• 제목/요약/키워드: Rate constant

검색결과 4,789건 처리시간 0.031초

부피법 자동장치를 이용한 유사 일정 압력에서 Mg의 수소 흡수 및 방출 반응에 대한 연구 (The Study of the Hydrogen Absorption and Desorption Reactions of Mg under Near Constant Pressure Using the Sievert's Type Automatic Apparatus)

  • 한정섭;김선중
    • 한국수소및신에너지학회논문집
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    • 제30권1호
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    • pp.8-13
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    • 2019
  • In order to apply the Sievert's type automatic apparatus to thermal analysis of hydrogen absorbing materials, the Sievert's type automatic apparatus was modified in my laboratory. In this study, an experiment was conducted to see if hydrogen absorption and desorption reactions are possible under near constant pressure (${\pm}0.05atm$) using this device. The hydrogenation and dehydrogenation of the Mg-H system was investigated. And the program was also modified for the kinetics. It was found that it is possible to measure the hydrogen absorption rate under near constant pressure of Mg by using the modified Sievert's type automatic apparatus at 573 K and 598 K. And using this system, the hydrogen desorption rate of Mg hydride under near constant pressure at 623 K was also measurable. However, since the hydrogen desorption rate of Mg hydride is fast at 648 K, the hydrogen desorption reaction did not proceed within a constant pressure range of $0.15{\pm}0.05atm$.

미셀용액에서 Cyanocobalt(II) 착물의 리간드치환 반응에 대한 속도론적 연구 (Kinetic Studies on the Ligand Substitution Reactions of Cyanocobalt(II) Complexes in Micellar Solutions)

  • 안범수
    • 한국응용과학기술학회지
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    • 제26권3호
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    • pp.370-378
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    • 2009
  • Kinetic studies on the ligand substitution reactions of cyanocomplexes were performed in several micellar solutions. It showed the observed rate constants was found to be independent of the entering ligand concentration at high concentration of cyanopyridine and pyrazinecarboxylate. We could see also that in nonionic and anionic micellar solutions no influence of changes in the surfactant concentration on the observed rate constants was found. Taking into account the hydrophilic nature of the cobalt complex, the cobalt complex molecule was expected to be located in the aqueous phase of the micellar systems, where the reaction would take place. In cationic micellar solutions, a small increase in the observed rate constant was found when the cationic surfactant concentration increased. After reaching a maximum, the rate constant decreased on increasing surfactant concentration and subsequently it reached a plateau, where the observed rate constant was independent of changes in the surfactant concentration.

고장률이 시간 구간별로 다른 경우의 신뢰도 (Reliability for Failure Rates Different over Time Intervals)

  • 전태보
    • 산업기술연구
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    • 제27권B호
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    • pp.245-253
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    • 2007
  • Failure rate serves as a pivotal role in reliability study. Of all, the constant failure rate is the most popularly used in field exercises. In reality, however, the electrical and electronic parts' life is represented by not only the constant failure rate but the decreasing and/or increasing failure rates. Explicit consideration and incorporation of them into the model development may yield more desirable results. In this study, we built a reliability model for failure rates varying over time intervals and derived well known measures such as probability density function, reliability function, mean life, moments, and mission time. We then evaluated mean life with consideration of the first-year multiplier and compared the results those with constant failure rate. The results given in the study may provide a reference applying for practical decision making.

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Experimental Study on Single Bubble Growth Under Subcooled, Saturated, and Superheated Nucleate Pool Boiling

  • Kim Jeong-Bae;Lee Jang-Ho;Kim Moo-Hwan
    • Journal of Mechanical Science and Technology
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    • 제20권5호
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    • pp.692-709
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    • 2006
  • Nucleate pool boiling experiments with constant wall temperature were performed using pure R1l3 for subcooled, saturated, and superheated pool conditions. A microscale heater array and Wheatstone bridge circuits were used to maintain the constant wall temperature and to measure the instantaneous heat flow rate accurately with high temporal and spatial resolutions. Images of bubble growth were taken at 5,000 frames per second using a high-speed CCD camera synchronized with the heat flow rate measurements. The bubble geometry was obtained from the captured bubble images. The effect of the pool conditions on the bubble growth behavior was analyzed using dimensionless parameters for the initial and thermal growth regions. The effect of the pool conditions on the heat flow rate behavior was also examined. This study will provide good experimental data with precise constant wall temperature boundary condition for such works.

정유량 밸브의 카트리지의 오리피스 구멍의 유출계수 (Discharge Coefficients of Orifice Hole in the Cartridge of Constant Flow Control Valve)

  • 유선학;강승덕;양의석;박경암
    • 유체기계공업학회:학술대회논문집
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    • 유체기계공업학회 2004년도 유체기계 연구개발 발표회 논문집
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    • pp.305-308
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    • 2004
  • The constant flow control valve is used to control the flow rate of heating water in the large apartment complex and buildings. It is important to have similar heating flow rate in the apartments, even though the apartment is top or bottom floors. To achieve those purposes, the constant flow control valve was developed. The performance of this control valve is effected by hole area and discharge coefficients of the cartridge holes. The discharge coefficients of orifice hole in the cartridge were testes with various sizes of holes and various flow direction in the holes. The discharge coefficients decreased as the hole size increased due to the collision at the cartridge wall of water jet. The effects of the flow direction at the hole were not significant on the discharge coefficients.

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온라인 서명 검증을 위한 SVM의 커널 함수와 결정 계수 선택 (Selection of Kernels and its Parameters in Applying SVM to ASV)

  • 판윈허;우영운;김성훈
    • 한국정보통신학회:학술대회논문집
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    • 한국정보통신학회 2015년도 추계학술대회
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    • pp.1045-1046
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    • 2015
  • When using the Support Vector Machine in the online signature verification, SVM kernel function should be chosen to use non-linear SVM and the constant parameters in the kernel functions should be adjusted to appropriate values to reduce the error rate of signature verification. Non-linear SVM which is built on a strong mathematical basis shows better performance of classification with the higher discrimination power. However, choosing the kernel function and adjusting constant parameter values depend on the heuristics of the problem domain. In the signature verification, this paper deals with the problems of selecting the correct kernel function and constant parameters' values, and shows the kernel function and coefficient parameter's values with the minimum error rate. As a result of this research, we expect the average error rate to be less than 1%.

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정 진폭 다중 보호 이진 직교 변조 (Constant-Amplitude Biorthogonal Multi-Code Modulation)

  • 홍대기;강성진;주민철;김용성;서경학;조진웅
    • 한국통신학회논문지
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    • 제30권3C호
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    • pp.69-76
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    • 2005
  • 본 논문에서는 다중 부호 신호 (MC: multi-code signal)를 정 진폭으로 전송하는 정 진폭 이진 직교 다중 부호 변조 방식 (CABM: constant-amplitude biorthogonal multi-code modulation)을 제안한다. 정 진폭을 유지하기 위해 제안된 CABM 방식에서는 잉여 비트를 사용하여 신호를 부호화 하였다. 제안된 CABM 변조 방식은 매우 높은 스펙트럼 효율을 지원할 수 있다. 또한 본 논문에서는 제안된 CABM 신호를 복조하기 위한 다양한 복조 방식들을 제시하고 기존의 정 진폭 직교 변조 방식 (CAOM: Constant-amplitude orthogonal multi-code modulation)과 그 성능을 비교한다. 제안된 CABM 변/복조 방식은 고속 데이터 율을 제공해야 하는 디지털 무선 통신 시스템으로 사용될 수 있다.

주택 실내.외 이산화질소 측정을 이용한 환기량 및 발생량 추정 (Estimation of Ventilation and Generation Rates Using Nitrogen Dioxide Measurements of Indoor and Outdoor in Houses)

  • 양원호;임성국;손부순
    • 한국환경과학회지
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    • 제17권10호
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    • pp.1069-1073
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    • 2008
  • Indoor air quality can be affected by indoor sources, ventilation, decay and outdoor levels. Although technologies exist to measure these factors, direct measurements are often difficult. The purpose of this study was to develop an alternative method to characterize indoor environmental factors by multiple indoor and outdoor measurements. Using a mass balance model and regression analysis, penetration factor (ventilation rate divided by the sum of ventilation rate and deposition constant) and source strength factor (source strength divided by the sum of ventilation rate and deposition constant) were calculated using multiple indoor and outdoor measurements. Subsequently, the ventilation rate and $NO_2$ generation rate were estimated. Mean of ventilation rate was 1.41 ACH in houses, assuming a residential N02 deposition constant of 0.94 $hr^{-1}$. Mean generation rate of $NO_2$ was 16.5 ppbv/hr. According to house characterization, inside smoking and family number were higher $NO_2$ generation rates, and apartment was higher than single-family house. In conclusion, indoor environmental factors were effectively characterized by this method using multiple indoor and outdoor measurements.

Parametric Empirical Bayes Estimation of A Constant Hazard with Right Censored Data

  • Mashayekhi, Mostafa
    • International Journal of Reliability and Applications
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    • 제2권1호
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    • pp.49-56
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    • 2001
  • In this paper we consider empirical Bayes estimation of the hazard rate and survival probabilities with right censored data under the assumption that the hazard function is constant over the period of observation and the prior distribution is gamma. We provide an estimator of the first derivative of the prior moment generating function that converges at each point to the true value in $L_2$ and use it to obtain, easy to compute, asymptotically optimal estimators under the squared error loss function.

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약품 주입비율에 따른 하수 슬러지 형태(소화·비소화)가 건조효율에 미치는 영향 - 근적외선 및 마이크로파를 중심으로 - (Effect on Drying Efficiency of the Sewage Sludge (Digested, non digested) according to Polymer dose Ratio - Focus on the NIR and Microwave -)

  • 이승원
    • 한국환경과학회지
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    • 제30권3호
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    • pp.245-255
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    • 2021
  • In this study, we evaluated the effect of the type of sewage sludge (digested, non digested) on drying efficiency according to the polymer injection rate. The drying characteristics were shown using a near-infrared ray (NIR) and a microwave. As a result of the drying characteristics with NIR at a polymer dose ratio of 8%, the heating up period is up to 6 minutes after the start of the drying experiment. Afterwards, the constant rate drying period of the digested sludge (A, C and G sites) was 6 minute → 18 minute, showing a rapid decrease in moisture. On the other hand, non digested sludge (B, D, E, F, H, I, J and K sites) showed gradual drying characteristics compared to digested sludge until complete drying (10%). As the polymer dose ratio of 10% and 12%, the heating up period for digested sludge is up to 6 minute after the start of the experiment. Afterwards, the constant rate drying period of the digested sludge was 6 minute → 20 minute, showing a rapid decrease in moisture. On the other hand, the heating up period of non digested sludge was up to 10 minute after the start of the experiment, and the constant rate drying period was 10 minute → 22 minute, which was shorter than digested sludge. As a result of the drying characteristics with microwave at a polymer dose ratio of 8%, 10% and 12%, the constant rate drying period the digested sludge was 4 minute → 20~22 minute, showing a rapid decrease in moisture. On the other hand, non digested sludge of the constant rate drying period was 4 minute → 22~30 minute, which was longer than digested sludge.