• Journal of the Korean Chemical Society
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• v.30 no.6
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• pp.538-547
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• 1986

The 8 rare earth elements were determined in the monazite concentrates by X-ray fluorescence spectrometry. The spectral line overlapping interferences from the other elements were investigated and the correction methods of interferences were studied using line overlap coefficients. The coefficients were calculated from the ratios of the intensities measured at the diffracted angle (2${\theta}$) of the analytical lines of other elements to the intensity of pure rare earth oxide. The coefficients were used to correct the line overlaps by a regression analysis. The linearities of calibration curves from the corrected intensities were remarkably improved, and their standard deviations were decreased. The analytical results agreed with that of the inductively coupled plasma(ICP) spectrometry within an allowable error range.

• Nuclear Engineering and Technology
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• v.53 no.12
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• pp.4106-4113
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• 2021

Rare earth doped barium tellurite glasses were synthesised and explored for their radiation shielding applications. All the samples showed good thermal stability with values varying between 101 ℃ and 135 ℃ based on dopants. Structural properties showed the dominance of matrix elements compared to rare earth dopants in forming the bridging and non-bridging atoms in the network. Bandgap values varied between 3.30 and 4.05 eV which was found to be monotonic with respective rare earth dopants indicating their modification effect in the network. Various radiation shielding parameters like linear attenuation coefficient, mean free path and half value layer were calculated and each showed the effect of doping. For all samples, LAC values decreased with increase in energy and is attributed to photoelectric mechanism. Thulium doped glasses showed the highest value of 1.18 cm^-1 at 0.245 MeV for 2 mol.% doping, which decreased in the order of erbium, holmium and the base barium tellurite glass, while half value layer and mean free paths showed an opposite trend with least value for 2 mol.% thulium indicating that thulium doped samples are better attenuators compared to undoped and other rare earth doped samples. Studies indicate an increased level of thulium doping in barium tellurite glasses can lead to efficient shielding materials for high energy radiation.

• Journal of the Korean Chemical Society
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• v.33 no.3
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• pp.304-308
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• 1989

The spectrophotometric determination of $Lu^{3+},\;Eu^{3+}$ and some other rare earths have been investigated using Methyl Thymol Blue(MTB) as spectrophotometric reagent. Rare earth elements form a stable complex with MTB abount pH 6.5 and the ratio of its complex is 1 to 1. MTB has a absorption maxima at 440nm and rare earth MTB complex has absorption maxima 610nm at pH 6.5, respectively. The absorbance of the rare earth MTB complex is stable in 7 hours after color developing and obey the Beer law in the range of $0{\sim}110{\mu}g/50ml$. The ligand such as phosphate, citrate and EDTA decrease the absorbance of its complex considerably, and this method has a poor selectivity of each rare earth element and the molar absorptivity is $1.2{\sim}2.0{\times}10^4mol^{-1}{\cdot}l{\cdot}cm^{-1}$. In methyl alcohol, ethyl alcohol and acetone medium we did not find out any absorption change of the rare earth MTB complex.

• Journal of Powder Materials
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• v.28 no.2
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• pp.91-96
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• 2021

Rare earth magnets with excellent magnetic properties are indispensable in the electric device, wind turbine, and e-mobility industries. The demand for the development of eco-friendly recycling techniques has increased to realize sustainable green technology, and the supply of rare earth resources, which are critical for the production of permanent magnets, are limited. Liquid metal extraction (LME), which is a type of pyrometallurgical recycling, is known to selectively extract the metal forms of rare earth elements. Although several studies have been carried out on the formation of intermetallic compounds and oxides, the effect of oxide formation on the extraction efficiency in the LME process remains unknown. In this study, microstructural and phase analyses are conducted to confirm the oxidation behavior of magnets pulverized by a jaw crusher. The LME process is performed with pulverized scrap, and extraction percentages are calculated to confirm the effect of the oxide phases on the extraction of Dy during the reaction. During the L ME process, Nd is completely extracted after 6 h, while Dy remains as Dy₂Fe₁₇ and Dy-oxide. Because the decomposition rate of Dy₂Fe₁₇ is faster than the reduction rate of Dy-oxide, the importance of controlling Dy-oxide on Dy extraction is confirmed.

• Journal of the Korean Magnetics Society
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• v.22 no.2
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• pp.58-65
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• 2012

Since Nd-Fe-B magnet was first synthesized in 1983, many new applications have emerged in the past two decades. With regard to motor market, it will expand because of strong energy saving requirements from the automobile and electric application markets. Especially, permanent magnet motors for hybrid and electric vehicles are drawing great attention and the usage of Nd-Fe-B magnets will increase all the more hereafter. There is, however, a serious problem as motors in such eco-friendly cars are said to operate in high temperatures of about $200^{\circ}C$. Nd-Fe-B magnet has a drawback of dramatically decreasing coercive force with the rise of temperature. In order to improve this aspect. the best way is to add dysprosium (Dy) into the magnet. So, Dy has become an essential element for Nd-Fe-B high-performance magnet as it helps to maintain coercive force even at high temperatures. On the other hand, the rare earth resources in the earth crust are eccentrically-located and its majority is produced in China. There is a need to reduce its usage as, especially compared to light rare earth elements as neodymium (Nd) and samarium (Sm), heavy rare earth elements including Dy are unevenly distributed to a dramatic degree, their output low, and their prices are about 10 times that of Nd. The present article includes a summary of the trend in research and development of motors and permanent magnets to solve rare-earth resources problem.

• Proceedings of the Materials Research Society of Korea Conference
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• 2010.05a
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• pp.48.2-48.2
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• 2010

The effect of additives as rare-earth in dielectric materials has been studied to meet the development trend in electronics on the miniaturization with increasing the capacitance of MLCCs (multi-layered ceramic capacitors). It was reported that the addition of rare-earth oxides in dielectrics would contribute to enhance dielectric properties and high temperature stability. Especially, dysprosium and thulium are well known to the representative elements functioned as selective substitution in barium titanate with perovskite structure. The effects of these additives on microstructure and electric properties were studied. The 0.8 mol% Dy doped $BaTiO_3$ and the 1.0 mol% Tm doped $BaTiO_3$ had the highest electric properties as optimized composition, respectively. According to the increase of rare-earth contents, the growth of abnormal grains was suppressed and pyrochlore phase was formed in more than solubility limits. Furthermore, the effect of two rare-earth elements co-doped $BaTiO_3$ on the dielectric properties and insulation resistance was investigated with different concentration. The dielectric specimens with $BaTiO_3-Dy_2O_3-Tm2O_3$ system were prepared by design of experiment for improving the electric properties and sintered at $1320^{\circ}C$ for 2h in a reducing atmosphere. The dielectric properties were evaluated from -55 to $125^{\circ}C$ (at $1KHz{\pm}10%$ and $1.0{\pm}0.2V$) and the insulation resistance was examined at 16V for 2 min. The morphology and crystallinity of the specimens were determined by microstructural and phase analysis.

• Journal of the Korean Magnetics Society
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• v.21 no.6
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• pp.225-230
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• 2011

Magnetic materials has been applied to various fields due to their energy convertible properties between electrical and mechanical energy. Particularly, permanent magnets have been currently attracted much attention because they produce external magnetic field without any electrical current. For high efficiency, a demand for permanent magnets containing rare earth elements has been continuously increased, which abruptly raises the price and causes the supply difficulty of rare earth materials. Therefore, the development of permanent magnets with less or without rare earth elements become a urgent issue. In this report, the current trend and major issues on high efficiency permanent magnets, particularly exchange-coupling magnets, are discussed.

• Proceedings of the KSEEG Conference
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• 2005.04a
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• pp.3-6
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• 2005

• Journal of the Korean Chemical Society
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• v.39 no.2
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• pp.28-81
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• 1995

Inductively coupled plasma atomic emission spectrometry was used for the determination of all 14 rare earth elements (REE) in geological materials. Samples were decomposed by using acid digestion followed by alkaline fusion. Group separation of the REE was achieved by solvent extraction with TOPO (trioctylphosphine oxide) and back extraction into HCl. The results for standard rock sample, AGV-1, showed a good agreement with those obtained by US Geological Survey as well as reported values in other articles.

• Analytical Science and Technology
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• v.8 no.1
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• pp.41-45
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• 1995

To analyze mixed rare earth elements quantitatively a nonlinear fitting method was applied to laser induced fluorescence signals. Mixed flourescence signal of two elements, Sm and Eu were resolved independently and determined the concentration of these two elements simultaneously. It was found that detection limit for each element in the mixture was sub-ppb level which was the same as that of the single element sample. Additionally it was found that lifetimes of Sm and Eu extracted from the nonlinear fitting method is the same as in the single element cases.