• 제목/요약/키워드: Rate-Determining

검색결과 1,472건 처리시간 0.027초

A Kinetic Study of the Chemiluminescent Reactions of Bis(2,4-dinitrophenyl)Oxalate, Hydrogen Peroxide, and Fluorescent Polycyclic Aromatic Hydrocarbons

  • Shin, Hyung-Seon;Kang, Sung-Chul;Kim, Kang-Jin
    • Bulletin of the Korean Chemical Society
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    • 제10권3호
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    • pp.251-254
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    • 1989
  • A kinetic study on the chemiluminescence resulting from the reaction between bis(2,4-dinitrophenyl) oxalate(DNPO) and hydrogen peroxide in the presence of fluorescent polycyclic aromatic hydrocarbons in a viscous phthalate medium has been conducted. The resultant data confirm that the reaction between DNPO and $H_2O_2$ is the rate determining step. Higher rate constants are obtained with DNPO than those with bis(2,4,6-trichlorophenyl) oxalate (TCPO).

중재계임을 이용한 송전비용배분비율 결정에 관한 분석 (Analysis on the Decision of Transmission Cost Allocation Rate Using the Arbitration Game)

  • 정구형;유청일;강동주;한석만;김발호
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2002년도 추계학술대회 논문집 전력기술부문
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    • pp.375-377
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    • 2002
  • In many parts of the world. the electricity industry is undergoing unprecedented changes. Hence, in order to reform the electricity industry readily and efficiently and minimize the confusion by these restructuring, it is required the systematic studies related to transmission pricing and transmission cost allocation issues. However, even now the basis of transmission cost allocation rate is not equipped so that the regulation body has determined the allocating rate under the common practice. In this paper it is demonstrated that the decision of transmission cost allocation rate is the regulation body's own right. For the analysis, game theory is applied to the procedure determining this rate and the competition to determine this rate between generators and distributors is modeled as the arbitration game.

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Development of a Nitrogen Application System for Nitrogen Deficiency in Corn

  • Noh, Hyun Kwon
    • Journal of Biosystems Engineering
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    • 제42권2호
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    • pp.98-103
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    • 2017
  • Purpose: Precision agriculture includes determining the right amount of nitrogen for a specific location in the field. This work focused on developing and validating a model using variable rate nitrogen application based on the estimated SPAD value from the ground-based image sensor. Methods: A variable rate N application based on the decision making system was performed using a sensor-based variable rate nitrogen application system. To validate the nitrogen application decision making system based on the SPAD values, the developed N recommendation was compared with another conventional N recommendation. Results: Sensor-based variable rate nitrogen application was performed. The nitrogen deficiency level was measured using the image sensor system. Then, a variable rate application was run using the decision model and real-ti me control. Conclusions: These results would be useful for nitrogen management of corn in the field. The developed nitrogen application decision making system worked well, when considering the SPAD value estimation.

선박보검과준의 결정요인에 관한 연구 (A Study on Determining Factors of Hull Insurance Rate)

  • 김경건;민성규
    • 한국항해학회지
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    • 제18권4호
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    • pp.59-81
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    • 1994
  • Korean property and liability insurance companies have underwrited hull insurance without proper undrewriting ability. But after April 1996. in case of Korean insurance market being opened the companies have to make hull insurance rate by themselves. Accordingly, in this study, the writer embodies important factors in making hull insurance rate by an empirical survey. In empirical survey, the writer used a questionnaire, 74 proper data was obtained from 96 officers working in making hull insurance rate in 12 Korean property and liablity insurance companies and 24 the foreign companies at home. Reliability was tested by Cronbach's Alpha and a conceptual validity by Factor Analysis. Hypothesis estabilished in this study was tested by Correlation and Multiple Regression Analysis. Results of testing hypothesis are as follows: Firstly, the traits of insurer and the assured influence significantly(P<0.05) on making hull insurance rate. Secondly, expected loss ratio, ship manager, ship's age, insured amount, level of the cost of repairing and salvage, shipowner, period of insurance, level of overseas rating, profit and expense, trading limits, ship's classification, conditions of insurance, and ship's size influence significantly(P<0.05) on making hull insurance rate.

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A Survey of Rate-Adaptation Schemes for IEEE 802.11 Compliant WLANs

  • Khan, Shahbaz;Ullah, Sadiq;Ahmed, Aziz;Mahmud, Sahibzada Ali
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • 제7권3호
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    • pp.425-445
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    • 2013
  • The IEEE 802.11 compliant stations can transmit at multiple transmission rates. Selection of an appropriate transmission rate plays a significant role in determining the overall efficiency of a communication system. The technique which determines the channel state information and accordingly selects an appropriate transmission rate is called rate-adaptation protocol. The IEEE 802.11 standard does not provide standard specification for implementing a rate-adaptation protocol for its multi-rate capable wireless stations. Due to the lack of standard specification, there is a myriad of rate-adaptation protocols, proposed by industry and various research institutes. This paper surveys the existing rate-adaptation schemes, discusses various features which contribute significantly in the process of rate-adaptation, the timing constraints on such schemes, and the performance gains in terms of throughput, delay and energy efficiency; which can be gained by the use of rate-adaptation. The paper also discusses the implication of rate-adaptation schemes on the performance of overall communication and identifies existing research challenges in the design of rate-adaptation schemes.

원전 배관감육 평가를 위한 새로운 기법의 도입 및 타당성 (Introduction and Feasibility on a New Technology for the Pipe Wall Thinning Evaluation of Nuclear Power Plants)

  • 황경모;윤훈;박현철
    • Corrosion Science and Technology
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    • 제13권2호
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    • pp.62-69
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    • 2014
  • A huge number of carbon steel piping components installed in the secondary system of nuclear power plants are exposed to aging mechanisms such as FAC (Flow-Accelerated Corrosion), Cavitation, Flashing, and LDIE (Liquid Droplet Impingement Erosion). Those aging mechanisms can lead to thinning of the piping components. To manage the wall thinning degradation, most of utilities in the world predict the wall thinning rate based on the computational program such as CHECWORKS, COMSY, and BRT-CICERO, evaluate the UT (Ultrasonic Test) data, and determine next inspection timing, repair or replacement, if needed. There are several evaluation methods, such as band, blanket, and strip methods, commonly used for determining the wear of piping components from single UT inspection data. It has been identified that those single UT evaluation methods not only do not consider the manufacturing features of pipes, but also may exclude the data of the most thinned point when determining the representative wear rate of piping components. This paper describes a newly developed single UT evaluation method, E-Cross method, for solving above problems and introduces application examples for several pipes and elbows. It was identified that the E-Cross method using the length and width of UT data excluded the most thinned points appropriate as the single UT evaluation method for thinned piping components.

Correlation of the Rates of Solvolysis of Phenyl Fluorothionoformate

  • Choi, Song-Hee;Seong, Mi-Hye;Lee, Yong-Woo;Kyong, Jin-Burm;Kevill, Dennis N.
    • Bulletin of the Korean Chemical Society
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    • 제32권4호
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    • pp.1268-1272
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    • 2011
  • The specific rates of solvolysis of phenyl fluorothionoformate (PhOCSF, 1) have been determined in 22 pure and binary solvents at $10.0^{\circ}C$. The extended Grunwald-Winstein equation has been applied to the specific rates of solvolysis of 1 over the full range of solvents. The sensitivities (l = $1.32{\pm}0.13$ and m = $0.39{\pm}0.08$) toward the changes in solvent nucleophilicity and solvent ionizing power, and the $k_F/k_{Cl}$ values are similar to those previously observed for solvolyses of acyl haloformate esters, consistent with the addition step of an additionelimination pathway being rate-determining. The large negative values for the entropies of activation are consistent with the bimolecular nature of the proposed rate-determining step. The results are compared with those reported earlier for phenyl chloroformate and chlorothionoformate esters and mechanistic conclusions are drawn.

고체산화물 연료전지용 $YSZ/La_0.85S_r0.15MnO_3$계 복합전극의 개발 (Development of $YSZ/La_0.85S_r0.15MnO_3$ Composite Electrodes for Solid Oxide Fuel Cells)

  • 윤성필;현상훈;김승구;남석우;홍성안
    • 한국세라믹학회지
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    • 제36권9호
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    • pp.982-990
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    • 1999
  • YSZ/LSM composite cathode was fabricated by dip-coating of YSZ sol on the internal pore surface of a LSM cathode followed by sintering at low temperature (800-100$0^{\circ}C$) The YSZ coating significantly increased the TPB(Triple Phase Boundary) where the gas the electrode and the electrolyte were in contact with each other. Sinter the formation of resistive materials such as La2Zr2O7 or SrZrO3 was prevented due to the low processing temperature and TPB was increased due to the YSZ film coating the electrode resistance (Rel) was reduced about 100 times compared to non-modified cathode. From the analysis of a.c impedance it was shown that microstructural change of the cathode caused by YSZ film coating affected the oxygen reduction reaction. In the case of non-modified cathode the RDS (rate determining step) was electrode reactions rather than mass transfer or the oxygen gas diffusion in the experimental conditions employed in this study ($600^{\circ}C$-100$0^{\circ}C$ and 0,01-1 atm of Po2) for the YSZ film coated cathode however the RDS involved the oxygen diffusion through micropores of YSZ film at high temperature of 950-100$0^{\circ}C$ and low oxygen partial pressure of 0.01-0.03 atm.

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