• 제목/요약/키워드: Rare

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Extraction Chromatograph Separation Spark Source Mass Spectrometric Analysis of 14 Rare Earth Impurities in High Purity Rare Earth Oxide

  • Sui, Xiyun;Wang, Zishu;Shao, Baohai
    • 분석과학
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    • 제8권4호
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    • pp.553-559
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    • 1995
  • An extraction chromatographic method of separating rare earth impurities from high purity $Nd_2O_3$, $Sm_2O_3$, $Gd_2O_3$, $Er_2O_3$, $Dy_2O_3$ and $Yb_2O_3$ was studied by using $HCl-NH_4Cl$ as moving phase and P507 as stationary phase. After the impurities were enriched from the eluate by chelant-activated carbon, the active carbon was ashed and the ignited residue was used to prepare the sample electrode for spark source mass spectrometric determination. The impurities in 99.9999% rare earth oxide can be determined by the proposed method with recovery over 80%.

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POSCO's Research and Development works on rare earth reduced NdFeB magnets production process

  • Yuh, Junhan
    • 한국자기학회:학술대회 개요집
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    • 한국자기학회 2013년도 자성 및 자성재료 국제학술대회
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    • pp.90-90
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    • 2013
  • Since discovery, NdFeB permanent magnet has replaced application of the conventional magnets rapidly because of its superior physical and mechanical properties. With increasing consumption of power combined with energy resource depletion, energy efficiency is becoming more and more inportant. According to recent reports, almost almost half of the electric power is consumed by motor, and NdFeB magnets which are the core component of the motor play a key role on improving energy efficiency of the devices. In parallel with finding alternatives energy resources, research works improving energy efficiecy have been conducted world wide. Althogh NdFeB magnets usage have been expanded to various applications, key materials such as Nd and Dy, resouces lean heavily on specific area, China. Magnetic industry revently experienced skyrocketing price fluctuatioin of rare earth at around 2008. Chineses government's regulations worsened the situation and arose a necessity to develop methods to minimize rare earth use. In this presentation, POSCO's recent research works on rare earth reduction is presented including novel powder alloying method using nitrate precursors. Also, future R&D plans for rare earth free magnets is briefly introduced as well.

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음이온교환수지에 의한 모나자이트중 희토류원소의 분리 (Separation of Rare Earth Elements in Monazite Sand by Anion Exchange Resin)

  • 차기원;이종해;하영구
    • 대한화학회지
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    • 제24권3호
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    • pp.239-244
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    • 1980
  • 모나자이트 중의 Y, La, Ce, Pr 및 Nd 들을 pH 8.4에서 EDTA와 착염을 만들어 미리 음이온 교환수지에 EDTA를 흡착시킨 수지관에 용리시켜 희토류 원소들의 분리를 시도하였다. 용리액은 pH 8.4의 EDTA를 사용하였으며, 용리액의 분율에 따라 측정한 각이온의 분리도는 55∼98%이었다.

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Identification of HGD mutations in an alkaptonuria patient: using the Internet to seek rare diseases

  • Cho, Sang-Yeun;Kim, Ja Hye
    • Journal of Genetic Medicine
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    • 제15권1호
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    • pp.17-19
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    • 2018
  • Alkaptonuria (AKU, OMIM: 203500) is a rare autosomal recessive disorder of tyrosine metabolism due to a defect of enzyme activity, homogentisate 1,2-dioxygenase (HGD). The patients with AKU initially presented with dark urine discoloration, and ochronosis and arthritis develop after third decades of life. With advances of Internet resources, web-based health seekers for rare disease are increasing. Here, we report the case of an 18-year-old boy with AKU who visited our center due to dark black urine based on self-diagnosis via web searching of this rare condition. Compound heterozygous mutations in HGD gene, IVS5+3A>C and IVS12+6T>C were identified and both of mutations were detected in his parents. Our case illustrates the utility of publicly available Internet resources for diagnosis of rare disease.

Porous Materials Based on Nickel and Aluminum

  • Dubinina, L.V.;Lopatin, V.U.;Narva, V.K.;Shugaev, V.A.;Vin, Tein
    • 한국분말야금학회:학술대회논문집
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    • 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part 1
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    • pp.614-615
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    • 2006
  • Investigation of influence the morphology of initial powder particles, application pore-formers for sintering of nickel powders and application of flux for sintering of aluminum was made. Using different methods was prepared material with size of porous in wide range size of pores ($1-500{\mu}m$). Using the flux for gravity sintering of aluminum in air atmosphere was manufactured porous material with porosity about 45%..

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Terpolymerization of Carbon Monoxide, Styrene, and 4-Methylstyrene Catalyzed by Palladium-Rare Earth Catalyst

  • Tian, Jing;Guo, Jin-Tang;Li, Peng;Zhang, Xin;Chen, Zhi-Kun;Zhao, Hai-Yang
    • Macromolecular Research
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    • 제17권8호
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    • pp.563-567
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    • 2009
  • In order to improve the thermomechanical performance of polyketone, a third monomer (4-methylstyrene) was added to the copolymerization system. The terpolymer of CO, styrene, and 4-methylstyrene was synthesized in the presence of multi component catalysts containing palladium acetate and rare earth metal phosphonates. The products were characterized by infrared spectroscopy (IR), and nuclear magnetic resonance spectroscopy (NMR). The effects of the different components, including the third monomer, palladium acetate, 2,2'-bipyridyl, rare earth phosphonate, p-toluene-sulphonic acid, and p-benzoquinone, were also studied. The highest catalytic activity of 965.51 g/(gPd h) was obtained with a catalyst containing palladium acetate and rare earth phosphonate.

Low Temperature Test of HWR Cryomodule

  • Kim, Heetae;Kim, Youngkwon;Lee, Min Ki;Park, Gunn-Tae;Kim, Wookang
    • Applied Science and Convergence Technology
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    • 제25권3호
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    • pp.47-50
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    • 2016
  • Low temperature test for half-wave resonator (HWR) cryomodule is performed at the superfluid helium temperature of 2 K. The effective temperature is defined for non-uniform temperature distribution. Helium leak detection techniques are introduced for cryogenic system. Experimental set up is shown to make the low temperature test for the HWR cryomodule. The cooldown procedure of the HWR cryomodule is shown from room temperature to 2 K. The cryomodules is precooled with liquid nitrogen and then liquid helium is supplied to the helium reservoirs and cavities. The pressure of cavity and chamber are monitored as a function of time. The vacuum pressure of the cryomodule is not increased at 2 K, which shows leak-tight in the superfluid helium environment. Static heat load is also measured for the cryomodule at 2.5 K.

국내 원자력발전소 지진 PSA의 CDF 과평가 방지를 위한 비희귀사건 모델링 방법 연구 (A Simple Approach to Calculate CDF with Non-rare Events in Seismic PSA Model of Korean Nuclear Power Plants)

  • 임학규
    • 한국안전학회지
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    • 제36권5호
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    • pp.86-91
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    • 2021
  • Calculating the scrutable core damage frequency (CDF) of nuclear power plants is an important component of the seismic probabilistic safety assessment (SPSA). In this work, a simple approach is developed to calculate CDF from minimal cut sets (MCSs) with non-rare events. When conventional calculation methods based on rare event approximations are employed, the CDF of industry SPSA models is significantly overestimated by non-rare events in the MCSs. Recently, quantification algorithms using binary decision diagrams (BDDs) have been introduced to prevent CDF overestimation in the SPSA. However, BDD structures are generated from a small part of whole MCSs due to limited computational memory, and they cannot be reviewed due to their complicated logic structure. This study suggests a simple approach for scrutinizing the CDF calculation based on whole MCSs in the SPSA system analysis model. The proposed approach compares the new results to outputs from existing algorithms, which helps in avoiding CDF overestimation.

First Records of Rare Ascomycete Fungi, Acrostalagmus luteoalbus, Bartalinia robillardoides, and Collariella carteri from Freshwater Samples in Korea

  • Nguyen, Thuong T.T.;Lee, Seo Hee;Jeon, Sun Jeong;Lee, Hyang Burm
    • Mycobiology
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    • 제47권1호
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    • pp.1-11
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    • 2019
  • The distribution and occurrence of rare ascomycete fungi within freshwater samples in Korea was investigated. Three rare fungal strains, CNUFC-YR537-1, CNUFC-CNUP1-1, and CNUFC-NDR3-1, were isolated using serial dilution method. On the basis of their morphological characteristics and phylogenetic analysis of their internal transcribed spacer regions and 28S rDNA sequences, the three isolates were identified as Acrostalagmus luteoalbus, Bartalinia robillardoides, and Collariella carteri, respectively. To our knowledge, these are the first records of rare genera Acrostalagmus, Bartalinia, and Collariella from Korea, and the first reports of A. luteoalbus, B. robillardoides, and C. carteri from freshwater samples.

Multi-omics techniques for the genetic and epigenetic analysis of rare diseases

  • Yeonsong Choi;David Whee-Young Choi;Semin Lee
    • Journal of Genetic Medicine
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    • 제20권1호
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    • pp.1-5
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    • 2023
  • Until now, rare disease studies have mainly been carried out by detecting simple variants such as single nucleotide substitutions and short insertions and deletions in protein-coding regions of disease-associated gene panels using diagnostic next-generation sequencing in association with patient phenotypes. However, several recent studies reported that the detection rate hardly exceeds 50% even when whole-exome sequencing is applied. Therefore, the necessity of introducing whole-genome sequencing is emerging to discover more diverse genomic variants and examine their association with rare diseases. When no diagnosis is provided by whole-genome sequencing, additional omics techniques such as RNA-seq also can be considered to further interrogate causal variants. This paper will introduce a description of these multi-omics techniques and their applications in rare disease studies.