• Title/Summary/Keyword: Rate Limiting

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Foaming Properties and Flame Retardancy of the Foams Based on NBR/GTR Compounds (니트릴고무/타이어고무분말(GTR)를 이용한 발포체의 발포 및 난연 특성에 관한 연구)

  • Moon, Sung-Chul;Jo, Byung-Wook;Choi, Jae-Kon
    • Elastomers and Composites
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    • v.37 no.3
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    • pp.159-169
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    • 2002
  • The improvement of flame retardancy of the foams based on NBR/GTR compounds was conducted by formulating various materials i.e. NBR, GTR, inorganic and phosphorus containing flame retardants, foaming agent, cross-linking agent and activator. The foaming properties, morphology, smoke density and flame retardancy of the specimens were investigated using SEM, LOI tester, smoke density control system and cone calorimeter. The phosphorus containing flame retardant reduces heat release rate, increases the limiting oxygen index and a char formation. The inorganic flame retardant increases the limiting oxygen index and reduces heat release rate with an increased CO yield by char formation, and smoke suppressing effect. The formed char seemed to intercept the oxygen transport and heat transfer into the core area. When the composition ratios of the compounds of NBR/GTR were $100{\sim}80/0{\sim}20 wt.%$, and the ratios of the rubbers/flame retardants were $1/1.55{\sim}3.60 wt.%$, we could developed foams with low heat release rate, high limiting oxygen index($28.0{\sim}39.3$), closed or semi-closed cell of uniformity and reasonable expandability($225{\sim}250 %$).

Study on Rate-Limiting Factors with a Heavy Loaded Biofilter

  • Son, Hyun-Keun
    • Journal of Korean Society for Atmospheric Environment
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    • v.23 no.E2
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    • pp.74-81
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    • 2007
  • Feasibility test for a biofilter was performed to treat VOCs. The applied loading rate to the biofilter was calculated between 60 to $3,700\;kg\;COD/m^3$. Trimethyl-pentene and trimethyl-hexene were the two most dominant compounds and they occupy about 85 percent. During the acclimation period, it is desirable for a biofilter to receive relatively lower VOCs concentration and flow rate, until it can adjust to new substrate and operational environment. Temperature at various points inside the biofilter reactor was observed with more than 23 temperature sensors. With steam heating, temperatures of the top sections of the media were greater than those of bottom sections. Without steam heating, intermediate stages generally had higher temperature measurement than those of bottom and top stages. Because the pH values for different biofilter materials vary significantly, measurement of the pH for the mixture of different combinations of biofilter materials is necessary. Based on the types and brands of media, the measured pH ranged from 5.38 to 9.10. The range of measured pH of different mixtures with perlite, compost, saw dust, peat moss, limestone, vermiculite was 7.05 to 8.62.

Dissolution Kinetics of Sphalerite in Aqueous Ferric Chloride Solution (염화제이철 수용액에서 섬아연광의 용해에 관한 속도론적 연구)

  • Yoo, Seung-Joon;Park, Hyung-Sang;Choi, Cheong-Song;So, Chil-Sup
    • Economic and Environmental Geology
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    • v.26 no.3
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    • pp.421-429
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    • 1993
  • Dissolution reactions of chemical grade zinc sulfide and natural sphalerite were studied in ferric chloride solution as an oxidant. To enhance the leaching reaction, ultrasonic technique was employed in this investigation. For the reaction with pure zinc sulfide, chemical reaction was the rate limiting step in the range of low conversion irrespective of applying ultrasonic wave. And the diffusion through liquid film instead of diffusion through product layer of free sulfur was the rate determining step because ultrasonic vibration removes the product from reaction zone. In the case of sphalerite with the ultrasonic vibrator, it was found that inert mineral layer diffusion was the rate determining step, in which the elemental sulfurs formed were removed by the ultrasonic action. Experimental results showed that the ultrasonic technique proved to be the methods which can significants improve the leaching performance.

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Experiments on PEMFC performance enhancement by pulsating cathode flow

  • Han, Hun-Sik;Kim, Ki-Woong;Kim, Yun-Ho;Kim, Seo-Young
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.05a
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    • pp.542-545
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    • 2008
  • Experiments have been performed to investigate effects of pulsating cathode flow on a 10-cell proton exchange membrane fuel cell (PEMFC) stack. For all the experiments, the flow rate, temperature and relative humidity of hydrogen at the anode inlet are fixed. The effects of the pulsating frequency, amplitude and flow rate at the cathode inlet on performance of 10-cell PEMFC are examined. The polarization and power curves show that the power output and limiting current is substantially increased when the pulsating component is added to cathode flow channel. The maximum power output increases by up to 38% and enhancement of the overall performance is more pronounced at lower flow rate region.

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Reductive Dechlorination of Chlorinated Oraganic Compounds Using Zero-Valent Iron (0가 철분을 이용한 유기염소화합물의 환원적 탈염소화)

  • Lee, Chang-soo;Bae, Woo-keun
    • Journal of the Korean Society of Industry Convergence
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    • v.4 no.4
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    • pp.427-432
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    • 2001
  • The purpose of study is to examine the sensitivity of the rate of degradation to initial TCE concentration and iron concentration in the solution. The batch tests were executed to assess the degradation rate at varying initial conditions. First order rate constants($k_a$) were more rapid with the lower initial TCE concentration, Howere the correleation was not always linear between $k_a$ and initial TCE concentration. $k_a$ was proportionally increased as the increasing surface area. It implied that the effective reactive surface area acted as the limiting factor on the reductive dechlorination of TCE by iron.

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Theoretical analysis on the correlation between the amount of available phosphorus and the growth rate of Chlorella ellipsoidea. (Chlorella 익 비성장율에 미치는 유효인산량과 그 이론적 분석)

  • 이주식;장남기;이태우
    • Korean Journal of Microbiology
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    • v.5 no.1
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    • pp.34-38
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    • 1967
  • Theoretical analysis reported in this paper is on the varities of the growth rate of Chlorella ellipsoidea due to the amount of available phosphorus for the purpose of the continual mass culture. Available phosphorus in the culture media of the Chlorella was also estimated at a limiting factor as this experiment. The equation between the concentration of Chlorella n and growth period t is $\frac{dn}{dt}=Kn$, and the functional relation between the Specific growth rate K and steady state period T is the following: $K=\frac{2.303}{T}$log\frac{n}{no}$ ($n_o$=initial concentration).

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Dissoultion and Rectal Absorption of Acetaminophen from Suppositories (아세트아미노펜 좌제의 용출과 직장흡수)

  • 한정선;심창구;김신근
    • YAKHAK HOEJI
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    • v.31 no.5
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    • pp.286-295
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    • 1987
  • The relationship between in vitro release and in vivo bioavailability of acetaminophen from suppositories was investigated. Effect of glycyrrhizin on the drug release and rectal absorption in rats was also examined. Suppositories containing 25mg of acetaminophen were prepared with Wecobee FS (fatty base) or PEG (water-soluble base) bases. The release from the suppositories were determined with USP rotating basket dissolution apparatus and with the suppository release tester. The temperature of the dissolution medium was very critical for the dissolution of acetaminophen from Wecobee FS suppositories. The bioavailability of acetaminophen was calculated from the plasma concentration-time curve after rectal administration of the suppositories to the rats. There were no significant differences in AUC following rectal administration of Wecobee FS and PEG suppositories, but the release and absorption from the Wecobee FS suppositories were faster than those from PEG suppositories. The dissolution rate obtained by the suppository release tester was better correlated with in vivo absorption rate constant than that by the USP dissolution apparatus. It suggests that the partitioning between rectal fluid and suppository base is the rate-limiting step in the rectal absorption of acetaminophen from suppositories. Glycyrrhizin was found not to affect in vitro dissolution and rectal absorption of acetaminophen.

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A surrogate model for the helium production rate in fast reactor MOX fuels

  • D. Pizzocri;M.G. Katsampiris;L. Luzzi;A. Magni;G. Zullo
    • Nuclear Engineering and Technology
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    • v.55 no.8
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    • pp.3071-3079
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    • 2023
  • Helium production in the nuclear fuel matrix during irradiation plays a critical role in the design and performance of Gen-IV reactor fuel, as it represents a life-limiting factor for the operation of fuel pins. In this work, a surrogate model for the helium production rate in fast reactor MOX fuels is developed, targeting its inclusion in engineering tools such as fuel performance codes. This surrogate model is based on synthetic datasets obtained via the SCIANTIX burnup module. Such datasets are generated using Latin hypercube sampling to cover the range of input parameters (e.g., fuel initial composition, fission rate density, and irradiation time) and exploiting the low computation requirement of the burnup module itself. The surrogate model is verified against the SCIANTIX burnup module results for helium production with satisfactory performance.

Characteristics of a Rhodobacter sphaeroides mutant selected by increased growth rate under light-limiting photoheterotrophic conditions

  • Lim, Soo-Kyoung;Lee, Il-Han;Lee, Jeong K.
    • Proceedings of the Botanical Society of Korea Conference
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    • 1999.08a
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    • pp.55-67
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    • 1999
  • A puc -deleted cell of Rhodobacter sphaeroides grows with a doubling time longer than 160 h under the light-limiting photoheterotrophic ( 3 Watts [W]/㎡) conditions due to an absence of the peripheral light-harvesting B800-850 complex. A spontaneous fast-growing mutant, R.sphaeroides SK101 was ioslate dto have∼40-h doubling at 3 Watts/㎡, while the growth of the mutant was not distinguished from its parental strain during both aerobic and light-saturating photoheterotrphic (10W/㎡) growth. The B875 complex of SK101 under the light-limiting conditions was elevated by 20 to 30% compared with that of the puc -deleted cell, reflecting parallel increase of bacteriochlorophyll and carotenoid contents of the mutant. The formation of B875 complex of SK101 under the anaerobic dark conditions with dimethylsulfoxide was the same as that of the puc-deleted cell. suggesting that the mutation of SK101 result in the altered control of B875 complex formation by light. When puc is restored in SK101 , it is not B875 complex but B800-850 complex which formation is elevated. The mutation of SK101 affected the bchF transcription most drastically to show two to tenfold increase during both aerobic and photoheterotrophic growth. The mutated phenotype of SK101 was complemented with pW2, which contains approximately 100-kb HNA of the photosynthetic gene clusters. The complementing DNA was narrowed down to a 1.1-kb DNA containing orfQ and pufKBA . The mutation of SK101 appeared to be exerted through the mutation of the orfQ gene encoding a putative bacteriochlorophyll -mobilizing protein.

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Operation of Electrodialysis at Over Limiting Current Density (한계전류밀도 이상에서 전기투석공정의 운전)

  • 박진수;최재환;문승현
    • Membrane Journal
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    • v.12 no.3
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    • pp.171-181
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    • 2002
  • The parameter which determines the plateau length of current-voltage curve for ion- exchange membranes was studied at various concentrations of NaCl and different flow rates. Moreover, the feasibility of the electrodialytic removal of 0.1 M NaCl solution at various current densities was tested by assessing the electrodialysis performance parameters such as salt removal efficiency, current efficiency, energy consumption and water dissociation. The diffusion boundary layer (DBL) thickness decreased with the NaCl concentration and flow rate of fled solution and it was observed that the plateau length of current-voltage curves was related with the DBL thickness. The removal efficiency and current efficiency were not affected significantly by the current densities even at the overlimiting current region indicating that most current were passed by electrolyte, and water dissociations are not responsible for the overlimiting current. Energy consumption increased when the current density supplied exceeded the limiting current density (LCD) values, because additional energy was necessary to overcome the plateau potential. Beyond the LCD values the energy consumption required to get a certain removal efficiency was not affected by the current density applied. The result suggests that it is allowed to operate electrodialysis processes at as high as possible current density unless water-splitting does not occur.