Bulletin of the Korean Chemical Society

Korean Chemical Society (대한화학회)
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A Kinetic Study of the Chemiluminescent Reactions of Bis(2,4-dinitrophenyl)Oxalate, Hydrogen Peroxide, and Fluorescent Polycyclic Aromatic Hydrocarbons

  • Published : 1989.06.20
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Abstract

A kinetic study on the chemiluminescence resulting from the reaction between bis(2,4-dinitrophenyl) oxalate(DNPO) and hydrogen peroxide in the presence of fluorescent polycyclic aromatic hydrocarbons in a viscous phthalate medium has been conducted. The resultant data confirm that the reaction between DNPO and $H_2O_2$ is the rate determining step. Higher rate constants are obtained with DNPO than those with bis(2,4,6-trichlorophenyl) oxalate (TCPO).

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