray tube voltage varied from 150 to 250 kV, the tube current remained constant at 5 mA. Absorbed dose rate in water, $\dot{D}_w$, was determined using the air kerma calibration factor, $N_k$, which was derived from the exposure calibration factor, $N_x$, of the NE 2571 ion chamber. The reference exposure rate, $\dot{X}_c$, was measured using the Exradin A-2 ion chamber calibrated at ETL, Japan. The half value layers of the X-rays determined to meet ETL calibration qualities. The absorbed dose rates determined at the calibration point were compared to the values obtained from Burlin's general cavity theory, and the percentage depth-dose values determined from $N_k$ showed a good agreement with the values of the published depth dose data(BJR Suppl. 17).

• Journal of Korean Ophthalmic Optics Society
• /
• v.20 no.2
• /
• pp.167-175
• /
• 2015

Purpose: The new-type rangefinder, which is using the biprism principle, is introduced to develop the range finder which can be easily carried by soldiers, and in order to realize those technologies specifically, we try to develop a scope for military rangefinder by doing optical design which can secure enough space to move the biprism. Methods: After setting up the verious initial condition to realize two kinds of goals, that are the securement of enough space to move the biprism and the easy-exchangeability of two kinds of biprisms, and then the optical system was optimized by using optical design program CodeV in order to minimize the finite ray aberrations. Results: We designed the biprism housing to makes it possible to swap the two kinds of biprisms. It was appeared that the Schmidt prism is suitable as erecting prism which can make sure the space to move the biprism. 16.5 mm was good for the face length of Schmidt prism. The optical system with a Schmidt prism and a biprism was designed, and the finite ray aberrations was minimized. Conclusions: We developed a 5X scope for an optical rangefinder using a biprism and a Schmidt prism with 16.5 mm face length. This scope is valid for the optical system which has the effective field angle of ${\pm}3.6^{\circ}$, and the finite ray aberrations are well controlled within the ${\pm}8.95^{\prime}$.

• Korean Journal of Materials Research
• /
• v.6 no.8
• /
• pp.817-824
• /
• 1996

Removal of Cu impurities on Si substrates using remote H-plasma was investigated. Si substrates were intentionally contaminated by 1ppm ${CuCI}_{2}$, standard chemical solution. To determine the optimal process condition, remote H-plasma cleaning was conducted varying the parameters of rf power, cleaning time and remoteness(the distance between the center of plasma and the surface of Si substrate). After remote H-plasma cleaning was conducted, Si surfaces were analysed by TXRF(total x-ray reflection fluorescence) and AFM(atomic force microscope). The concentration of Cu impurity was reduced by more than a factor of 10 and its RMS roughness was improved by more than 30% after remote H-plasma cleaning. TXRF analysis results show that remote H-plasma cleaning is effective in eliminating Cu impurity on Si surface when it is performed under the optimal process condition. AFM analysis results also verifies that remote H-plasma cleaning makes no damage to the Si surface. The deposition mechanism of Cu impurity may be explained by the redox potential(oxidation-reduction reaction potential) theory. Based on the XPS analysis results we could draw a conclusion that Cu impurities on the Si substrate are removed together with the oxide by a "lift-off" mechanism when the chemical oxide( which forms when Cu ions are adsorbed on the Si surface) is etched off by reactive hydrogen atoms.gen atoms.

• Journal of the Optical Society of Korea
• /
• v.10 no.3
• /
• pp.105-111
• /
• 2006

A novel image quality evaluation method, which is based on combination of the rigorous grating diffraction theory and the ray-optic method, is proposed. It is applied for design optimization and, tolerance analysis of optical imaging systems implementing diffractive optical elements (DOE). The evaluation method can predict the quality and resolution of the image on the image sensor plane through the optical imaging system. Especially, we can simulate the effect of diffraction efficiencies of DOE in the camera lenses module, which is very effective for predicting different color sense and MTF performance. Using this method, we can effectively determine the fabrication tolerances of diffractive and refractive optical elements such as the variations' in profile thickness, and the shoulder of the DOE, as well as conventional parameters such as decenter and tilt in optical-surface alignments. A DOE-based 2M-resolution camera lens module designed by the optimization process based on the proposed image quality evaluation method shows ${\sim}15%$ MTF improvement compared with a design without such an optimization.

• Journal of Korean Medicine Rehabilitation
• /
• v.15 no.1
• /
• pp.1-8
• /
• 2005

Objectives : This dissertation is to study the relationship between Scoliosis and Sasang Constitution. Methods : The researcher discriminated the Sasang constitutions of those observed - the out-patients - who were treated from January to June 2004, and showed, through whole spine X-ray, over 10 degrees in Cobb's angle. The result coming out from this study was compared firstly with the existing Sasang constitution theory from 《Dongyi Suse Bowon》 《東醫壽世保元》 and secondly with the existing of QSCCII statistics. The statistics were taken as Goodness-of-fit test, T-test, and ANOVA test. Results : 1. Of those 29 observed, 4(13.79%) were categorized in Taeum-in, 14(48.28%) in Soyang-in, and 11(37.93%)in Soum-in. 2. The result showed a significant difference with the Sasang constitution from Dong-isusebowon. 3. The result showed a difference with the existing from QSCCII. 4. There of no significant relations between each constitutions and Scoliosis. 5. There no significant relations between distinction and Scoliosis. Conclusions : In this study, rate of Soyang-in, among patients diagnosed scoliosis, was the higher.

• 제어로봇시스템학회:학술대회논문집
• /
• 2004.08a
• /
• pp.1550-1554
• /
• 2004

This paper deals with an unmanned vehicle system configuration using all terrain vehicle. Many research institutes and university study and develop unmanned vehicle system and control algorithm. Now a day, they try to apply unmanned vehicle to use military device and explore space and deep sea. These unmanned vehicles can help us to work is difficult task and approach. In the previous research of unmanned vehicle in our lab, we used 1/10 scale radio control vehicle and composed the unmanned vehicle system using ultrasonic sensors, CCD camera and kinds of sensor for vehicle's motion control. We designed lane detecting algorithm using vision system and obstacle detecting and avoidance algorithm using ultrasonic sensor and infrared ray sensor. As the system is increased, it is hard to compose the system on the 1/10 scale RC car. So we have to choose a new vehicle is bigger than 1/10 scale RC car but it is smaller than real size vehicle. ATV(all terrain vehicle) and real size vehicle have similar structure and its size is smaller. In this research, we make unmanned vehicle using ATV and explain control theory of each component

• Bulletin of the Korean Chemical Society
• /
• v.31 no.7
• /
• pp.1875-1880
• /
• 2010

A dicycle pyrazoline derivative, 1-phenyl-5-(p-fluorophenyl)-3,4-($\alpha$-p-fluoro-tolylenecyclohexano) pyrazoline, was synthesized and characterized by elemental analysis, IR, UV-vis, fluorescence spectra and X-ray single crystal diffraction. Density function theory (DFT) calculations were performed by using B3LYP method with 6-$311G^{**}$ basis set. The optimized geometry can well simulate the molecular structure. Vibrational frequencies were predicted, assigned and compared with the experimental values, which suggest that B3LYP/6-$311G^{**}$ method can well predict the IR spectra. Both the experimental electronic absorption spectra and the predicted ones by B3LYP/6-$311G^{**}$ method reveal three electron-transition bands, with the theoretical ones having some red shifts compared with the experimental data. Natural bond orbital analyses indicate that the absorption bands are mainly derived from the contribution of n $\rightarrow\pi^*$ and $\pi\rightarrow\pi^*$ transitions. Fluorescence spectra determination shows that the title compound can emit blue-light at about 478 nm. On the basis of vibrational analysis, the thermodynamic properties of title compound at different temperature have been calculated, revealing the correlations between $C^0_{p,m}$, $S^0_m$, $H^0_m$ and temperature.

• Proceedings of the Korean Vacuum Society Conference
• /
• 2016.02a
• /
• pp.145.2-145.2
• /
• 2016

We report the phase transformation of Co thin films on a sapphire substrate induced by laser irradiation. As grown Co films were initially strained and tetragonally distorted. With low power laser irradiation, the surface was ruptured and irregular holes were formed. As the laser power was increased, the films changed into round shape Co nanocrystals with well-defined 6-fold structure. By measuring the XRD of Co nanostructure as a function of laser energy densities, we found that the change of morphological shapes from films to nanocrystals was accompanied with decrease of the tetragonal distortion as well as strain relaxation. By measuring the size distribution of nanocrystals as a function of film thickness, the average diameter is proportional to 1.7 power of the film thickness which was consistent with the prediction of thin film hydrodynamic (TFT) dwetting theory. Finally, we fabricated the formation of size controlling nanocrystals on the sapphire substrate without strain.

• Journal of The Korean Astronomical Society
• /
• v.37 no.5
• /
• pp.543-546
• /
• 2004

The inverse Compton scattering of the cosmic microwave background (CMB) radiation with electrons in the intracluster medium which has a temperature gradient, was examined by the third-order perturbation theory of the Compton scattering. A new type of the spectrum distortion of the CMB was found and named as gradient T Sunyaev-Zel'dovich effect (gradT SZE). The spectrum has an universal shape. There is a zero distortion point, the cross over frequency, at 326GHz. When the hotter region locates closer to an observer, the intensity becomes brighter than the CMB in the frequency region lower than the cross over frequency and fainter than the CMB in the frequency region higher than the cross over frequency. When the cooler region locates closer to an observer, the distorted part of the spectrum has an opposite sign to the above case. The amplitude of the spectrum distortion does not de-pend on the electron density and depends on the heat conductivity and the total temperature variation along a line of sight. Therefore, the gradT SZE provides an unique opportunity to measure thermally nonequilibrium electron momentum distribution function in the ICM and combined with the X-ray measurements of the electron temperature distribution provides an opportunity of direct measurement of the heat conductivity in the ICM.