• 한국건설순환자원학회논문집
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• 제7권4호
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• pp.302-309
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• 2019

본 논문은 5℃의 해수 환경에 노출한 알칼리 활성 플라이애시-슬래그 시멘트의 기본 특성에 관한 실험적 연구이다. 플라이애시와 슬래그의 배합비는 6:4, 7:3 및 8:2의 세 가지로 하였으며, 활성화제(수산화나트륨 및 규산나트륨)는 결합재 중량의 5%로 하였다. 실험 결과는 플라이애시의 치환율이 증가할수록 압축강도와 밀도는 감소하는 것으로 나타났으며, 또한 흡수율은 증가하는 것으로 나타났다. 경화된 샘플의 열중량 및 X선 회절분석을 통해 샘플 내에 생성된 반응물의 종류에는 변화가 없었으나, 슬래그의 치환율이 높을수록 C-S-H gel의 생성은 증가한 것을 알 수 있었다. 본 연구에서는 5℃의 해수에 노출된 알칼리 활성 플라이애시-슬래그 시멘트에서 플라이애시 보다 오히려 슬래그의 치환율이 샘플의 역학적 특성에 영향을 미치는 것으로 나타났다.

• 대한전자공학회:학술대회논문집
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• 대한전자공학회 2004년도 하계종합학술대회 논문집(2)
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• pp.517-520
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• 2004

Organosilicate films are promising porous low-dielectric materials, which can replace the silicon dioxide films. It was researched that organosilicate films have two different chemical shifts according to the increase of the flow rate ratio. There are the red shift due to the electron deficient substitution group, and the blue shift of the electron rich substitution group. Among these chemical shifts, the blue shift from $1000 cm^{-1}$ to $1250 cm^{-1}$ was related with the formation of pores. The methyl radicals of the electron-rich substitution group terminate easily the Si-O-Si cross-link, and the Si-O-C cage-link near $1057 cm^{-1}$ is originated from the cross-link breakdown due to much methyl radicals.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2019년도 추계 학술논문 발표대회
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• pp.79-80
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• 2019

This study was intended to examine the possibility of reducing hydration heat by FA substitution and combination of slag (CGS) from coal gasification power generation (IGCC) with mixed aggregate for concrete. The analysis results showed good results if liquidity increases as the ratio of CGS increases, air volume decreases, and compressive strength is mixed up to 25% in the residual aggregate. The results showed that the heat of hydration was reduced compared to plain due to the boron content of CGS as the CGS substitution rate increased, but it was larger due to the combination with FA substitution. It was found that the heat of hydration was reduced.

• Journal of information and communication convergence engineering
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• 제19권2호
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• pp.93-101
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• 2021

Cardiac arrhythmias are common heart diseases and generally cause sudden cardiac death. Electrocardiogram (ECG) is an effective tool that can reveal the electrical activity of the heart and diagnose cardiac arrhythmias. We propose detection of P waves based on QRST cancellation zero-one substitution. After preprocessing, the QRST segment is determined by detecting the Q wave start point and T wave end point separately. The Q wave start point is detected by digital analyses of the QRS complex width, and the T wave end point is detected by computation of an indicator related to the area covered by the T wave curve. Then, we determine whether the sampled value of the signal is in the interval of the QRST segment and substitute zero or one for the value to cancel the QRST segment. Finally, the maximum amplitude is selected as the peak of the P wave in each RR interval of the residual signal. The average detection rate for the QT database was 97.67%.

• Advances in concrete construction
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• 제15권1호
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• pp.63-74
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• 2023

All production and consumption activities produce wastes, which often cause damage to our environment and multiple risks to the human health. The valorization of these wastes in concrete technology is a future solution that will allow finding other construction materials sources, optimizing energy consumption and protecting the environment. Among these wastes, there is the marble waste. Every year, huge amount of marble waste is discarded as dust or aggregates form, in open-air storage areas causing serious problems for the environment and public health. In this context, the incorporation of marble waste as a replacement of ordinary aggregates or cement in concrete composition is actively investigated by researchers. This paper presents a comprehensive review of published studies over the last 20 years, dealing the effect of marble waste on fresh and hardened properties of concrete. Most of the studies carried out have used marble waste as dust with substitution rates between 5 and 20%. Besides the economic and ecological benefits, this review showed that marble waste can improve the physical, mechanical and durability properties of concrete. This improvement depends on the form (dust, fine aggregate or coarse aggregate), substitution method (as cement or aggregates replacement) and substitution rate of marble waste. Additionally, the review results showed that the use of 10-15% of marble waste dust as cement substitution can lead to increase the compressive strength.

• 펄프종이기술
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• 제35권1호
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• pp.41-47
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• 2003

Recently, interest in utilization plan of recycling paper have been enhanced. Therefore, this research aimed to develop the manufacture process of cellulose acetate using old newsprint by acetosolv pulping process. And the manufactured cellulose acetate was also analyzed, especially based on chemical properties. The summarized results in this research were as follows; Reaction time, kind and amount of catalyst, and ratio of liquor to material were varied during acetosolv pulping process of old newsprint. Ratio of liquor to material did not give the significant difference in reaction product. Delignification rate was increased with increasing reaction time during acetosolv pulping, but yield and degree of substitution decreased with increasing reaction time. Sulfuric acid are better catalyst than hydrochloric acid in acetosolv pulping process for old newsprint, and optimal addition amount of catalyst was 1% based on reaction material. Delignification, yield, and degree of substitution were influenced by the catalyst and reaction time. Under pulping condition of $120^{\circ}C$ in 1/12 liquor to material ratio and 60min, degree of substitution was about 0.7. The acetylation reaction was not completely caused by these reaction condition. The examination of the FT-IR spectra revealed that absorption band(1200$\textrm{cm}^{-2}$, 1,750$\textrm{cm}^{-1}$) caused by carbonyl group were confirmed.

• 한국구조물진단유지관리공학회 논문집
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• 제26권2호
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• pp.18-27
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• 2022

본 연구에서는 해양 폭로 조건과 배합 사항을 고려하여 GGBFS 콘크리트의 시간의존적 염화물 확산 거동을 분석하였다. 사용 콘크리트 배합은 3 수준의 물-결합재 비 및 고로슬래그 미분말 치환률을 고려한 콘크리트 배합이며 노출 조건으로는 침지대, 간만대, 비말대 총 3 수준을 고려하여 옥외 폭로 시험을 수행하였다. 겉보기 염화물 확산계수 평가 결과, 고로슬래그 미분말의 치환률이 증가할수록 노출 기간 730일(2년)을 기준으로 평가한 확산계수의 감소율이 감소하였다. 또한 노출 조건에 따른 확산거동을 평가한 결과, 침지대, 간만대, 비말대 순으로 확산계수가 평가되었다. 비말대에서는 해수의 건습 반복으로 인해 비교적 높은 확산계수가 평가되었다. 본 연구에서는 고로슬래그 미분말 치환률이 겉보기 염화물 확산계수 감소 거동에 미치는 영향을 노출 조건 및 기간을 고려하여 분석하였다. 확산계수를 출력 값으로, 고로슬래그를 입력 값으로 설정한 선형 회귀분석을 수행하였으며, 노출 기간 730일 이후 고로슬래그 미분말이 확산계수에 미치는 영향이 크게 감소하였다. OPC 콘크리트라 할지라도 730일 이후 GGBFS 콘크리트 만큼 낮은 확산계수를 나타냈기 때문이며 고로슬래그 미분말의 사용을 통해 730일 이전에 뛰어난 초기 염해 내구성능 확보가 가능하다고 사료된다.

• Macromolecular Research
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• 제12권1호
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• pp.71-77
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• 2004

We have synthesized various types of poly(ethylene glycol) (PEG)-ibuprofen conjugates by nucleophilic substitution of bromo-terminated PEG with ibuprofen-Cs salt. The conversion of the terminal hydroxyl groups to bromo-termini was quantitative, as was the drug conjugation process, which suggests that the present synthetic method is very useful for the preparation of PEG-based prodrugs from pharmaceuticals having carboxyl functionalities. The drug-release behavior of the prodrugs was examined in both phosphate buffer (PBS, pH 7.4) and rat plasma. From the drug-release behavior in PBS, we determined that each prodrug has high storage stability. The drug-release rate was observed to be much faster in rat plasma than in buffer solution as a result of the acceleration effect provided by enzymes present in the plasma. The drug-release rate in rat plasma depends on the degree of molecular aggregation of the prodrugs, which can be changed effectively by the nature of their spacer groups or by the use of Pluronic as the polymer carrier.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2006년도 춘계 학술발표회 논문집(II)
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• pp.377-380
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• 2006

HPFRCCs(High performance fiber reinforced cementitious composites) is a class of FRCCs(Fiber reinforced cementitious composites) exhibit multiple crack. Multiple crack lead to improvement in ductility, toughness, and deformation capacity under compressive and tensile stress. These properties of HPFRCCs are affected by type of fiber, water cement ratio, type of admixture and rate of substitution. Furthermore these influence dispersion of fiber, mixing performance and fluidity of mixture. In this paper, HPFRCCs made of steel cord and carbon fiber were tested with water cement ratio, type of admixture and rate of substitution to evaluate characteristics of mixing and flexural strength.

• 한국축산시설환경학회지
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• 제3권1호
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• pp.19-26
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• 1997

Composting has recently become popular as a means of recycling swine manure into products for sale off the farm, but bulking agent(usually sawdust) are expensive and availability is limited. This experiment was conducted to investigate the effect of fly ash as a bulking agent on the composting of swine manure and to analyze the effective substitution rate of fly ash mixed with swine manure for sawdust. Fly ash was able to be substituted for sawdust and the most effective substitution rate are 50% of sawdust. According to the results the advanced research and development are required, the effect of swine manure with fly ash on the soil properties, forage composition and animal performance.